Preparation, characterization of (La0.9Ca0.1)(Cr0.9Mg0.1)O3 high emissivity coatings deposited by APS

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Abstract

Solid state synthesis was employed to prepare ceramic powders. The (La0.9Ca0.1)(Cr0.9Mg0.1)O3 coatings were deposited by APS equipment on GH98 Super-alloy substrate. The Mg and Ca atoms entered the lattice of LaCrO3 crystal to form (La0.9Ca0.1)(Cr0.1Mg0.1)O3 but did not change the orthorhombic perovskite structure. The coatings are composed of splats, pores and micro cracks. The average porosity of (La0.9Ca0.1)(Cr0.9Mg0.1)O3 coating is 12.4% and the average bond strength is 28.3Mpa.The (La0.9Ca0.1)(Cr0.9Mg0.1)O3 powders did not occur phase transition during heated process in high temperature plasma plume. No impurity is introduced in the coating during plasma spraying process. Due to the significant distortion of (La0.9Ca0.1)(Cr0.9Mg0.1)O3 lattice, the normal total emissivity of (La0.9Ca0.1)(Cr0.9Mg0.1)O3 coatings are 0.88 at 600°C and 0.89 at 800°C. The crystal structure is stable in the temperature range of thermal shock test from room temperature to 1100BC. And no spalling or fracture occurred within 10 times thermal shock which means the coatings could withstand the impact of thermal stress.

Original languageEnglish
Title of host publicationInternational Thermal Spray Conference and Exposition, ITSC 2016
PublisherASM International
Pages1120-1131
Number of pages12
ISBN (Electronic)9781510844001
Publication statusPublished - 2016
EventInternational Thermal Spray Conference and Exposition, ITSC 2016 - Shanghai, China
Duration: 10 May 201612 May 2016

Publication series

NameProceedings of the International Thermal Spray Conference
Volume2

Conference

ConferenceInternational Thermal Spray Conference and Exposition, ITSC 2016
Country/TerritoryChina
CityShanghai
Period10/05/1612/05/16

Keywords

  • High emissivity coatings
  • Plasma spraying
  • The normal total emissivity
  • Thermal-shock resistance

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