Preparation and performances research of two kinds of polymerizable quaternary ammonium salt

Yu Chen; Huan Lin Tang; Yun Fei Liu; Hai Peng Yu; Yi Xing Liu; Hui Min Tan

Preparation and performances research of two kinds of polymerizable quaternary ammonium salt

Yu Chen^*, Huan Lin Tang, Yun Fei Liu, Hai Peng Yu, Yi Xing Liu, Hui Min Tan

^*Corresponding author for this work

School of Material Science and Engineering

Research output: Contribution to journal › Article › peer-review

Abstract

Two kinds of polymerizable vinyl quaternary ammonium salt, namely dimethyldiallyl ammonium chloride-and trimethyldiallyl ammonium chloride respectively, were prepared via the SN₂ nucleophilic substitution of the allyl chloride with the tertiary amine. The structure of the prepared quaternary ammonium salts were characterized through the methods of element analysis, FTIR, H¹-NMR and C¹³-NMR. Two kinds of polyampholytic superabsorbent polymer, which include CMCTS-g-(PAA-co-PDMDAAC) and CMCTS-g-(PAA-co-TMAAC) respectively, were prepared through graft copolymerization of prepared vinyl quaternary ammonium salt and acrylic acid onto the chain of carboxymethyl chitosan, initiated with persulfate and crosslinked properly. The structure of the superbasorbent polymer was characterized by FTIR. Influence of the pH value of the solution on the swelling ratio of the polyampholytic superabsorbent polymer was studied.

Original language	English
Pages (from-to)	42-45
Number of pages	4
Journal	Shiyou Huagong Gaodeng Xuexiao Xuebao/Journal of Petrochemical Universities
Volume	21
Issue number	1
Publication status	Published - Mar 2008

Keywords

Polyampholytic
Superabsorbent polymer
Vinyl quaternary ammonium salt

Cite this

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title = "Preparation and performances research of two kinds of polymerizable quaternary ammonium salt",

abstract = "Two kinds of polymerizable vinyl quaternary ammonium salt, namely dimethyldiallyl ammonium chloride-and trimethyldiallyl ammonium chloride respectively, were prepared via the SN2 nucleophilic substitution of the allyl chloride with the tertiary amine. The structure of the prepared quaternary ammonium salts were characterized through the methods of element analysis, FTIR, H1-NMR and C13-NMR. Two kinds of polyampholytic superabsorbent polymer, which include CMCTS-g-(PAA-co-PDMDAAC) and CMCTS-g-(PAA-co-TMAAC) respectively, were prepared through graft copolymerization of prepared vinyl quaternary ammonium salt and acrylic acid onto the chain of carboxymethyl chitosan, initiated with persulfate and crosslinked properly. The structure of the superbasorbent polymer was characterized by FTIR. Influence of the pH value of the solution on the swelling ratio of the polyampholytic superabsorbent polymer was studied.",

keywords = "Polyampholytic, Superabsorbent polymer, Vinyl quaternary ammonium salt",

author = "Yu Chen and Tang, {Huan Lin} and Liu, {Yun Fei} and Yu, {Hai Peng} and Liu, {Yi Xing} and Tan, {Hui Min}",

year = "2008",

month = mar,

language = "English",

volume = "21",

pages = "42--45",

journal = "Shiyou Huagong Gaodeng Xuexiao Xuebao/Journal of Petrochemical Universities",

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T1 - Preparation and performances research of two kinds of polymerizable quaternary ammonium salt

AU - Chen, Yu

AU - Tang, Huan Lin

AU - Liu, Yun Fei

AU - Yu, Hai Peng

AU - Liu, Yi Xing

AU - Tan, Hui Min

PY - 2008/3

Y1 - 2008/3

N2 - Two kinds of polymerizable vinyl quaternary ammonium salt, namely dimethyldiallyl ammonium chloride-and trimethyldiallyl ammonium chloride respectively, were prepared via the SN2 nucleophilic substitution of the allyl chloride with the tertiary amine. The structure of the prepared quaternary ammonium salts were characterized through the methods of element analysis, FTIR, H1-NMR and C13-NMR. Two kinds of polyampholytic superabsorbent polymer, which include CMCTS-g-(PAA-co-PDMDAAC) and CMCTS-g-(PAA-co-TMAAC) respectively, were prepared through graft copolymerization of prepared vinyl quaternary ammonium salt and acrylic acid onto the chain of carboxymethyl chitosan, initiated with persulfate and crosslinked properly. The structure of the superbasorbent polymer was characterized by FTIR. Influence of the pH value of the solution on the swelling ratio of the polyampholytic superabsorbent polymer was studied.

AB - Two kinds of polymerizable vinyl quaternary ammonium salt, namely dimethyldiallyl ammonium chloride-and trimethyldiallyl ammonium chloride respectively, were prepared via the SN2 nucleophilic substitution of the allyl chloride with the tertiary amine. The structure of the prepared quaternary ammonium salts were characterized through the methods of element analysis, FTIR, H1-NMR and C13-NMR. Two kinds of polyampholytic superabsorbent polymer, which include CMCTS-g-(PAA-co-PDMDAAC) and CMCTS-g-(PAA-co-TMAAC) respectively, were prepared through graft copolymerization of prepared vinyl quaternary ammonium salt and acrylic acid onto the chain of carboxymethyl chitosan, initiated with persulfate and crosslinked properly. The structure of the superbasorbent polymer was characterized by FTIR. Influence of the pH value of the solution on the swelling ratio of the polyampholytic superabsorbent polymer was studied.

KW - Polyampholytic

KW - Superabsorbent polymer

KW - Vinyl quaternary ammonium salt

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M3 - Article

AN - SCOPUS:41349102190

SN - 1006-396X

VL - 21

SP - 42

EP - 45

JO - Shiyou Huagong Gaodeng Xuexiao Xuebao/Journal of Petrochemical Universities

JF - Shiyou Huagong Gaodeng Xuexiao Xuebao/Journal of Petrochemical Universities

IS - 1

ER -

Preparation and performances research of two kinds of polymerizable quaternary ammonium salt

Abstract

Keywords

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