Recent research progress in the study of catalytic CO oxidation by gas phase atomic clusters

Li Na Wang; Xiao Na Li; Sheng Gui He

doi:10.1007/s40843-019-1206-2

Recent research progress in the study of catalytic CO oxidation by gas phase atomic clusters

Li Na Wang, Xiao Na Li, Sheng Gui He^*

^*Corresponding author for this work

Research output: Contribution to journal › Review article › peer-review

29 Citations (Scopus)

Abstract

Oxidation of CO into CO₂ is a major solution to reduce CO emission into the atmosphere and to remove CO in fuel gas cleanup. Furthermore, CO oxidation serves as a prototypical reaction for heterogeneous catalysis. This review provides an overview and an update on how to study catalytic CO oxidation at a strictly molecular level by performing well-controlled gas-phase experiments in combination with quantum chemistry calculations. The advances in the unique catalytic reactivity of single-atom cluster catalysts are emphasized. The catalytically active sites and various mechanistic aspects in the redox couples N₂O/CO and O₂/CO for the seemingly simple oxidation reaction are described.

Translated title of the contribution	气相原子团簇催化氧化一氧化碳研究新进展
Original language	English
Pages (from-to)	892-902
Number of pages	11
Journal	Science China Materials
Volume	63
Issue number	6
DOIs	https://doi.org/10.1007/s40843-019-1206-2
Publication status	Published - 1 Jun 2020
Externally published	Yes

Keywords

CO oxidation
atomic clusters
density functional theory calculations
mass spectrometry
single-atom catalysts

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10.1007/s40843-019-1206-2

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title = "Recent research progress in the study of catalytic CO oxidation by gas phase atomic clusters",

abstract = "Oxidation of CO into CO2 is a major solution to reduce CO emission into the atmosphere and to remove CO in fuel gas cleanup. Furthermore, CO oxidation serves as a prototypical reaction for heterogeneous catalysis. This review provides an overview and an update on how to study catalytic CO oxidation at a strictly molecular level by performing well-controlled gas-phase experiments in combination with quantum chemistry calculations. The advances in the unique catalytic reactivity of single-atom cluster catalysts are emphasized. The catalytically active sites and various mechanistic aspects in the redox couples N2O/CO and O2/CO for the seemingly simple oxidation reaction are described.",

keywords = "CO oxidation, atomic clusters, density functional theory calculations, mass spectrometry, single-atom catalysts",

author = "Wang, {Li Na} and Li, {Xiao Na} and He, {Sheng Gui}",

note = "Publisher Copyright: {\textcopyright} 2019, Science China Press and Springer-Verlag GmbH Germany, part of Springer Nature.",

year = "2020",

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T1 - Recent research progress in the study of catalytic CO oxidation by gas phase atomic clusters

AU - Wang, Li Na

AU - Li, Xiao Na

AU - He, Sheng Gui

PY - 2020/6/1

Y1 - 2020/6/1

N2 - Oxidation of CO into CO2 is a major solution to reduce CO emission into the atmosphere and to remove CO in fuel gas cleanup. Furthermore, CO oxidation serves as a prototypical reaction for heterogeneous catalysis. This review provides an overview and an update on how to study catalytic CO oxidation at a strictly molecular level by performing well-controlled gas-phase experiments in combination with quantum chemistry calculations. The advances in the unique catalytic reactivity of single-atom cluster catalysts are emphasized. The catalytically active sites and various mechanistic aspects in the redox couples N2O/CO and O2/CO for the seemingly simple oxidation reaction are described.

AB - Oxidation of CO into CO2 is a major solution to reduce CO emission into the atmosphere and to remove CO in fuel gas cleanup. Furthermore, CO oxidation serves as a prototypical reaction for heterogeneous catalysis. This review provides an overview and an update on how to study catalytic CO oxidation at a strictly molecular level by performing well-controlled gas-phase experiments in combination with quantum chemistry calculations. The advances in the unique catalytic reactivity of single-atom cluster catalysts are emphasized. The catalytically active sites and various mechanistic aspects in the redox couples N2O/CO and O2/CO for the seemingly simple oxidation reaction are described.

KW - CO oxidation

KW - atomic clusters

KW - density functional theory calculations

KW - mass spectrometry

KW - single-atom catalysts

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DO - 10.1007/s40843-019-1206-2

M3 - Review article

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SN - 2095-8226

VL - 63

SP - 892

EP - 902

JO - Science China Materials

JF - Science China Materials

IS - 6

ER -

Recent research progress in the study of catalytic CO oxidation by gas phase atomic clusters

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Keywords

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