Poly[[μ-2-amino-4-(2-pyridyl)-6-(4-pyridyl)pyrimidine-k3 N,N′:N′′]di-μ-bromido-dicopper(I)]

Ying Nan Chi; Feng Yun Cui; Chang Wen Hu

doi:10.1107/S1600536807015127

Poly[[μ-2-amino-4-(2-pyridyl)-6-(4-pyridyl)pyrimidine-k³ N,N′:N′′]di-μ-bromido-dicopper(I)]

Ying Nan Chi, Feng Yun Cui, Chang Wen Hu^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

Abstract

In the title complex, [Cu2Br2(C14H11N5)] n , there are two crystallographically independent Cu^I cations with different coordination geometries: one has tetra-hedral geometry (CuBr2N2), and the other adopts a trigonal geometry (CuBr2N). The 2-amino-4-(2-pyrid-yl)-6-(4-pyrid-yl) pyrimidine (appm) ligand acts as a bridging ligand. Four Br^- anions connect four Cu^I cations to form an eight-membered ring, and the appm ligands link adjacent eight-membered rings to construct a one-dimensional ribbon chain.

Original language	English
Pages (from-to)	m1830-m1831
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	63
Issue number	7
DOIs	https://doi.org/10.1107/S1600536807015127
Publication status	Published - 6 Jun 2007

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title = "Poly[[μ-2-amino-4-(2-pyridyl)-6-(4-pyridyl)pyrimidine-k3 N,N′:N′′]di-μ-bromido-dicopper(I)]",

abstract = "In the title complex, [Cu2Br2(C14H11N5)] n , there are two crystallographically independent CuI cations with different coordination geometries: one has tetra-hedral geometry (CuBr2N2), and the other adopts a trigonal geometry (CuBr2N). The 2-amino-4-(2-pyrid-yl)-6-(4-pyrid-yl) pyrimidine (appm) ligand acts as a bridging ligand. Four Br- anions connect four CuI cations to form an eight-membered ring, and the appm ligands link adjacent eight-membered rings to construct a one-dimensional ribbon chain.",

author = "Chi, {Ying Nan} and Cui, {Feng Yun} and Hu, {Chang Wen}",

year = "2007",

month = jun,

day = "6",

doi = "10.1107/S1600536807015127",

language = "English",

volume = "63",

pages = "m1830--m1831",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

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T1 - Poly[[μ-2-amino-4-(2-pyridyl)-6-(4-pyridyl)pyrimidine-k3 N,N′:N′′]di-μ-bromido-dicopper(I)]

AU - Chi, Ying Nan

AU - Cui, Feng Yun

AU - Hu, Chang Wen

PY - 2007/6/6

Y1 - 2007/6/6

N2 - In the title complex, [Cu2Br2(C14H11N5)] n , there are two crystallographically independent CuI cations with different coordination geometries: one has tetra-hedral geometry (CuBr2N2), and the other adopts a trigonal geometry (CuBr2N). The 2-amino-4-(2-pyrid-yl)-6-(4-pyrid-yl) pyrimidine (appm) ligand acts as a bridging ligand. Four Br- anions connect four CuI cations to form an eight-membered ring, and the appm ligands link adjacent eight-membered rings to construct a one-dimensional ribbon chain.

AB - In the title complex, [Cu2Br2(C14H11N5)] n , there are two crystallographically independent CuI cations with different coordination geometries: one has tetra-hedral geometry (CuBr2N2), and the other adopts a trigonal geometry (CuBr2N). The 2-amino-4-(2-pyrid-yl)-6-(4-pyrid-yl) pyrimidine (appm) ligand acts as a bridging ligand. Four Br- anions connect four CuI cations to form an eight-membered ring, and the appm ligands link adjacent eight-membered rings to construct a one-dimensional ribbon chain.

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DO - 10.1107/S1600536807015127

M3 - Article

AN - SCOPUS:34547143404

SN - 1600-5368

VL - 63

SP - m1830-m1831

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 7

ER -

Poly[[μ-2-amino-4-(2-pyridyl)-6-(4-pyridyl)pyrimidine-k³ N,N′:N′′]di-μ-bromido-dicopper(I)]

Abstract

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