Rechargeable Metasurfaces for Dynamic Color Display Based on a Compositional and Mechanical Dual-Altered Mechanism

Dynamic color display can be realized by tunable optical metasurfaces based on the compositional or structural control. However, it is still a challenge to realize the efficient modulation by a single-field method. Here, we report a novel compositional and mechanical dual-altered rechargeable metasurface for reversible and broadband optical reconfiguration in both visible and near-infrared wavelength regions. By employing a simple fabrication and integration strategy, the continuous optical reconfiguration is manipulated through an electro-chemo-mechanical coupled process in a lithium ion battery, where lithiation and delithiation processes occur dynamically under a low electric voltage (≤1.5 V). By controlling the phase transformation from Si to Li_xSi, both structural morphology and optical scattering could be rapidly and dramatically tailored within 30 s, exhibiting high-contrast colorization and decolorization in a large-area nanofilm and showing long cyclic stability. Significant wide-angle reconfiguration of high-resolution structural colors in bowtie metasurfaces is demonstrated from anomalous reflection. The results provide a multifield mechanism for reconfigurable photonic devices, and the new platform can be introduced to the multidimensional information encryption and storage.