Piperazinium hexaaquacobalt(II) disulfate

Jian Xin Pan; Guo Yu Yang; Yan Qiong Sun

doi:10.1107/S1600536803008407

Piperazinium hexaaquacobalt(II) disulfate

Jian Xin Pan
, Guo Yu Yang^*
, Yan Qiong Sun

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

26 Citations (Scopus)

Abstract

The crystal structure of the title compound, (C₄H ₁₂N₂)[Co-(H₂O)₆](SO ₄)₂, is built of [Co(H₂O)₆] ²⁺, cations, diprotonated piperazinium cations (each of the two crystallographically independent piperazinium cations occupies a special position on an inversion centre) and sulfate anions. The Co atom is coordinated by six water molecules in a slightly distorted octahedral geometry. The cations are linked to anions by N-H⋯O and O-H⋯O hydrogen bonds, forming an extensive three-dimensional hydrogen-bond network in the crystal structure.

Original language	English
Pages (from-to)	m286-m288
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	59
Issue number	5
DOIs	https://doi.org/10.1107/S1600536803008407
Publication status	Published - May 2003
Externally published	Yes

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title = "Piperazinium hexaaquacobalt(II) disulfate",

abstract = "The crystal structure of the title compound, (C4H 12N2)[Co-(H2O)6](SO 4)2, is built of [Co(H2O)6] 2+, cations, diprotonated piperazinium cations (each of the two crystallographically independent piperazinium cations occupies a special position on an inversion centre) and sulfate anions. The Co atom is coordinated by six water molecules in a slightly distorted octahedral geometry. The cations are linked to anions by N-H⋯O and O-H⋯O hydrogen bonds, forming an extensive three-dimensional hydrogen-bond network in the crystal structure.",

author = "Pan, \{Jian Xin\} and Yang, \{Guo Yu\} and Sun, \{Yan Qiong\}",

year = "2003",

month = may,

doi = "10.1107/S1600536803008407",

language = "English",

volume = "59",

pages = "m286--m288",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "5",

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TY - JOUR

T1 - Piperazinium hexaaquacobalt(II) disulfate

AU - Pan, Jian Xin

AU - Yang, Guo Yu

AU - Sun, Yan Qiong

PY - 2003/5

Y1 - 2003/5

N2 - The crystal structure of the title compound, (C4H 12N2)[Co-(H2O)6](SO 4)2, is built of [Co(H2O)6] 2+, cations, diprotonated piperazinium cations (each of the two crystallographically independent piperazinium cations occupies a special position on an inversion centre) and sulfate anions. The Co atom is coordinated by six water molecules in a slightly distorted octahedral geometry. The cations are linked to anions by N-H⋯O and O-H⋯O hydrogen bonds, forming an extensive three-dimensional hydrogen-bond network in the crystal structure.

AB - The crystal structure of the title compound, (C4H 12N2)[Co-(H2O)6](SO 4)2, is built of [Co(H2O)6] 2+, cations, diprotonated piperazinium cations (each of the two crystallographically independent piperazinium cations occupies a special position on an inversion centre) and sulfate anions. The Co atom is coordinated by six water molecules in a slightly distorted octahedral geometry. The cations are linked to anions by N-H⋯O and O-H⋯O hydrogen bonds, forming an extensive three-dimensional hydrogen-bond network in the crystal structure.

UR - https://www.scopus.com/pages/publications/18444398047

U2 - 10.1107/S1600536803008407

DO - 10.1107/S1600536803008407

M3 - Article

AN - SCOPUS:18444398047

SN - 1600-5368

VL - 59

SP - m286-m288

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 5

ER -

Piperazinium hexaaquacobalt(II) disulfate

Abstract

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