Poly(polyoxotungstate)s with 20 nickel centers: From nanoclusters to one-dimensional chains

Shou Tian Zheng; Jie Zhang; Juan Modesto Clemente-Juan; Da Qiang Yuan; Guoyu Yang

doi:10.1002/anie.200901653

Poly(polyoxotungstate)s with 20 nickel centers: From nanoclusters to one-dimensional chains

Shou Tian Zheng
, Jie Zhang
, Juan Modesto Clemente-Juan
, Da Qiang Yuan
, Guoyu Yang

School of Chemistry and Chemical Engineering

CAS - Fujian Institute of Research on the Structure of Matter
University of Valencia

Research output: Contribution to journal › Article › peer-review

210 Citations (Scopus)

Abstract

Line them up: Under hydrothermal conditions, trilacunary Keggin {B-α-PW₉O₃₄} fragments and nickel ions form the two largest Ni-substituted poly(polyoxotungstate)s with the greatest number of Ni ions in a known polyoxometalate. Bridging amine ligands connect the fragments to form the 1D structure of the polyoxometalates (see structure; red octahedra WO₆, yellow tetrahedra PO₄, green Ni, red O, blue N, gray C).

Original language	English
Pages (from-to)	7176-7179
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	48
Issue number	39
DOIs	https://doi.org/10.1002/anie.200901653
Publication status	Published - 14 Sept 2009

Keywords

Lacunary structures
Nickel
Polyoxometalates
Substitution

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10.1002/anie.200901653

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abstract = "Line them up: Under hydrothermal conditions, trilacunary Keggin \{B-α-PW9O34\} fragments and nickel ions form the two largest Ni-substituted poly(polyoxotungstate)s with the greatest number of Ni ions in a known polyoxometalate. Bridging amine ligands connect the fragments to form the 1D structure of the polyoxometalates (see structure; red octahedra WO6, yellow tetrahedra PO4, green Ni, red O, blue N, gray C).",

keywords = "Lacunary structures, Nickel, Polyoxometalates, Substitution",

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T1 - Poly(polyoxotungstate)s with 20 nickel centers

T2 - From nanoclusters to one-dimensional chains

AU - Zheng, Shou Tian

AU - Zhang, Jie

AU - Clemente-Juan, Juan Modesto

AU - Yuan, Da Qiang

AU - Yang, Guoyu

PY - 2009/9/14

Y1 - 2009/9/14

N2 - Line them up: Under hydrothermal conditions, trilacunary Keggin {B-α-PW9O34} fragments and nickel ions form the two largest Ni-substituted poly(polyoxotungstate)s with the greatest number of Ni ions in a known polyoxometalate. Bridging amine ligands connect the fragments to form the 1D structure of the polyoxometalates (see structure; red octahedra WO6, yellow tetrahedra PO4, green Ni, red O, blue N, gray C).

AB - Line them up: Under hydrothermal conditions, trilacunary Keggin {B-α-PW9O34} fragments and nickel ions form the two largest Ni-substituted poly(polyoxotungstate)s with the greatest number of Ni ions in a known polyoxometalate. Bridging amine ligands connect the fragments to form the 1D structure of the polyoxometalates (see structure; red octahedra WO6, yellow tetrahedra PO4, green Ni, red O, blue N, gray C).

KW - Lacunary structures

KW - Nickel

KW - Polyoxometalates

KW - Substitution

UR - https://www.scopus.com/pages/publications/70349928965

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 39

ER -

Poly(polyoxotungstate)s with 20 nickel centers: From nanoclusters to one-dimensional chains

Abstract

Keywords

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