Open-framework aluminoborates co-templated by two types of primary amines

Gao Juan Cao; Jian Lin; Wei Hui Fang; Shou Tian Zheng; Guo Yu Yang

doi:10.1039/c0dt01537g

Open-framework aluminoborates co-templated by two types of primary amines

Gao Juan Cao
, Jian Lin
, Wei Hui Fang
, Shou Tian Zheng
, Guo Yu Yang^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

CAS - Fujian Institute of Research on the Structure of Matter
Fujian Agriculture and Forestry University
Xiamen University

Research output: Contribution to journal › Article › peer-review

43 Citations (Scopus)

Abstract

A series of open-framework aluminoborates (ABOs), [CH₃NH ₃][(CH₃CH₂)₂NH₂] [Al(B₅O₁₀)] (1), [CH₃CH₂NH ₃][(CH₃CH₂)₂NH₂] [Al(B₅O₁₀)] (2), [CH₃CH₂NH ₃][(CH₃)₂NH₂](H₂O) _0.5[Al(B₅O₁₀)] (3) and [CH₃NH ₃][CH₃CH₂NH₃](H₂O) ₂[Al(B₅O₁₀)] (4) have been made co-templated by two types of primary amines under solvothermal conditions and characterized by elemental analysis, IR, TGA, UV-Vis, powder XRD, single crystal XRD and NLO determination, respectively. These four ABOs display two structural types: 1, 2 and 3 are isostructural and exhibit CrB₄ topology, showing three different layers along three different directions; while 4 contains 8-, 14-ring layers, which are packed along the [001] direction to form a noncentrosymmetric 3D framework with 8-, 14-ring channels, showing second harmonic generation (SHG) response that is about 0.5 times that of KDP (KH₂PO₄). The electronic structure calculations for 1 and 4 also have been performed.

Original language	English
Pages (from-to)	2940-2946
Number of pages	7
Journal	Dalton Transactions
Volume	40
Issue number	12
DOIs	https://doi.org/10.1039/c0dt01537g
Publication status	Published - 28 Mar 2011

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@article{b91191128ccc43a1be1f732678d81e45,

title = "Open-framework aluminoborates co-templated by two types of primary amines",

abstract = "A series of open-framework aluminoborates (ABOs), [CH3NH 3][(CH3CH2)2NH2] [Al(B5O10)] (1), [CH3CH2NH 3][(CH3CH2)2NH2] [Al(B5O10)] (2), [CH3CH2NH 3][(CH3)2NH2](H2O) 0.5[Al(B5O10)] (3) and [CH3NH 3][CH3CH2NH3](H2O) 2[Al(B5O10)] (4) have been made co-templated by two types of primary amines under solvothermal conditions and characterized by elemental analysis, IR, TGA, UV-Vis, powder XRD, single crystal XRD and NLO determination, respectively. These four ABOs display two structural types: 1, 2 and 3 are isostructural and exhibit CrB4 topology, showing three different layers along three different directions; while 4 contains 8-, 14-ring layers, which are packed along the [001] direction to form a noncentrosymmetric 3D framework with 8-, 14-ring channels, showing second harmonic generation (SHG) response that is about 0.5 times that of KDP (KH2PO4). The electronic structure calculations for 1 and 4 also have been performed.",

author = "Cao, \{Gao Juan\} and Jian Lin and Fang, \{Wei Hui\} and Zheng, \{Shou Tian\} and Yang, \{Guo Yu\}",

year = "2011",

month = mar,

day = "28",

doi = "10.1039/c0dt01537g",

language = "English",

volume = "40",

pages = "2940--2946",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "12",

}

TY - JOUR

T1 - Open-framework aluminoborates co-templated by two types of primary amines

AU - Cao, Gao Juan

AU - Lin, Jian

AU - Fang, Wei Hui

AU - Zheng, Shou Tian

AU - Yang, Guo Yu

PY - 2011/3/28

Y1 - 2011/3/28

N2 - A series of open-framework aluminoborates (ABOs), [CH3NH 3][(CH3CH2)2NH2] [Al(B5O10)] (1), [CH3CH2NH 3][(CH3CH2)2NH2] [Al(B5O10)] (2), [CH3CH2NH 3][(CH3)2NH2](H2O) 0.5[Al(B5O10)] (3) and [CH3NH 3][CH3CH2NH3](H2O) 2[Al(B5O10)] (4) have been made co-templated by two types of primary amines under solvothermal conditions and characterized by elemental analysis, IR, TGA, UV-Vis, powder XRD, single crystal XRD and NLO determination, respectively. These four ABOs display two structural types: 1, 2 and 3 are isostructural and exhibit CrB4 topology, showing three different layers along three different directions; while 4 contains 8-, 14-ring layers, which are packed along the [001] direction to form a noncentrosymmetric 3D framework with 8-, 14-ring channels, showing second harmonic generation (SHG) response that is about 0.5 times that of KDP (KH2PO4). The electronic structure calculations for 1 and 4 also have been performed.

AB - A series of open-framework aluminoborates (ABOs), [CH3NH 3][(CH3CH2)2NH2] [Al(B5O10)] (1), [CH3CH2NH 3][(CH3CH2)2NH2] [Al(B5O10)] (2), [CH3CH2NH 3][(CH3)2NH2](H2O) 0.5[Al(B5O10)] (3) and [CH3NH 3][CH3CH2NH3](H2O) 2[Al(B5O10)] (4) have been made co-templated by two types of primary amines under solvothermal conditions and characterized by elemental analysis, IR, TGA, UV-Vis, powder XRD, single crystal XRD and NLO determination, respectively. These four ABOs display two structural types: 1, 2 and 3 are isostructural and exhibit CrB4 topology, showing three different layers along three different directions; while 4 contains 8-, 14-ring layers, which are packed along the [001] direction to form a noncentrosymmetric 3D framework with 8-, 14-ring channels, showing second harmonic generation (SHG) response that is about 0.5 times that of KDP (KH2PO4). The electronic structure calculations for 1 and 4 also have been performed.

UR - https://www.scopus.com/pages/publications/79952661211

U2 - 10.1039/c0dt01537g

DO - 10.1039/c0dt01537g

M3 - Article

AN - SCOPUS:79952661211

SN - 1477-9226

VL - 40

SP - 2940

EP - 2946

JO - Dalton Transactions

JF - Dalton Transactions

IS - 12

ER -

Open-framework aluminoborates co-templated by two types of primary amines

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