Abstract
For the polycondensation reaction of Aa1…Aas—Bb1…Bbt type, the sol fraction above the gel point is investigated in detail by taking Stockmayers gelation condition as a criterion. Furthermore, the scaling behavior near the gel point is revealed to reach an asymptopic form of Stockmayers equilibrium number distribution from which a generalized scaling law is deduced.
| Original language | English |
|---|---|
| Pages (from-to) | 797-804 |
| Number of pages | 8 |
| Journal | Macromolecules |
| Volume | 21 |
| Issue number | 3 |
| DOIs | |
| Publication status | Published - 1988 |
| Externally published | Yes |