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On the Curing Theory and the Scaling Study of the Polycondensation Reaction of Aa1…Aas—Bb1…Bbt Type

  • Au Chin Tang
  • , Li Ze-sheng
  • , Sun Chia-chung
  • , Tang Xin-yi
  • Jilin University

Research output: Contribution to journalArticlepeer-review

Abstract

For the polycondensation reaction of Aa1…Aas—Bb1…Bbt type, the sol fraction above the gel point is investigated in detail by taking Stockmayers gelation condition as a criterion. Furthermore, the scaling behavior near the gel point is revealed to reach an asymptopic form of Stockmayers equilibrium number distribution from which a generalized scaling law is deduced.

Original languageEnglish
Pages (from-to)797-804
Number of pages8
JournalMacromolecules
Volume21
Issue number3
DOIs
Publication statusPublished - 1988
Externally publishedYes

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