Properties of glycidyl azide polymer/polyethylene glycol dual-soft segments energetic polyurethane elastomer

Xupeng Wang; Yunjun Luo; Xiaoqing Wang; Zhen Ge

Properties of glycidyl azide polymer/polyethylene glycol dual-soft segments energetic polyurethane elastomer

Xupeng Wang, Yunjun Luo^*, Xiaoqing Wang, Zhen Ge

^*Corresponding author for this work

School of Materials Science & Engineering, Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

To improve the performance of glycidyl azide polymer(GAP), trimethylolpropane(TMP) as the crosslinker, isophorone diisocyanate(IPDI) as the curing agent, glycidyl azide polymer/polyethylene glycol(PEG) dual-soft segments energetic polyurethane elastomer was synthesized. The elastomer was characterized with Fourier transform infrared spectrum(FT-IR), differential scanning calorimetry(DSC) and other means. The experimental results show that: When PEG is introduced into the elastomer, tensile strength of elastomer increases 168%, extension rate of elastomer increases 77%. Due to molecular weight of PEG soft segment is low, elastomer showes T_g of GAP soft segment only, with the content of crosslinker increasing, T_g of GAP soft segment raises from -36.85°C to -34.81°C and then drops to -40.31°C. The thermal decomposition behavior of elastomer can be divided into two sections, and the initial decomposition temperature is 183°C.

Original language	English
Pages (from-to)	77-79
Number of pages	3
Journal	Gaofenzi Cailiao Kexue Yu Gongcheng/Polymeric Materials Science and Engineering
Volume	27
Issue number	1
Publication status	Published - Jan 2011
Externally published	Yes

Keywords

Copolymerization
Glycidyl azide polymer
Polyurethane
Thermal properties

Cite this

@article{8ff76aa9fab34441a79e7f161f509d72,

title = "Properties of glycidyl azide polymer/polyethylene glycol dual-soft segments energetic polyurethane elastomer",

abstract = "To improve the performance of glycidyl azide polymer(GAP), trimethylolpropane(TMP) as the crosslinker, isophorone diisocyanate(IPDI) as the curing agent, glycidyl azide polymer/polyethylene glycol(PEG) dual-soft segments energetic polyurethane elastomer was synthesized. The elastomer was characterized with Fourier transform infrared spectrum(FT-IR), differential scanning calorimetry(DSC) and other means. The experimental results show that: When PEG is introduced into the elastomer, tensile strength of elastomer increases 168\%, extension rate of elastomer increases 77\%. Due to molecular weight of PEG soft segment is low, elastomer showes Tg of GAP soft segment only, with the content of crosslinker increasing, Tg of GAP soft segment raises from -36.85°C to -34.81°C and then drops to -40.31°C. The thermal decomposition behavior of elastomer can be divided into two sections, and the initial decomposition temperature is 183°C.",

keywords = "Copolymerization, Glycidyl azide polymer, Polyurethane, Thermal properties",

author = "Xupeng Wang and Yunjun Luo and Xiaoqing Wang and Zhen Ge",

year = "2011",

month = jan,

language = "English",

volume = "27",

pages = "77--79",

journal = "Gaofenzi Cailiao Kexue Yu Gongcheng/Polymeric Materials Science and Engineering",

issn = "1000-7555",

publisher = "Chengdu University of Science and Technology",

number = "1",

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TY - JOUR

T1 - Properties of glycidyl azide polymer/polyethylene glycol dual-soft segments energetic polyurethane elastomer

AU - Wang, Xupeng

AU - Luo, Yunjun

AU - Wang, Xiaoqing

AU - Ge, Zhen

PY - 2011/1

Y1 - 2011/1

N2 - To improve the performance of glycidyl azide polymer(GAP), trimethylolpropane(TMP) as the crosslinker, isophorone diisocyanate(IPDI) as the curing agent, glycidyl azide polymer/polyethylene glycol(PEG) dual-soft segments energetic polyurethane elastomer was synthesized. The elastomer was characterized with Fourier transform infrared spectrum(FT-IR), differential scanning calorimetry(DSC) and other means. The experimental results show that: When PEG is introduced into the elastomer, tensile strength of elastomer increases 168%, extension rate of elastomer increases 77%. Due to molecular weight of PEG soft segment is low, elastomer showes Tg of GAP soft segment only, with the content of crosslinker increasing, Tg of GAP soft segment raises from -36.85°C to -34.81°C and then drops to -40.31°C. The thermal decomposition behavior of elastomer can be divided into two sections, and the initial decomposition temperature is 183°C.

AB - To improve the performance of glycidyl azide polymer(GAP), trimethylolpropane(TMP) as the crosslinker, isophorone diisocyanate(IPDI) as the curing agent, glycidyl azide polymer/polyethylene glycol(PEG) dual-soft segments energetic polyurethane elastomer was synthesized. The elastomer was characterized with Fourier transform infrared spectrum(FT-IR), differential scanning calorimetry(DSC) and other means. The experimental results show that: When PEG is introduced into the elastomer, tensile strength of elastomer increases 168%, extension rate of elastomer increases 77%. Due to molecular weight of PEG soft segment is low, elastomer showes Tg of GAP soft segment only, with the content of crosslinker increasing, Tg of GAP soft segment raises from -36.85°C to -34.81°C and then drops to -40.31°C. The thermal decomposition behavior of elastomer can be divided into two sections, and the initial decomposition temperature is 183°C.

KW - Copolymerization

KW - Glycidyl azide polymer

KW - Polyurethane

KW - Thermal properties

UR - http://www.scopus.com/inward/record.url?scp=79955075642&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:79955075642

SN - 1000-7555

VL - 27

SP - 77

EP - 79

JO - Gaofenzi Cailiao Kexue Yu Gongcheng/Polymeric Materials Science and Engineering

JF - Gaofenzi Cailiao Kexue Yu Gongcheng/Polymeric Materials Science and Engineering

IS - 1

ER -

Properties of glycidyl azide polymer/polyethylene glycol dual-soft segments energetic polyurethane elastomer

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Keywords

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