One-dimensional structure of an aluminum coordination compound

Zhi Yang; Kai Li; Xiaoli Ma; Herbert W. Roesky; Pengfei Hao; Mingdong Zhong

doi:10.1002/ejic.201301384

One-dimensional structure of an aluminum coordination compound

Zhi Yang^*
, Kai Li
, Xiaoli Ma
, Herbert W. Roesky
, Pengfei Hao
, Mingdong Zhong

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology
University of Göttingen

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

The reaction of trimethylaluminum with a salen {salenH₂ = [N,N′-bis(salicylidene)ethylenediamine]} ligand in toluene afforded the complex [Me₂AlOC₆H₄CH=NCH₂-] _n. It shows a one-dimensional structure in the crystal state with pentacoordinate aluminum. This complex was characterized by ¹H and ¹³C NMR spectroscopy, IR spectroscopy, single-crystal X-ray structure, and elemental analysis. The reaction of trimethylaluminum with a salen {salenH₂ = [N,N′-bis(salicylidene)ethylenediamine]} ligand afforded an aluminum-centered chain structure of composition [Me ₂AlOC₆H₄CH=NCH₂-]_n in the crystal.

Original language	English
Pages (from-to)	1102-1104
Number of pages	3
Journal	European Journal of Inorganic Chemistry
Issue number	6
DOIs	https://doi.org/10.1002/ejic.201301384
Publication status	Published - 2014

Keywords

Aluminum
IR spectroscopy
Macromolecules
Schiff bases
X-ray diffraction

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@article{d6746dbac7974a6cbddb3ec190302804,

title = "One-dimensional structure of an aluminum coordination compound",

abstract = "The reaction of trimethylaluminum with a salen \{salenH2 = [N,N′-bis(salicylidene)ethylenediamine]\} ligand in toluene afforded the complex [Me2AlOC6H4CH=NCH2-] n. It shows a one-dimensional structure in the crystal state with pentacoordinate aluminum. This complex was characterized by 1H and 13C NMR spectroscopy, IR spectroscopy, single-crystal X-ray structure, and elemental analysis. The reaction of trimethylaluminum with a salen \{salenH2 = [N,N′-bis(salicylidene)ethylenediamine]\} ligand afforded an aluminum-centered chain structure of composition [Me 2AlOC6H4CH=NCH2-]n in the crystal.",

keywords = "Aluminum, IR spectroscopy, Macromolecules, Schiff bases, X-ray diffraction",

author = "Zhi Yang and Kai Li and Xiaoli Ma and Roesky, \{Herbert W.\} and Pengfei Hao and Mingdong Zhong",

year = "2014",

doi = "10.1002/ejic.201301384",

language = "English",

pages = "1102--1104",

journal = "European Journal of Inorganic Chemistry",

issn = "1434-1948",

publisher = "Wiley-VCH Verlag",

number = "6",

}

TY - JOUR

T1 - One-dimensional structure of an aluminum coordination compound

AU - Yang, Zhi

AU - Li, Kai

AU - Ma, Xiaoli

AU - Roesky, Herbert W.

AU - Hao, Pengfei

AU - Zhong, Mingdong

PY - 2014

Y1 - 2014

N2 - The reaction of trimethylaluminum with a salen {salenH2 = [N,N′-bis(salicylidene)ethylenediamine]} ligand in toluene afforded the complex [Me2AlOC6H4CH=NCH2-] n. It shows a one-dimensional structure in the crystal state with pentacoordinate aluminum. This complex was characterized by 1H and 13C NMR spectroscopy, IR spectroscopy, single-crystal X-ray structure, and elemental analysis. The reaction of trimethylaluminum with a salen {salenH2 = [N,N′-bis(salicylidene)ethylenediamine]} ligand afforded an aluminum-centered chain structure of composition [Me 2AlOC6H4CH=NCH2-]n in the crystal.

AB - The reaction of trimethylaluminum with a salen {salenH2 = [N,N′-bis(salicylidene)ethylenediamine]} ligand in toluene afforded the complex [Me2AlOC6H4CH=NCH2-] n. It shows a one-dimensional structure in the crystal state with pentacoordinate aluminum. This complex was characterized by 1H and 13C NMR spectroscopy, IR spectroscopy, single-crystal X-ray structure, and elemental analysis. The reaction of trimethylaluminum with a salen {salenH2 = [N,N′-bis(salicylidene)ethylenediamine]} ligand afforded an aluminum-centered chain structure of composition [Me 2AlOC6H4CH=NCH2-]n in the crystal.

KW - Aluminum

KW - IR spectroscopy

KW - Macromolecules

KW - Schiff bases

KW - X-ray diffraction

UR - https://www.scopus.com/pages/publications/84894413001

U2 - 10.1002/ejic.201301384

DO - 10.1002/ejic.201301384

M3 - Article

AN - SCOPUS:84894413001

SN - 1434-1948

SP - 1102

EP - 1104

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

IS - 6

ER -

One-dimensional structure of an aluminum coordination compound

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