One-step preparation of fluorescent inorganic-organic hybrid material used for explosive sensing

Xin Ming Hu; Qi Che; Ding Zhou; Jie Cao; Yu Jian He; Bao Hang Han

doi:10.1039/c1py00012h

One-step preparation of fluorescent inorganic-organic hybrid material used for explosive sensing

Xin Ming Hu, Qi Che, Ding Zhou, Jie Cao^*, Yu Jian He, Bao Hang Han

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

69 Citations (Scopus)

Abstract

As a fluorescent inorganic-organic hybrid polymer, cross-linked poly(tetraphenylethylene-co-cyclotriphosphazene) (TPE-CP) is prepared through one-step polycondensation and well characterized. Owing to the aggregation-induced emission feature of the tetraphenylethylene residue, TPE-CP exhibits a remarkable fluorescent emission property in the suspension and solid-state. Both 2,4,6-trinitrotoluene (TNT) and 2,4,6-trinitrophenol (picric acid, PA) can cause a significant fluorescence quenching of TPE-CP due to the electron transfer from TPE-CP to TNT or PA. Additional energy transfer makes PA more sensitive to TPE-CP than TNT in the fluorescence quenching detection.

Original language	English
Pages (from-to)	1124-1128
Number of pages	5
Journal	Polymer Chemistry
Volume	2
Issue number	5
DOIs	https://doi.org/10.1039/c1py00012h
Publication status	Published - 2011
Externally published	Yes

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title = "One-step preparation of fluorescent inorganic-organic hybrid material used for explosive sensing",

abstract = "As a fluorescent inorganic-organic hybrid polymer, cross-linked poly(tetraphenylethylene-co-cyclotriphosphazene) (TPE-CP) is prepared through one-step polycondensation and well characterized. Owing to the aggregation-induced emission feature of the tetraphenylethylene residue, TPE-CP exhibits a remarkable fluorescent emission property in the suspension and solid-state. Both 2,4,6-trinitrotoluene (TNT) and 2,4,6-trinitrophenol (picric acid, PA) can cause a significant fluorescence quenching of TPE-CP due to the electron transfer from TPE-CP to TNT or PA. Additional energy transfer makes PA more sensitive to TPE-CP than TNT in the fluorescence quenching detection.",

author = "Hu, {Xin Ming} and Qi Che and Ding Zhou and Jie Cao and He, {Yu Jian} and Han, {Bao Hang}",

year = "2011",

doi = "10.1039/c1py00012h",

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publisher = "Royal Society of Chemistry",

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T1 - One-step preparation of fluorescent inorganic-organic hybrid material used for explosive sensing

AU - Hu, Xin Ming

AU - Che, Qi

AU - Zhou, Ding

AU - Cao, Jie

AU - He, Yu Jian

AU - Han, Bao Hang

PY - 2011

Y1 - 2011

N2 - As a fluorescent inorganic-organic hybrid polymer, cross-linked poly(tetraphenylethylene-co-cyclotriphosphazene) (TPE-CP) is prepared through one-step polycondensation and well characterized. Owing to the aggregation-induced emission feature of the tetraphenylethylene residue, TPE-CP exhibits a remarkable fluorescent emission property in the suspension and solid-state. Both 2,4,6-trinitrotoluene (TNT) and 2,4,6-trinitrophenol (picric acid, PA) can cause a significant fluorescence quenching of TPE-CP due to the electron transfer from TPE-CP to TNT or PA. Additional energy transfer makes PA more sensitive to TPE-CP than TNT in the fluorescence quenching detection.

AB - As a fluorescent inorganic-organic hybrid polymer, cross-linked poly(tetraphenylethylene-co-cyclotriphosphazene) (TPE-CP) is prepared through one-step polycondensation and well characterized. Owing to the aggregation-induced emission feature of the tetraphenylethylene residue, TPE-CP exhibits a remarkable fluorescent emission property in the suspension and solid-state. Both 2,4,6-trinitrotoluene (TNT) and 2,4,6-trinitrophenol (picric acid, PA) can cause a significant fluorescence quenching of TPE-CP due to the electron transfer from TPE-CP to TNT or PA. Additional energy transfer makes PA more sensitive to TPE-CP than TNT in the fluorescence quenching detection.

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U2 - 10.1039/c1py00012h

DO - 10.1039/c1py00012h

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VL - 2

SP - 1124

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JO - Polymer Chemistry

JF - Polymer Chemistry

IS - 5

ER -

One-step preparation of fluorescent inorganic-organic hybrid material used for explosive sensing

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