Poly(polyoxometalate)s assembled by (Ni6PW9) units: From ring-shaped Ni24-tetramers to rod-shaped Ni40-octamers

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Abstract

Both structure-directing effect and synergistic-directing effect of PW9O34 fragments result in two poly(polyoxotungstate)s (poly(POT)s) of the Ni24-based tetramer with largest transition metal atoms among ring-shaped poly(POT) tetramers and the Ni40-based poly(POT) octamer with the highest number of Ni ions among all known poly(POT)s to date, respectively.

Original languageEnglish
Pages (from-to)9658-9660
Number of pages3
JournalChemical Communications
Volume48
Issue number77
DOIs
Publication statusPublished - 29 Aug 2012

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