Preparation of porous biphasic β -TCP/HA bioceramics witha natural trabecular structure from calcined cancellousbovine bone

Hai Bo Jin; Chao Bang Guo; Ke Ya Mao; Sergey Dorozhkin; Simeon Agathopoulos

doi:10.2109/jcersj2.118.52

Preparation of porous biphasic β -TCP/HA bioceramics witha natural trabecular structure from calcined cancellousbovine bone

Hai Bo Jin^*
, Chao Bang Guo
, Ke Ya Mao
, Sergey Dorozhkin
, Simeon Agathopoulos

^*Corresponding author for this work

School of Material Science and Engineering

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

Porous biphasic β-TCP/HA bioceramics were fabricated by sintering of calcined cancellous bovine bone (CBB) treated with different quantities of NH₄H₂PO₄ at various temperatures. The obtained materials had a porous structure (macropores within 200-800 μm and micropores within 1-5 μm) of natural trabecular bones. The specimens were characterized by X-ray diffraction, scanning electron microscopy (SEM), and gravimetric thermal analysis (TG). The results revealed that porous biphasic β-TCP/HA bioceramics were successfully prepared at sintering temperatures within 762°C-829°C. Biological apatite of calcined CBB was found to transform partly into Ca₂P₂O₇ at heating temperatures between 503°C and 762°C. As the ratio NH₄H₂PO ₄/calcined-CBB increased, bioceramics with different phase compositions of β-TCP/HA, β-TCP/HA/Ca₂P₂O ₇ or β-TCP/Ca₂P₂O₇ were produced after sintering.

Original language	English
Pages (from-to)	52-56
Number of pages	5
Journal	Journal of the Ceramic Society of Japan
Volume	118
Issue number	1373
DOIs	https://doi.org/10.2109/jcersj2.118.52
Publication status	Published - Jan 2010

Keywords

Bioceramics
Biphasic calcium phosphate
Calcined cancellous bovine bone
Hydroxyapatite
β-TCP

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10.2109/jcersj2.118.52

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@article{16b23ed3de094f67a3d53c5735b411e5,

title = "Preparation of porous biphasic β -TCP/HA bioceramics witha natural trabecular structure from calcined cancellousbovine bone",

abstract = "Porous biphasic β-TCP/HA bioceramics were fabricated by sintering of calcined cancellous bovine bone (CBB) treated with different quantities of NH4H2PO4 at various temperatures. The obtained materials had a porous structure (macropores within 200-800 μm and micropores within 1-5 μm) of natural trabecular bones. The specimens were characterized by X-ray diffraction, scanning electron microscopy (SEM), and gravimetric thermal analysis (TG). The results revealed that porous biphasic β-TCP/HA bioceramics were successfully prepared at sintering temperatures within 762°C-829°C. Biological apatite of calcined CBB was found to transform partly into Ca2P2O7 at heating temperatures between 503°C and 762°C. As the ratio NH4H2PO 4/calcined-CBB increased, bioceramics with different phase compositions of β-TCP/HA, β-TCP/HA/Ca2P2O 7 or β-TCP/Ca2P2O7 were produced after sintering.",

keywords = "Bioceramics, Biphasic calcium phosphate, Calcined cancellous bovine bone, Hydroxyapatite, β-TCP",

author = "Jin, \{Hai Bo\} and Guo, \{Chao Bang\} and Mao, \{Ke Ya\} and Sergey Dorozhkin and Simeon Agathopoulos",

year = "2010",

month = jan,

doi = "10.2109/jcersj2.118.52",

language = "English",

volume = "118",

pages = "52--56",

journal = "Journal of the Ceramic Society of Japan",

issn = "1882-0743",

publisher = "Ceramic Society of Japan",

number = "1373",

}

TY - JOUR

T1 - Preparation of porous biphasic β -TCP/HA bioceramics witha natural trabecular structure from calcined cancellousbovine bone

AU - Jin, Hai Bo

AU - Guo, Chao Bang

AU - Mao, Ke Ya

AU - Dorozhkin, Sergey

AU - Agathopoulos, Simeon

PY - 2010/1

Y1 - 2010/1

N2 - Porous biphasic β-TCP/HA bioceramics were fabricated by sintering of calcined cancellous bovine bone (CBB) treated with different quantities of NH4H2PO4 at various temperatures. The obtained materials had a porous structure (macropores within 200-800 μm and micropores within 1-5 μm) of natural trabecular bones. The specimens were characterized by X-ray diffraction, scanning electron microscopy (SEM), and gravimetric thermal analysis (TG). The results revealed that porous biphasic β-TCP/HA bioceramics were successfully prepared at sintering temperatures within 762°C-829°C. Biological apatite of calcined CBB was found to transform partly into Ca2P2O7 at heating temperatures between 503°C and 762°C. As the ratio NH4H2PO 4/calcined-CBB increased, bioceramics with different phase compositions of β-TCP/HA, β-TCP/HA/Ca2P2O 7 or β-TCP/Ca2P2O7 were produced after sintering.

AB - Porous biphasic β-TCP/HA bioceramics were fabricated by sintering of calcined cancellous bovine bone (CBB) treated with different quantities of NH4H2PO4 at various temperatures. The obtained materials had a porous structure (macropores within 200-800 μm and micropores within 1-5 μm) of natural trabecular bones. The specimens were characterized by X-ray diffraction, scanning electron microscopy (SEM), and gravimetric thermal analysis (TG). The results revealed that porous biphasic β-TCP/HA bioceramics were successfully prepared at sintering temperatures within 762°C-829°C. Biological apatite of calcined CBB was found to transform partly into Ca2P2O7 at heating temperatures between 503°C and 762°C. As the ratio NH4H2PO 4/calcined-CBB increased, bioceramics with different phase compositions of β-TCP/HA, β-TCP/HA/Ca2P2O 7 or β-TCP/Ca2P2O7 were produced after sintering.

KW - Bioceramics

KW - Biphasic calcium phosphate

KW - Calcined cancellous bovine bone

KW - Hydroxyapatite

KW - β-TCP

UR - https://www.scopus.com/pages/publications/75749117097

U2 - 10.2109/jcersj2.118.52

DO - 10.2109/jcersj2.118.52

M3 - Article

AN - SCOPUS:75749117097

SN - 1882-0743

VL - 118

SP - 52

EP - 56

JO - Journal of the Ceramic Society of Japan

JF - Journal of the Ceramic Society of Japan

IS - 1373

ER -

Preparation of porous biphasic β -TCP/HA bioceramics witha natural trabecular structure from calcined cancellousbovine bone

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Keywords

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