One-pot synthesis of 2-chloro-2-Thio/selenocyanato ketones from β-keto acids

Di Wu; Chengcheng Li; Yongjie Duan; Hongquan Yin; Fuxue Chen

doi:10.1039/d1qo00405k

One-pot synthesis of 2-chloro-2-Thio/selenocyanato ketones from β-keto acids

Di Wu
, Chengcheng Li
, Yongjie Duan
, Hongquan Yin
, Fuxue Chen^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

A chlorothiocyanato difunctionalization reaction was achieved, and various α-chlorothio/selenocyanato difunctional ketones were synthesized through a one-pot strategy from β-keto acids. The high yield and wide scope of substrates make this approach more practical for the synthesis of α-substituented difunctional ketones.

Original language	English
Pages (from-to)	3724-3728
Number of pages	5
Journal	Organic Chemistry Frontiers
Volume	8
Issue number	14
DOIs	https://doi.org/10.1039/d1qo00405k
Publication status	Published - 21 Jul 2021

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title = "One-pot synthesis of 2-chloro-2-Thio/selenocyanato ketones from β-keto acids",

abstract = "A chlorothiocyanato difunctionalization reaction was achieved, and various α-chlorothio/selenocyanato difunctional ketones were synthesized through a one-pot strategy from β-keto acids. The high yield and wide scope of substrates make this approach more practical for the synthesis of α-substituented difunctional ketones.",

author = "Di Wu and Chengcheng Li and Yongjie Duan and Hongquan Yin and Fuxue Chen",

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T1 - One-pot synthesis of 2-chloro-2-Thio/selenocyanato ketones from β-keto acids

AU - Wu, Di

AU - Li, Chengcheng

AU - Duan, Yongjie

AU - Yin, Hongquan

AU - Chen, Fuxue

PY - 2021/7/21

Y1 - 2021/7/21

N2 - A chlorothiocyanato difunctionalization reaction was achieved, and various α-chlorothio/selenocyanato difunctional ketones were synthesized through a one-pot strategy from β-keto acids. The high yield and wide scope of substrates make this approach more practical for the synthesis of α-substituented difunctional ketones.

AB - A chlorothiocyanato difunctionalization reaction was achieved, and various α-chlorothio/selenocyanato difunctional ketones were synthesized through a one-pot strategy from β-keto acids. The high yield and wide scope of substrates make this approach more practical for the synthesis of α-substituented difunctional ketones.

UR - https://www.scopus.com/pages/publications/85110309280

U2 - 10.1039/d1qo00405k

DO - 10.1039/d1qo00405k

M3 - Article

AN - SCOPUS:85110309280

SN - 2052-4110

VL - 8

SP - 3724

EP - 3728

JO - Organic Chemistry Frontiers

JF - Organic Chemistry Frontiers

IS - 14

ER -

One-pot synthesis of 2-chloro-2-Thio/selenocyanato ketones from β-keto acids

Abstract

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