Planar {Ni6} cluster-containing polyoxometalate-based inorganic-organic hybrid compound and its extended structure

Xingquan Wang; Shuxia Liu; Yiwei Liu; Danfeng He; Ning Li; Jun Miao; Yujuan Ji; Guoyu Yang

doi:10.1021/ic502321v

Planar {Ni₆} cluster-containing polyoxometalate-based inorganic-organic hybrid compound and its extended structure

Xingquan Wang
, Shuxia Liu^*
, Yiwei Liu
, Danfeng He
, Ning Li
, Jun Miao
, Yujuan Ji
, Guoyu Yang

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

25 Citations (Scopus)

Abstract

Two {Ni₆} cluster-containing inorganic-organic hybrid compounds have been successfully synthesized in the presence of organic amine under hydrothermal conditions, and they were characterized by powder and single-crystal X-ray diffraction, elemental analysis, thermogravimetric analysis, and IR spectroscopy. Structural analysis indicates that [Ni_0.5(H₂O)₃][{Ni₆(μ₃-OH)₃en(H₂O)₁₀}(H₂P₂W₁₅O₅₆)]·10H₂O (1, en = ethylenediamine) is a triangular inorganic {Ni₆} cluster substituted polyoxotungstate with only one en to stabilize the {Ni₆} cluster. However, [Ni(dap)₂]{[Ni_1.5(dap)_1.5(H₂O)₃][Ni₆(μ₃-OH)₃(dap)₂(en)(H₂O) {O₂C(CH₂)₂CO₂}_0.5(CH₃COO)(P₂W₁₅O₅₆)]}·15H₂O (2, dap = 1,2-diaminopropane) is a three-dimensional inorganic-organic hybrid compound linked by succinic acid. The magnetic properties of both compounds were studied. In addition, the adsorption properties of compound 2 have also been investigated.

Original language	English
Pages (from-to)	13130-13135
Number of pages	6
Journal	Inorganic Chemistry
Volume	53
Issue number	24
DOIs	https://doi.org/10.1021/ic502321v
Publication status	Published - 15 Dec 2014
Externally published	Yes

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@article{e6cdebe7f38e4ce5be5ba33875ef20d2,

title = "Planar \{Ni6\} cluster-containing polyoxometalate-based inorganic-organic hybrid compound and its extended structure",

abstract = "Two \{Ni6\} cluster-containing inorganic-organic hybrid compounds have been successfully synthesized in the presence of organic amine under hydrothermal conditions, and they were characterized by powder and single-crystal X-ray diffraction, elemental analysis, thermogravimetric analysis, and IR spectroscopy. Structural analysis indicates that [Ni0.5(H2O)3][\{Ni6(μ3-OH)3en(H2O)10\}(H2P2W15O56)]·10H2O (1, en = ethylenediamine) is a triangular inorganic \{Ni6\} cluster substituted polyoxotungstate with only one en to stabilize the \{Ni6\} cluster. However, [Ni(dap)2]\{[Ni1.5(dap)1.5(H2O)3][Ni6(μ3-OH)3(dap)2(en)(H2O) \{O2C(CH2)2CO2\}0.5(CH3COO)(P2W15O56)]\}·15H2O (2, dap = 1,2-diaminopropane) is a three-dimensional inorganic-organic hybrid compound linked by succinic acid. The magnetic properties of both compounds were studied. In addition, the adsorption properties of compound 2 have also been investigated.",

author = "Xingquan Wang and Shuxia Liu and Yiwei Liu and Danfeng He and Ning Li and Jun Miao and Yujuan Ji and Guoyu Yang",

note = "Publisher Copyright: {\textcopyright} 2014 American Chemical Society.",

year = "2014",

month = dec,

day = "15",

doi = "10.1021/ic502321v",

language = "English",

volume = "53",

pages = "13130--13135",

journal = "Inorganic Chemistry",

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publisher = "American Chemical Society",

number = "24",

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TY - JOUR

T1 - Planar {Ni6} cluster-containing polyoxometalate-based inorganic-organic hybrid compound and its extended structure

AU - Wang, Xingquan

AU - Liu, Shuxia

AU - Liu, Yiwei

AU - He, Danfeng

AU - Li, Ning

AU - Miao, Jun

AU - Ji, Yujuan

AU - Yang, Guoyu

PY - 2014/12/15

Y1 - 2014/12/15

N2 - Two {Ni6} cluster-containing inorganic-organic hybrid compounds have been successfully synthesized in the presence of organic amine under hydrothermal conditions, and they were characterized by powder and single-crystal X-ray diffraction, elemental analysis, thermogravimetric analysis, and IR spectroscopy. Structural analysis indicates that [Ni0.5(H2O)3][{Ni6(μ3-OH)3en(H2O)10}(H2P2W15O56)]·10H2O (1, en = ethylenediamine) is a triangular inorganic {Ni6} cluster substituted polyoxotungstate with only one en to stabilize the {Ni6} cluster. However, [Ni(dap)2]{[Ni1.5(dap)1.5(H2O)3][Ni6(μ3-OH)3(dap)2(en)(H2O) {O2C(CH2)2CO2}0.5(CH3COO)(P2W15O56)]}·15H2O (2, dap = 1,2-diaminopropane) is a three-dimensional inorganic-organic hybrid compound linked by succinic acid. The magnetic properties of both compounds were studied. In addition, the adsorption properties of compound 2 have also been investigated.

AB - Two {Ni6} cluster-containing inorganic-organic hybrid compounds have been successfully synthesized in the presence of organic amine under hydrothermal conditions, and they were characterized by powder and single-crystal X-ray diffraction, elemental analysis, thermogravimetric analysis, and IR spectroscopy. Structural analysis indicates that [Ni0.5(H2O)3][{Ni6(μ3-OH)3en(H2O)10}(H2P2W15O56)]·10H2O (1, en = ethylenediamine) is a triangular inorganic {Ni6} cluster substituted polyoxotungstate with only one en to stabilize the {Ni6} cluster. However, [Ni(dap)2]{[Ni1.5(dap)1.5(H2O)3][Ni6(μ3-OH)3(dap)2(en)(H2O) {O2C(CH2)2CO2}0.5(CH3COO)(P2W15O56)]}·15H2O (2, dap = 1,2-diaminopropane) is a three-dimensional inorganic-organic hybrid compound linked by succinic acid. The magnetic properties of both compounds were studied. In addition, the adsorption properties of compound 2 have also been investigated.

UR - https://www.scopus.com/pages/publications/84920197345

U2 - 10.1021/ic502321v

DO - 10.1021/ic502321v

M3 - Article

AN - SCOPUS:84920197345

SN - 0020-1669

VL - 53

SP - 13130

EP - 13135

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 24

ER -

Planar {Ni₆} cluster-containing polyoxometalate-based inorganic-organic hybrid compound and its extended structure

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