Radicamines A and B: Synthesis and revision of the absolute configuration

Chu Yi Yu; Mu Hua Huang

doi:10.1021/ol0609210

Radicamines A and B: Synthesis and revision of the absolute configuration

Chu Yi Yu^*
, Mu Hua Huang

^*Corresponding author for this work

CAS - Institute of Chemistry
University of Chinese Academy of Sciences

Research output: Contribution to journal › Article › peer-review

86 Citations (Scopus)

Abstract

Starting from D-xylose, enantioselective syntheses of 1 and 2, the proposed structures for radicamines A and B, were accomplished. Both ¹H and ¹³C NMR spectra of 1 and 2 were identical with those of the natural products, but the optical rotation measurements identified that 1 and 2 were actually the enantiomers of the natural radicamines A and B, respectively.

Original language	English
Pages (from-to)	3021-3024
Number of pages	4
Journal	Organic Letters
Volume	8
Issue number	14
DOIs	https://doi.org/10.1021/ol0609210
Publication status	Published - 6 Jul 2006
Externally published	Yes

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10.1021/ol0609210

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title = "Radicamines A and B: Synthesis and revision of the absolute configuration",

abstract = "Starting from D-xylose, enantioselective syntheses of 1 and 2, the proposed structures for radicamines A and B, were accomplished. Both 1H and 13C NMR spectra of 1 and 2 were identical with those of the natural products, but the optical rotation measurements identified that 1 and 2 were actually the enantiomers of the natural radicamines A and B, respectively.",

author = "Yu, \{Chu Yi\} and Huang, \{Mu Hua\}",

year = "2006",

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doi = "10.1021/ol0609210",

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T1 - Radicamines A and B

T2 - Synthesis and revision of the absolute configuration

AU - Yu, Chu Yi

AU - Huang, Mu Hua

PY - 2006/7/6

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N2 - Starting from D-xylose, enantioselective syntheses of 1 and 2, the proposed structures for radicamines A and B, were accomplished. Both 1H and 13C NMR spectra of 1 and 2 were identical with those of the natural products, but the optical rotation measurements identified that 1 and 2 were actually the enantiomers of the natural radicamines A and B, respectively.

AB - Starting from D-xylose, enantioselective syntheses of 1 and 2, the proposed structures for radicamines A and B, were accomplished. Both 1H and 13C NMR spectra of 1 and 2 were identical with those of the natural products, but the optical rotation measurements identified that 1 and 2 were actually the enantiomers of the natural radicamines A and B, respectively.

UR - https://www.scopus.com/pages/publications/33746622502

U2 - 10.1021/ol0609210

DO - 10.1021/ol0609210

M3 - Article

C2 - 16805542

AN - SCOPUS:33746622502

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VL - 8

SP - 3021

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JO - Organic Letters

JF - Organic Letters

IS - 14

ER -

Radicamines A and B: Synthesis and revision of the absolute configuration

Abstract

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