pH-induced coordination assembly of mononuclear and dinuclear copper(II) complexes based on a 4,4′-bipyridinium analogue

Xu Hui Jin; Li Xuan Cai; Jian Ke Sun; Zhan Feng Ju; Jie Zhang

doi:10.1016/j.inoche.2009.10.024

pH-induced coordination assembly of mononuclear and dinuclear copper(II) complexes based on a 4,4′-bipyridinium analogue

Xu Hui Jin
, Li Xuan Cai
, Jian Ke Sun
, Zhan Feng Ju
, Jie Zhang^*

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

Upon controlling coordination sites of a new bipyridinium analogue 4′-(N-carboxybenzyl-4-pyridinio)-2,2′:6′,2″-terpyridine chloride (HL·Cl) with different dosage of perchloric acid, two copper complexes with distinct bridging modes, {[Cu(L)Cl]·ClO₄·3H₂O}_n (1) and [Cu₂(HL)₂Cl₂]·4ClO₄·H₂O (2) have been obtained under hydrothermal condition. Complex 1 features a one-dimensional chain-like structure with mononuclear Cu(II) centers, while 2 is a dichloro-bridged dinuclear Cu(II) complex, which forms one-dimensional supramolecular chain via hydrogen bonding interactions between the carboxylic groups of HL ligands. The magnetic measurement reveals that an antiferromagnetic coupling interaction exists in complex 2.

Original language	English
Pages (from-to)	86-89
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	13
Issue number	1
DOIs	https://doi.org/10.1016/j.inoche.2009.10.024
Publication status	Published - Jan 2010
Externally published	Yes

Keywords

Antiferromagnetism
Bipyridinium analogue
Copper
Crystal structure

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10.1016/j.inoche.2009.10.024

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title = "pH-induced coordination assembly of mononuclear and dinuclear copper(II) complexes based on a 4,4′-bipyridinium analogue",

abstract = "Upon controlling coordination sites of a new bipyridinium analogue 4′-(N-carboxybenzyl-4-pyridinio)-2,2′:6′,2″-terpyridine chloride (HL·Cl) with different dosage of perchloric acid, two copper complexes with distinct bridging modes, \{[Cu(L)Cl]·ClO4·3H2O\}n (1) and [Cu2(HL)2Cl2]·4ClO4·H2O (2) have been obtained under hydrothermal condition. Complex 1 features a one-dimensional chain-like structure with mononuclear Cu(II) centers, while 2 is a dichloro-bridged dinuclear Cu(II) complex, which forms one-dimensional supramolecular chain via hydrogen bonding interactions between the carboxylic groups of HL ligands. The magnetic measurement reveals that an antiferromagnetic coupling interaction exists in complex 2.",

keywords = "Antiferromagnetism, Bipyridinium analogue, Copper, Crystal structure",

author = "Jin, \{Xu Hui\} and Cai, \{Li Xuan\} and Sun, \{Jian Ke\} and Ju, \{Zhan Feng\} and Jie Zhang",

year = "2010",

month = jan,

doi = "10.1016/j.inoche.2009.10.024",

language = "English",

volume = "13",

pages = "86--89",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

number = "1",

}

TY - JOUR

T1 - pH-induced coordination assembly of mononuclear and dinuclear copper(II) complexes based on a 4,4′-bipyridinium analogue

AU - Jin, Xu Hui

AU - Cai, Li Xuan

AU - Sun, Jian Ke

AU - Ju, Zhan Feng

AU - Zhang, Jie

PY - 2010/1

Y1 - 2010/1

N2 - Upon controlling coordination sites of a new bipyridinium analogue 4′-(N-carboxybenzyl-4-pyridinio)-2,2′:6′,2″-terpyridine chloride (HL·Cl) with different dosage of perchloric acid, two copper complexes with distinct bridging modes, {[Cu(L)Cl]·ClO4·3H2O}n (1) and [Cu2(HL)2Cl2]·4ClO4·H2O (2) have been obtained under hydrothermal condition. Complex 1 features a one-dimensional chain-like structure with mononuclear Cu(II) centers, while 2 is a dichloro-bridged dinuclear Cu(II) complex, which forms one-dimensional supramolecular chain via hydrogen bonding interactions between the carboxylic groups of HL ligands. The magnetic measurement reveals that an antiferromagnetic coupling interaction exists in complex 2.

AB - Upon controlling coordination sites of a new bipyridinium analogue 4′-(N-carboxybenzyl-4-pyridinio)-2,2′:6′,2″-terpyridine chloride (HL·Cl) with different dosage of perchloric acid, two copper complexes with distinct bridging modes, {[Cu(L)Cl]·ClO4·3H2O}n (1) and [Cu2(HL)2Cl2]·4ClO4·H2O (2) have been obtained under hydrothermal condition. Complex 1 features a one-dimensional chain-like structure with mononuclear Cu(II) centers, while 2 is a dichloro-bridged dinuclear Cu(II) complex, which forms one-dimensional supramolecular chain via hydrogen bonding interactions between the carboxylic groups of HL ligands. The magnetic measurement reveals that an antiferromagnetic coupling interaction exists in complex 2.

KW - Antiferromagnetism

KW - Bipyridinium analogue

KW - Copper

KW - Crystal structure

UR - https://www.scopus.com/pages/publications/72249101069

U2 - 10.1016/j.inoche.2009.10.024

DO - 10.1016/j.inoche.2009.10.024

M3 - Article

AN - SCOPUS:72249101069

SN - 1387-7003

VL - 13

SP - 86

EP - 89

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 1

ER -

pH-induced coordination assembly of mononuclear and dinuclear copper(II) complexes based on a 4,4′-bipyridinium analogue

Abstract

Keywords

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