Novel organic-inorganic hybrid one-dimensional chain assembled by oxalate-bridging terbium-substituted phosphotungstate dimers and dinuclear copper(ii)-oxalate clusters

Hai Yan Zhao; Jun Wei Zhao; Bai Feng Yang; Huan He; Guo Yu Yang

doi:10.1039/c3ce40573g

Novel organic-inorganic hybrid one-dimensional chain assembled by oxalate-bridging terbium-substituted phosphotungstate dimers and dinuclear copper(ii)-oxalate clusters

Hai Yan Zhao
, Jun Wei Zhao^*
, Bai Feng Yang
, Huan He
, Guo Yu Yang

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology
Henan University
CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

33 Citations (Scopus)

Abstract

A novel one-dimensional (1D) organic-inorganic hybrid oxalate-bridging Cu-Tb heterometallic phosphotungstate [Cu(en)₂(H₂O)] [Cu(en)₂][Tb(α-PW₁₁O₃₉)(H ₂O)₂(ox)Cu(en)]·6H₂O (1) with mixed organic ligands of ox and en (ox = oxalate, en = ethylenediamine) has been hydrothermally synthesized. Notably, it represents the first oxalate-bridging Ln-TM heterometallic hybrid built by oxalate-bridging terbium-substituted phosphotungstate {[Cu(en)₂]₂[(α-PW ₁₁O₃₉)Tb(H₂O)₂]₂(μ-ox) }^6- dimeric units and dinuclear copper(ii)-oxalate [Cu ₂(en)₂(μ-ox)]²⁺ linkers. Magnetic susceptibility measurements indicate weak antiferromagnetic couplings within 1.

Original language	English
Pages (from-to)	5209-5213
Number of pages	5
Journal	CrystEngComm
Volume	15
Issue number	26
DOIs	https://doi.org/10.1039/c3ce40573g
Publication status	Published - 14 Jul 2013

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@article{2243ac4425ec4934ad8793a6e094ddfd,

title = "Novel organic-inorganic hybrid one-dimensional chain assembled by oxalate-bridging terbium-substituted phosphotungstate dimers and dinuclear copper(ii)-oxalate clusters",

abstract = "A novel one-dimensional (1D) organic-inorganic hybrid oxalate-bridging Cu-Tb heterometallic phosphotungstate [Cu(en)2(H2O)] [Cu(en)2][Tb(α-PW11O39)(H 2O)2(ox)Cu(en)]·6H2O (1) with mixed organic ligands of ox and en (ox = oxalate, en = ethylenediamine) has been hydrothermally synthesized. Notably, it represents the first oxalate-bridging Ln-TM heterometallic hybrid built by oxalate-bridging terbium-substituted phosphotungstate \{[Cu(en)2]2[(α-PW 11O39)Tb(H2O)2]2(μ-ox) \}6- dimeric units and dinuclear copper(ii)-oxalate [Cu 2(en)2(μ-ox)]2+ linkers. Magnetic susceptibility measurements indicate weak antiferromagnetic couplings within 1.",

author = "Zhao, \{Hai Yan\} and Zhao, \{Jun Wei\} and Yang, \{Bai Feng\} and Huan He and Yang, \{Guo Yu\}",

year = "2013",

month = jul,

day = "14",

doi = "10.1039/c3ce40573g",

language = "English",

volume = "15",

pages = "5209--5213",

journal = "CrystEngComm",

issn = "1466-8033",

publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Novel organic-inorganic hybrid one-dimensional chain assembled by oxalate-bridging terbium-substituted phosphotungstate dimers and dinuclear copper(ii)-oxalate clusters

AU - Zhao, Hai Yan

AU - Zhao, Jun Wei

AU - Yang, Bai Feng

AU - He, Huan

AU - Yang, Guo Yu

PY - 2013/7/14

Y1 - 2013/7/14

N2 - A novel one-dimensional (1D) organic-inorganic hybrid oxalate-bridging Cu-Tb heterometallic phosphotungstate [Cu(en)2(H2O)] [Cu(en)2][Tb(α-PW11O39)(H 2O)2(ox)Cu(en)]·6H2O (1) with mixed organic ligands of ox and en (ox = oxalate, en = ethylenediamine) has been hydrothermally synthesized. Notably, it represents the first oxalate-bridging Ln-TM heterometallic hybrid built by oxalate-bridging terbium-substituted phosphotungstate {[Cu(en)2]2[(α-PW 11O39)Tb(H2O)2]2(μ-ox) }6- dimeric units and dinuclear copper(ii)-oxalate [Cu 2(en)2(μ-ox)]2+ linkers. Magnetic susceptibility measurements indicate weak antiferromagnetic couplings within 1.

AB - A novel one-dimensional (1D) organic-inorganic hybrid oxalate-bridging Cu-Tb heterometallic phosphotungstate [Cu(en)2(H2O)] [Cu(en)2][Tb(α-PW11O39)(H 2O)2(ox)Cu(en)]·6H2O (1) with mixed organic ligands of ox and en (ox = oxalate, en = ethylenediamine) has been hydrothermally synthesized. Notably, it represents the first oxalate-bridging Ln-TM heterometallic hybrid built by oxalate-bridging terbium-substituted phosphotungstate {[Cu(en)2]2[(α-PW 11O39)Tb(H2O)2]2(μ-ox) }6- dimeric units and dinuclear copper(ii)-oxalate [Cu 2(en)2(μ-ox)]2+ linkers. Magnetic susceptibility measurements indicate weak antiferromagnetic couplings within 1.

UR - https://www.scopus.com/pages/publications/84881618579

U2 - 10.1039/c3ce40573g

DO - 10.1039/c3ce40573g

M3 - Article

AN - SCOPUS:84881618579

SN - 1466-8033

VL - 15

SP - 5209

EP - 5213

JO - CrystEngComm

JF - CrystEngComm

IS - 26

ER -

Novel organic-inorganic hybrid one-dimensional chain assembled by oxalate-bridging terbium-substituted phosphotungstate dimers and dinuclear copper(ii)-oxalate clusters

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