Pd-Catalyzed Oxidative Heck Reaction of Grignard Reagents with Diaziridinone as Oxidant

Qipu Dai; Baoguo Zhao; Yihui Yang; Yian Shi

doi:10.1021/acs.orglett.9b01762

Pd-Catalyzed Oxidative Heck Reaction of Grignard Reagents with Diaziridinone as Oxidant

Qipu Dai, Baoguo Zhao, Yihui Yang, Yian Shi^*

^*Corresponding author for this work

Colorado State University

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

A novel Pd-catalyzed oxidative Heck reaction with readily available Grignard reagents using di-t-butyldiaziridinone as an oxidant has been developed. Various substituted olefins were obtained in 46-91% yields with high regioselectivity under mild reaction conditions.

Original language	English
Pages (from-to)	5157-5161
Number of pages	5
Journal	Organic Letters
Volume	21
Issue number	13
DOIs	https://doi.org/10.1021/acs.orglett.9b01762
Publication status	Published - 21 Jun 2019
Externally published	Yes

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title = "Pd-Catalyzed Oxidative Heck Reaction of Grignard Reagents with Diaziridinone as Oxidant",

abstract = "A novel Pd-catalyzed oxidative Heck reaction with readily available Grignard reagents using di-t-butyldiaziridinone as an oxidant has been developed. Various substituted olefins were obtained in 46-91% yields with high regioselectivity under mild reaction conditions.",

author = "Qipu Dai and Baoguo Zhao and Yihui Yang and Yian Shi",

note = "Publisher Copyright: Copyright {\textcopyright} 2019 American Chemical Society.",

year = "2019",

month = jun,

day = "21",

doi = "10.1021/acs.orglett.9b01762",

language = "English",

volume = "21",

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journal = "Organic Letters",

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T1 - Pd-Catalyzed Oxidative Heck Reaction of Grignard Reagents with Diaziridinone as Oxidant

AU - Dai, Qipu

AU - Zhao, Baoguo

AU - Yang, Yihui

AU - Shi, Yian

PY - 2019/6/21

Y1 - 2019/6/21

N2 - A novel Pd-catalyzed oxidative Heck reaction with readily available Grignard reagents using di-t-butyldiaziridinone as an oxidant has been developed. Various substituted olefins were obtained in 46-91% yields with high regioselectivity under mild reaction conditions.

AB - A novel Pd-catalyzed oxidative Heck reaction with readily available Grignard reagents using di-t-butyldiaziridinone as an oxidant has been developed. Various substituted olefins were obtained in 46-91% yields with high regioselectivity under mild reaction conditions.

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U2 - 10.1021/acs.orglett.9b01762

DO - 10.1021/acs.orglett.9b01762

M3 - Article

C2 - 31247760

AN - SCOPUS:85068191328

SN - 1523-7060

VL - 21

SP - 5157

EP - 5161

JO - Organic Letters

JF - Organic Letters

IS - 13

ER -

Pd-Catalyzed Oxidative Heck Reaction of Grignard Reagents with Diaziridinone as Oxidant

Abstract

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