[Ph3C][B(C6F5)4]: A Highly Efficient Metal-Free Single-Component Initiator for the Helical-Sense-Selective Cationic Copolymerization of Chiral Aryl Isocyanides and Achiral Aryl Isocyanides

Xinwen Yan; Shaowen Zhang; Pengfei Zhang; Xiaolu Wu; An Liu; Ge Guo; Yuping Dong; Xiaofang Li

doi:10.1002/anie.201803300

[Ph₃C][B(C₆F₅)₄]: A Highly Efficient Metal-Free Single-Component Initiator for the Helical-Sense-Selective Cationic Copolymerization of Chiral Aryl Isocyanides and Achiral Aryl Isocyanides

Xinwen Yan
, Shaowen Zhang
, Pengfei Zhang
, Xiaolu Wu
, An Liu
, Ge Guo
, Yuping Dong^*
, Xiaofang Li

^*Corresponding author for this work

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

33 Citations (Scopus)

Abstract

Commercially available [Ph₃C][B(C₆F₅)₄] served as a highly efficient metal-free and single-component initiator not only for the carbocationic polymerization of polar and bulky aryl isocyanides with extremely high activity up to 1.2×10⁷ g of polymer/(mol_cat. h), but also for the helical-sense-selective polymerization of chiral aryl isocyanides and copolymerization with achiral aryl isocyanides to afford high-molecular-weight functional poly(aryl isocyanide)s with good solubility as well as AIE characteristics and/or a single-handed helical conformation.

Original language	English
Pages (from-to)	8947-8952
Number of pages	6
Journal	Angewandte Chemie - International Edition
Volume	57
Issue number	29
DOIs	https://doi.org/10.1002/anie.201803300
Publication status	Published - 16 Jul 2018

Keywords

cationic mechanisms
helical structures
isocyanides
metal-free initiators
polymerization

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10.1002/anie.201803300

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Yan, X., Zhang, S., Zhang, P., Wu, X., Liu, A., Guo, G., Dong, Y., & Li, X. (2018). [Ph₃C][B(C₆F₅)₄]: A Highly Efficient Metal-Free Single-Component Initiator for the Helical-Sense-Selective Cationic Copolymerization of Chiral Aryl Isocyanides and Achiral Aryl Isocyanides. Angewandte Chemie - International Edition, 57(29), 8947-8952. https://doi.org/10.1002/anie.201803300

@article{8760eda1cc3c456a88fa5a4b5d93484c,

title = "[Ph3C][B(C6F5)4]: A Highly Efficient Metal-Free Single-Component Initiator for the Helical-Sense-Selective Cationic Copolymerization of Chiral Aryl Isocyanides and Achiral Aryl Isocyanides",

abstract = "Commercially available [Ph3C][B(C6F5)4] served as a highly efficient metal-free and single-component initiator not only for the carbocationic polymerization of polar and bulky aryl isocyanides with extremely high activity up to 1.2×107 g of polymer/(molcat. h), but also for the helical-sense-selective polymerization of chiral aryl isocyanides and copolymerization with achiral aryl isocyanides to afford high-molecular-weight functional poly(aryl isocyanide)s with good solubility as well as AIE characteristics and/or a single-handed helical conformation.",

keywords = "cationic mechanisms, helical structures, isocyanides, metal-free initiators, polymerization",

author = "Xinwen Yan and Shaowen Zhang and Pengfei Zhang and Xiaolu Wu and An Liu and Ge Guo and Yuping Dong and Xiaofang Li",

note = "Publisher Copyright: {\textcopyright} 2018 Wiley-VCH Verlag GmbH \& Co. KGaA, Weinheim",

year = "2018",

month = jul,

day = "16",

doi = "10.1002/anie.201803300",

language = "English",

volume = "57",

pages = "8947--8952",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "29",

}

Yan, X, Zhang, S, Zhang, P, Wu, X, Liu, A, Guo, G , Dong, Y & Li, X 2018, '[Ph₃C][B(C₆F₅)₄]: A Highly Efficient Metal-Free Single-Component Initiator for the Helical-Sense-Selective Cationic Copolymerization of Chiral Aryl Isocyanides and Achiral Aryl Isocyanides', Angewandte Chemie - International Edition, vol. 57, no. 29, pp. 8947-8952. https://doi.org/10.1002/anie.201803300

[Ph₃C][B(C₆F₅)₄]: A Highly Efficient Metal-Free Single-Component Initiator for the Helical-Sense-Selective Cationic Copolymerization of Chiral Aryl Isocyanides and Achiral Aryl Isocyanides. / Yan, Xinwen; Zhang, Shaowen; Zhang, Pengfei et al.
In: Angewandte Chemie - International Edition, Vol. 57, No. 29, 16.07.2018, p. 8947-8952.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - [Ph3C][B(C6F5)4]

T2 - A Highly Efficient Metal-Free Single-Component Initiator for the Helical-Sense-Selective Cationic Copolymerization of Chiral Aryl Isocyanides and Achiral Aryl Isocyanides

AU - Yan, Xinwen

AU - Zhang, Shaowen

AU - Zhang, Pengfei

AU - Wu, Xiaolu

AU - Liu, An

AU - Guo, Ge

AU - Dong, Yuping

AU - Li, Xiaofang

PY - 2018/7/16

Y1 - 2018/7/16

N2 - Commercially available [Ph3C][B(C6F5)4] served as a highly efficient metal-free and single-component initiator not only for the carbocationic polymerization of polar and bulky aryl isocyanides with extremely high activity up to 1.2×107 g of polymer/(molcat. h), but also for the helical-sense-selective polymerization of chiral aryl isocyanides and copolymerization with achiral aryl isocyanides to afford high-molecular-weight functional poly(aryl isocyanide)s with good solubility as well as AIE characteristics and/or a single-handed helical conformation.

AB - Commercially available [Ph3C][B(C6F5)4] served as a highly efficient metal-free and single-component initiator not only for the carbocationic polymerization of polar and bulky aryl isocyanides with extremely high activity up to 1.2×107 g of polymer/(molcat. h), but also for the helical-sense-selective polymerization of chiral aryl isocyanides and copolymerization with achiral aryl isocyanides to afford high-molecular-weight functional poly(aryl isocyanide)s with good solubility as well as AIE characteristics and/or a single-handed helical conformation.

KW - cationic mechanisms

KW - helical structures

KW - isocyanides

KW - metal-free initiators

KW - polymerization

UR - https://www.scopus.com/pages/publications/85049796453

U2 - 10.1002/anie.201803300

DO - 10.1002/anie.201803300

M3 - Article

C2 - 29756408

AN - SCOPUS:85049796453

SN - 1433-7851

VL - 57

SP - 8947

EP - 8952

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 29

ER -

[Ph₃C][B(C₆F₅)₄]: A Highly Efficient Metal-Free Single-Component Initiator for the Helical-Sense-Selective Cationic Copolymerization of Chiral Aryl Isocyanides and Achiral Aryl Isocyanides

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Keywords

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