Novel borate supramolecular frameworks constructed from isolated B4/B5 clusters and 1-D B17-based chains

Jia Jia Wang; Guo Yu Yang

doi:10.1016/j.inoche.2017.07.004

Novel borate supramolecular frameworks constructed from isolated B₄/B₅ clusters and 1-D B₁₇-based chains

Jia Jia Wang
, Guo Yu Yang^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

Three new borates [Cu(1,3-dap)₂(H₂O)₂][Cu(1,3-dap)₂(B(OH)₃)₂][B₄O₅(OH)₄]₂ (1, 1,3-dap = 1,3-diaminopropane), [Cu(py)₄(H₂O)][B₅O₆(OH)₄]₂·3py·H₂O (2, py = pyridine) and (HDMF)₂[NH(CH₃)₃]₄[NH₂(CH₃)₂]₂Mg₂[B₁₇O₂₆(OH)₄][B₁₇O₂₇(OH)₄]·NH₃ (3, DMF = N,N-dimethylformamide) have been synthesized under mild solvothermal conditions and characterized by elemental analysis, IR spectra, diffuse reflectance spectra, thermogravimetric analysis, single-crystal X-ray diffraction and powder X-ray diffraction. 1 and 2 exhibit 3-D supramolecular hydrogen-bonded architectures constructed from isolated oxoboron clusters [B₄O₅(OH)₄]^{2 −} and [B₅O₆(OH)₄]⁻, respectively. The structure of 3 features two different 1-D chains built by unprecedented [B₁₇O₂₆(OH)₄]^{5 −} and [B₁₇O₂₇(OH)₄]^{7 −} clusters, respectively. And the adjacent chains are alternatively linked by H-bonding to form a 3-D supramolecular framework.

Original language	English
Pages (from-to)	92-95
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	85
DOIs	https://doi.org/10.1016/j.inoche.2017.07.004
Publication status	Published - Nov 2017

Keywords

Borate
Cluster
Hydrogen bond
Solvothermal synthesis
Supramolecular framework

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10.1016/j.inoche.2017.07.004

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@article{ee304d51e6754c29b46eb8dde64a6f69,

title = "Novel borate supramolecular frameworks constructed from isolated B4/B5 clusters and 1-D B17-based chains",

abstract = "Three new borates [Cu(1,3-dap)2(H2O)2][Cu(1,3-dap)2(B(OH)3)2][B4O5(OH)4]2 (1, 1,3-dap = 1,3-diaminopropane), [Cu(py)4(H2O)][B5O6(OH)4]2·3py·H2O (2, py = pyridine) and (HDMF)2[NH(CH3)3]4[NH2(CH3)2]2Mg2[B17O26(OH)4][B17O27(OH)4]·NH3 (3, DMF = N,N-dimethylformamide) have been synthesized under mild solvothermal conditions and characterized by elemental analysis, IR spectra, diffuse reflectance spectra, thermogravimetric analysis, single-crystal X-ray diffraction and powder X-ray diffraction. 1 and 2 exhibit 3-D supramolecular hydrogen-bonded architectures constructed from isolated oxoboron clusters [B4O5(OH)4]2 − and [B5O6(OH)4]−, respectively. The structure of 3 features two different 1-D chains built by unprecedented [B17O26(OH)4]5 − and [B17O27(OH)4]7 − clusters, respectively. And the adjacent chains are alternatively linked by H-bonding to form a 3-D supramolecular framework.",

keywords = "Borate, Cluster, Hydrogen bond, Solvothermal synthesis, Supramolecular framework",

author = "Wang, \{Jia Jia\} and Yang, \{Guo Yu\}",

note = "Publisher Copyright: {\textcopyright} 2017 Elsevier B.V.",

year = "2017",

month = nov,

doi = "10.1016/j.inoche.2017.07.004",

language = "English",

volume = "85",

pages = "92--95",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Novel borate supramolecular frameworks constructed from isolated B4/B5 clusters and 1-D B17-based chains

AU - Wang, Jia Jia

AU - Yang, Guo Yu

PY - 2017/11

Y1 - 2017/11

N2 - Three new borates [Cu(1,3-dap)2(H2O)2][Cu(1,3-dap)2(B(OH)3)2][B4O5(OH)4]2 (1, 1,3-dap = 1,3-diaminopropane), [Cu(py)4(H2O)][B5O6(OH)4]2·3py·H2O (2, py = pyridine) and (HDMF)2[NH(CH3)3]4[NH2(CH3)2]2Mg2[B17O26(OH)4][B17O27(OH)4]·NH3 (3, DMF = N,N-dimethylformamide) have been synthesized under mild solvothermal conditions and characterized by elemental analysis, IR spectra, diffuse reflectance spectra, thermogravimetric analysis, single-crystal X-ray diffraction and powder X-ray diffraction. 1 and 2 exhibit 3-D supramolecular hydrogen-bonded architectures constructed from isolated oxoboron clusters [B4O5(OH)4]2 − and [B5O6(OH)4]−, respectively. The structure of 3 features two different 1-D chains built by unprecedented [B17O26(OH)4]5 − and [B17O27(OH)4]7 − clusters, respectively. And the adjacent chains are alternatively linked by H-bonding to form a 3-D supramolecular framework.

AB - Three new borates [Cu(1,3-dap)2(H2O)2][Cu(1,3-dap)2(B(OH)3)2][B4O5(OH)4]2 (1, 1,3-dap = 1,3-diaminopropane), [Cu(py)4(H2O)][B5O6(OH)4]2·3py·H2O (2, py = pyridine) and (HDMF)2[NH(CH3)3]4[NH2(CH3)2]2Mg2[B17O26(OH)4][B17O27(OH)4]·NH3 (3, DMF = N,N-dimethylformamide) have been synthesized under mild solvothermal conditions and characterized by elemental analysis, IR spectra, diffuse reflectance spectra, thermogravimetric analysis, single-crystal X-ray diffraction and powder X-ray diffraction. 1 and 2 exhibit 3-D supramolecular hydrogen-bonded architectures constructed from isolated oxoboron clusters [B4O5(OH)4]2 − and [B5O6(OH)4]−, respectively. The structure of 3 features two different 1-D chains built by unprecedented [B17O26(OH)4]5 − and [B17O27(OH)4]7 − clusters, respectively. And the adjacent chains are alternatively linked by H-bonding to form a 3-D supramolecular framework.

KW - Borate

KW - Cluster

KW - Hydrogen bond

KW - Solvothermal synthesis

KW - Supramolecular framework

UR - https://www.scopus.com/pages/publications/85024097684

U2 - 10.1016/j.inoche.2017.07.004

DO - 10.1016/j.inoche.2017.07.004

M3 - Article

AN - SCOPUS:85024097684

SN - 1387-7003

VL - 85

SP - 92

EP - 95

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -

Novel borate supramolecular frameworks constructed from isolated B₄/B₅ clusters and 1-D B₁₇-based chains

Abstract

Keywords

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