TY - JOUR
T1 - pH-Dependent Self-Assembly of Ladder-Like Lanthanide Chains with Copper(I) Halide Clusters
AU - Liu, Jin Ying
AU - Fang, Wei Hui
AU - Yang, Guo Yu
N1 - Publisher Copyright:
© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
PY - 2016/8/1
Y1 - 2016/8/1
N2 - Through adjustment of the pH value of the reaction system, two series of 3 D lanthanide(III)-copper(I) coordination polymers, namely [Ln2(na)7Cu6Br5(H2O)2] [Ln=La (1), Ce (2), Pr (3), Nd (4), Sm (5), Eu (6), Gd (7), Tb (8)] and [La2(na)7Cu3Br2(H2O)2]⋅H2O (9) (na−=nicotinate), are synthesized hydrothermally and characterized fully. It is worth nothing that these two series of heterometallic compounds are constructed from similar ladder-like Ln–organic chains, but different copper(I) halide clusters. The luminescence properties of the compounds with Nd (4), Eu (6), and Tb (8) are also investigated.
AB - Through adjustment of the pH value of the reaction system, two series of 3 D lanthanide(III)-copper(I) coordination polymers, namely [Ln2(na)7Cu6Br5(H2O)2] [Ln=La (1), Ce (2), Pr (3), Nd (4), Sm (5), Eu (6), Gd (7), Tb (8)] and [La2(na)7Cu3Br2(H2O)2]⋅H2O (9) (na−=nicotinate), are synthesized hydrothermally and characterized fully. It is worth nothing that these two series of heterometallic compounds are constructed from similar ladder-like Ln–organic chains, but different copper(I) halide clusters. The luminescence properties of the compounds with Nd (4), Eu (6), and Tb (8) are also investigated.
KW - coordination polymers
KW - heterometallic complexes
KW - hydrothermal syntheses
KW - lanthanides
KW - luminescence
UR - https://www.scopus.com/pages/publications/84970993211
U2 - 10.1002/cplu.201600135
DO - 10.1002/cplu.201600135
M3 - Article
AN - SCOPUS:84970993211
SN - 2192-6506
VL - 81
SP - 792
EP - 797
JO - ChemPlusChem
JF - ChemPlusChem
IS - 8
ER -