Organometallo-macrocycle assembled through dialumane-mediated C-H activation of pyridines

Weixing Chen; Li Liu; Yanxia Zhao; Yujie Xue; Wenhua Xu; Nan Li; Biao Wu; Xiao Juan Yang

doi:10.1039/d1cc00318f

Organometallo-macrocycle assembled through dialumane-mediated C-H activation of pyridines

Weixing Chen
, Li Liu
, Yanxia Zhao^*
, Yujie Xue
, Wenhua Xu
, Nan Li^*
, Biao Wu
, Xiao Juan Yang^*

^*Corresponding author for this work

Northwest University China

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

Dialumane 1 reacts with pyridines at elevated temperatures through regioselective reductive dehydrogenation of 4-H, affording a unique hexanuclear Al(iii) macrocycle [{LAl(pyridyl)}6], which represents the first dialumane-mediated C-H activation of Py and may suggest a new approach toward organometallo supra-molecules by one-pot small molecule activation and self-assembly.

Original language	English
Pages (from-to)	6268-6271
Number of pages	4
Journal	Chemical Communications
Volume	57
Issue number	51
DOIs	https://doi.org/10.1039/d1cc00318f
Publication status	Published - 28 Jun 2021

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title = "Organometallo-macrocycle assembled through dialumane-mediated C-H activation of pyridines",

abstract = "Dialumane 1 reacts with pyridines at elevated temperatures through regioselective reductive dehydrogenation of 4-H, affording a unique hexanuclear Al(iii) macrocycle [\{LAl(pyridyl)\}6], which represents the first dialumane-mediated C-H activation of Py and may suggest a new approach toward organometallo supra-molecules by one-pot small molecule activation and self-assembly.",

author = "Weixing Chen and Li Liu and Yanxia Zhao and Yujie Xue and Wenhua Xu and Nan Li and Biao Wu and Yang, \{Xiao Juan\}",

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T1 - Organometallo-macrocycle assembled through dialumane-mediated C-H activation of pyridines

AU - Chen, Weixing

AU - Liu, Li

AU - Zhao, Yanxia

AU - Xue, Yujie

AU - Xu, Wenhua

AU - Li, Nan

AU - Wu, Biao

AU - Yang, Xiao Juan

PY - 2021/6/28

Y1 - 2021/6/28

N2 - Dialumane 1 reacts with pyridines at elevated temperatures through regioselective reductive dehydrogenation of 4-H, affording a unique hexanuclear Al(iii) macrocycle [{LAl(pyridyl)}6], which represents the first dialumane-mediated C-H activation of Py and may suggest a new approach toward organometallo supra-molecules by one-pot small molecule activation and self-assembly.

AB - Dialumane 1 reacts with pyridines at elevated temperatures through regioselective reductive dehydrogenation of 4-H, affording a unique hexanuclear Al(iii) macrocycle [{LAl(pyridyl)}6], which represents the first dialumane-mediated C-H activation of Py and may suggest a new approach toward organometallo supra-molecules by one-pot small molecule activation and self-assembly.

UR - https://www.scopus.com/pages/publications/85108856448

U2 - 10.1039/d1cc00318f

DO - 10.1039/d1cc00318f

M3 - Article

C2 - 34075952

AN - SCOPUS:85108856448

SN - 1359-7345

VL - 57

SP - 6268

EP - 6271

JO - Chemical Communications

JF - Chemical Communications

IS - 51

ER -

Organometallo-macrocycle assembled through dialumane-mediated C-H activation of pyridines

Abstract

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