TY - JOUR
T1 - Potassium 4,5-Bis(dinitromethyl)furoxanate
T2 - A Green Primary Explosive with a Positive Oxygen Balance
AU - He, Chunlin
AU - Shreeve, Jean'ne M.
N1 - Publisher Copyright:
© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
PY - 2016/1/11
Y1 - 2016/1/11
N2 - Potassium 4,5-bis(dinitromethyl)furoxanate was synthesized readily from cyanoacetic acid. It was characterized by IR spectroscopy, elemental analysis, NMR spectroscopy, and differential scanning calorimetry (DSC), and the structure was confirmed by X-ray single-crystal diffraction. Its positive oxygen balance, high density (2.130 g cm-3), sensitivity (IS=2 J, FS=5 N), and calculated heat of formation (-421.0 kJ mol-1), combined with its calculated superior detonation performance (D=7759.0 m s-1, P=27.3 GPa), make it a competitive replacement as a green primary explosive.
AB - Potassium 4,5-bis(dinitromethyl)furoxanate was synthesized readily from cyanoacetic acid. It was characterized by IR spectroscopy, elemental analysis, NMR spectroscopy, and differential scanning calorimetry (DSC), and the structure was confirmed by X-ray single-crystal diffraction. Its positive oxygen balance, high density (2.130 g cm-3), sensitivity (IS=2 J, FS=5 N), and calculated heat of formation (-421.0 kJ mol-1), combined with its calculated superior detonation performance (D=7759.0 m s-1, P=27.3 GPa), make it a competitive replacement as a green primary explosive.
KW - energetic materials
KW - furoxans
KW - heterocycles
KW - oxygen balance
KW - primary explosives
UR - http://www.scopus.com/inward/record.url?scp=84958771402&partnerID=8YFLogxK
U2 - 10.1002/anie.201509209
DO - 10.1002/anie.201509209
M3 - Article
C2 - 26545957
AN - SCOPUS:84958771402
SN - 1433-7851
VL - 55
SP - 772
EP - 775
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 2
ER -