Preparation of nitrogen-rich carbon nitrides from 4,4',6,6'-tetra (azido)azo-1,3,5-triazine as precursor by pyrolysis

Qiao Li Ma; Yi Yu; Xue Jiao Zhang; Si Ping Pang

Preparation of nitrogen-rich carbon nitrides from 4,4',6,6'-tetra (azido)azo-1,3,5-triazine as precursor by pyrolysis

Qiao Li Ma
, Yi Yu
, Xue Jiao Zhang
, Si Ping Pang^*

^*Corresponding author for this work

School of Material Science and Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

4,4',6,6'-Tetra(azido)azo-1,3,5-triazine(TAAT) was synthesized by an improved synthesis method with the yield of 82.1%. DSC, IR, NMR, elemental analysis as well as crystal structure diffraction were used to characterize the TAAT and intermediate products. C ₂N ₃ and C ₃N ₅ whose N/C ratios highly resembled the theoretical peers were prepared by pyrolysis from TAAT. The mechanisms for TAAT pyrolysis and C ₂N ₃/C ₃N ₅ generation were discussed.

Original language	English
Pages (from-to)	46-51
Number of pages	6
Journal	Huozhayao Xuebao/Chinese Journal of Explosives and Propellants
Volume	35
Issue number	1
Publication status	Published - Feb 2012

Keywords

4,4',6,6'-tetra(azido)azo-1,3, 5-triazine(TAAT)
Carbon nitrides
Material science
Pyrolysis
Synthesis

Cite this

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title = "Preparation of nitrogen-rich carbon nitrides from 4,4',6,6'-tetra (azido)azo-1,3,5-triazine as precursor by pyrolysis",

abstract = "4,4',6,6'-Tetra(azido)azo-1,3,5-triazine(TAAT) was synthesized by an improved synthesis method with the yield of 82.1\%. DSC, IR, NMR, elemental analysis as well as crystal structure diffraction were used to characterize the TAAT and intermediate products. C 2N 3 and C 3N 5 whose N/C ratios highly resembled the theoretical peers were prepared by pyrolysis from TAAT. The mechanisms for TAAT pyrolysis and C 2N 3/C 3N 5 generation were discussed.",

keywords = "4,4',6,6'-tetra(azido)azo-1,3, 5-triazine(TAAT), Carbon nitrides, Material science, Pyrolysis, Synthesis",

author = "Ma, \{Qiao Li\} and Yi Yu and Zhang, \{Xue Jiao\} and Pang, \{Si Ping\}",

year = "2012",

month = feb,

language = "English",

volume = "35",

pages = "46--51",

journal = "Huozhayao Xuebao/Chinese Journal of Explosives and Propellants",

issn = "1007-7812",

publisher = "China Ordnance Industry Corporation",

number = "1",

}

TY - JOUR

T1 - Preparation of nitrogen-rich carbon nitrides from 4,4',6,6'-tetra (azido)azo-1,3,5-triazine as precursor by pyrolysis

AU - Ma, Qiao Li

AU - Yu, Yi

AU - Zhang, Xue Jiao

AU - Pang, Si Ping

PY - 2012/2

Y1 - 2012/2

N2 - 4,4',6,6'-Tetra(azido)azo-1,3,5-triazine(TAAT) was synthesized by an improved synthesis method with the yield of 82.1%. DSC, IR, NMR, elemental analysis as well as crystal structure diffraction were used to characterize the TAAT and intermediate products. C 2N 3 and C 3N 5 whose N/C ratios highly resembled the theoretical peers were prepared by pyrolysis from TAAT. The mechanisms for TAAT pyrolysis and C 2N 3/C 3N 5 generation were discussed.

AB - 4,4',6,6'-Tetra(azido)azo-1,3,5-triazine(TAAT) was synthesized by an improved synthesis method with the yield of 82.1%. DSC, IR, NMR, elemental analysis as well as crystal structure diffraction were used to characterize the TAAT and intermediate products. C 2N 3 and C 3N 5 whose N/C ratios highly resembled the theoretical peers were prepared by pyrolysis from TAAT. The mechanisms for TAAT pyrolysis and C 2N 3/C 3N 5 generation were discussed.

KW - 4,4',6,6'-tetra(azido)azo-1,3, 5-triazine(TAAT)

KW - Carbon nitrides

KW - Material science

KW - Pyrolysis

KW - Synthesis

UR - https://www.scopus.com/pages/publications/84860128837

M3 - Article

AN - SCOPUS:84860128837

SN - 1007-7812

VL - 35

SP - 46

EP - 51

JO - Huozhayao Xuebao/Chinese Journal of Explosives and Propellants

JF - Huozhayao Xuebao/Chinese Journal of Explosives and Propellants

IS - 1

ER -

Preparation of nitrogen-rich carbon nitrides from 4,4',6,6'-tetra (azido)azo-1,3,5-triazine as precursor by pyrolysis

Abstract

Keywords

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