Polyphosphazene-based copolymers containing pendant alkylsulfonic acid groups as proton exchange membranes

Fengyan Fu; Hulin Xu; Yan Dong; Minlan He; Tianwei Luo; Yanxia Zhang; Xin Hao; Tao Ma; Changjin Zhu

doi:10.1016/j.ssi.2015.05.018

Polyphosphazene-based copolymers containing pendant alkylsulfonic acid groups as proton exchange membranes

Fengyan Fu
, Hulin Xu
, Yan Dong
, Minlan He
, Tianwei Luo
, Yanxia Zhang
, Xin Hao
, Tao Ma
, Changjin Zhu^*

^*Corresponding author for this work

School of Mathematics and Statistics

Research output: Contribution to journal › Article › peer-review

21 Citations (Scopus)

Abstract

Abstract A series of polyphosphazene-based copolymers containing alkylsulfonated side chains were prepared and made into the corresponding membranes by the reaction with 2,6-bis(hydroxymethyl)-4-methylphenol (BHMP) as the cross-linking reagent. All the cross-linked membranes showed lower water uptake and dimensional swelling. They displayed significant methanol resistance ranging from 1.35 to 7.18 × 10^-7 cm²/s and high oxidative stabilities. The individual membrane PFMPP₁-r-PFSPP₉ showed good proton conductivity (0.14 S/cm) under fully hydrated conditions at 80 °C.

Original language	English
Article number	13675
Pages (from-to)	58-64
Number of pages	7
Journal	Solid State Ionics
Volume	278
DOIs	https://doi.org/10.1016/j.ssi.2015.05.018
Publication status	Published - 11 Jun 2015

Keywords

Cross-linked
Methanol permeability
Polyphosphazene copolymer
Proton conductivity
Proton exchange membrane

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10.1016/j.ssi.2015.05.018

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@article{83e29e1b20d042eaa8ed04d709fbb102,

title = "Polyphosphazene-based copolymers containing pendant alkylsulfonic acid groups as proton exchange membranes",

abstract = "Abstract A series of polyphosphazene-based copolymers containing alkylsulfonated side chains were prepared and made into the corresponding membranes by the reaction with 2,6-bis(hydroxymethyl)-4-methylphenol (BHMP) as the cross-linking reagent. All the cross-linked membranes showed lower water uptake and dimensional swelling. They displayed significant methanol resistance ranging from 1.35 to 7.18 × 10-7 cm2/s and high oxidative stabilities. The individual membrane PFMPP1-r-PFSPP9 showed good proton conductivity (0.14 S/cm) under fully hydrated conditions at 80 °C.",

keywords = "Cross-linked, Methanol permeability, Polyphosphazene copolymer, Proton conductivity, Proton exchange membrane",

author = "Fengyan Fu and Hulin Xu and Yan Dong and Minlan He and Tianwei Luo and Yanxia Zhang and Xin Hao and Tao Ma and Changjin Zhu",

note = "Publisher Copyright: {\textcopyright} 2015 Elsevier B.V.",

year = "2015",

month = jun,

day = "11",

doi = "10.1016/j.ssi.2015.05.018",

language = "English",

volume = "278",

pages = "58--64",

journal = "Solid State Ionics",

issn = "0167-2738",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Polyphosphazene-based copolymers containing pendant alkylsulfonic acid groups as proton exchange membranes

AU - Fu, Fengyan

AU - Xu, Hulin

AU - Dong, Yan

AU - He, Minlan

AU - Luo, Tianwei

AU - Zhang, Yanxia

AU - Hao, Xin

AU - Ma, Tao

AU - Zhu, Changjin

PY - 2015/6/11

Y1 - 2015/6/11

N2 - Abstract A series of polyphosphazene-based copolymers containing alkylsulfonated side chains were prepared and made into the corresponding membranes by the reaction with 2,6-bis(hydroxymethyl)-4-methylphenol (BHMP) as the cross-linking reagent. All the cross-linked membranes showed lower water uptake and dimensional swelling. They displayed significant methanol resistance ranging from 1.35 to 7.18 × 10-7 cm2/s and high oxidative stabilities. The individual membrane PFMPP1-r-PFSPP9 showed good proton conductivity (0.14 S/cm) under fully hydrated conditions at 80 °C.

AB - Abstract A series of polyphosphazene-based copolymers containing alkylsulfonated side chains were prepared and made into the corresponding membranes by the reaction with 2,6-bis(hydroxymethyl)-4-methylphenol (BHMP) as the cross-linking reagent. All the cross-linked membranes showed lower water uptake and dimensional swelling. They displayed significant methanol resistance ranging from 1.35 to 7.18 × 10-7 cm2/s and high oxidative stabilities. The individual membrane PFMPP1-r-PFSPP9 showed good proton conductivity (0.14 S/cm) under fully hydrated conditions at 80 °C.

KW - Cross-linked

KW - Methanol permeability

KW - Polyphosphazene copolymer

KW - Proton conductivity

KW - Proton exchange membrane

UR - https://www.scopus.com/pages/publications/84930939630

U2 - 10.1016/j.ssi.2015.05.018

DO - 10.1016/j.ssi.2015.05.018

M3 - Article

AN - SCOPUS:84930939630

SN - 0167-2738

VL - 278

SP - 58

EP - 64

JO - Solid State Ionics

JF - Solid State Ionics

M1 - 13675

ER -

Polyphosphazene-based copolymers containing pendant alkylsulfonic acid groups as proton exchange membranes

Abstract

Keywords

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