TY - JOUR
T1 - P-type InP thin films prepared by a non-vacuum process for photoelectrochemical water splitting
AU - Chen, Zequn
AU - Chen, Huihui
AU - Zhao, Qinfeng
AU - Cao, Chuanbao
AU - Chen, Zhuo
N1 - Publisher Copyright:
© 2019 Published under licence by IOP Publishing Ltd.
PY - 2019/10/21
Y1 - 2019/10/21
N2 - Photoelectrochemical (PEC) water splitting has been considered as a promising way to produce hydrogen production. Herein, we present an inexpensive and simple method for preparing high active p-type InP thin films photocathode with Zn doped at 500 °C. The amount of dopant was optimized to obtain the high PEC activity films. Electrical measurements indicated that the optimized film had the hole mobility of 350 cm2V-1s-1 and carrier density of 7.51017 cm3. Optical measurements demonstrated the high absorption of 90% in 450-750 nm, and the bandgaps of the samples ranged from 2.08 eV to 2.3 eV. PEC test showed that the onset potential of the optimized InP thin film was about 0.35 V vs. RHE and the saturation photocurrent of 8 mA/cm2 occurred at -0.3 V vs. RHE. These results indicated that our p type InP thin films were a potential material in PEC devices.
AB - Photoelectrochemical (PEC) water splitting has been considered as a promising way to produce hydrogen production. Herein, we present an inexpensive and simple method for preparing high active p-type InP thin films photocathode with Zn doped at 500 °C. The amount of dopant was optimized to obtain the high PEC activity films. Electrical measurements indicated that the optimized film had the hole mobility of 350 cm2V-1s-1 and carrier density of 7.51017 cm3. Optical measurements demonstrated the high absorption of 90% in 450-750 nm, and the bandgaps of the samples ranged from 2.08 eV to 2.3 eV. PEC test showed that the onset potential of the optimized InP thin film was about 0.35 V vs. RHE and the saturation photocurrent of 8 mA/cm2 occurred at -0.3 V vs. RHE. These results indicated that our p type InP thin films were a potential material in PEC devices.
UR - http://www.scopus.com/inward/record.url?scp=85074473972&partnerID=8YFLogxK
U2 - 10.1088/1757-899X/612/2/022092
DO - 10.1088/1757-899X/612/2/022092
M3 - Conference article
AN - SCOPUS:85074473972
SN - 1757-8981
VL - 612
JO - IOP Conference Series: Materials Science and Engineering
JF - IOP Conference Series: Materials Science and Engineering
IS - 2
M1 - 022092
T2 - 2019 6th International Conference on Advanced Composite Materials and Manufacturing Engineering, ACMME 2019
Y2 - 22 June 2019 through 23 June 2019
ER -