Novel (42 · 84)(43 · 63)2(46 · 63 · 86)2 topology network built up from the highly connective pyridine-2,4,6-tricarboxylate ligand

Peng Ren; Pang Kuan Chen; Gong Feng Xu; Zhi Chen

doi:10.1016/j.inoche.2007.03.031

Novel (4² · 8⁴)(4³ · 6³)₂(4⁶ · 6³ · 8⁶)₂ topology network built up from the highly connective pyridine-2,4,6-tricarboxylate ligand

Peng Ren, Pang Kuan Chen^*, Gong Feng Xu, Zhi Chen

^*Corresponding author for this work

Nankai University

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

A new manganese polymer Mn₃(ptc)₂(H₂O)₄ (1) (H₃ptc = Pyridine-2,4,6-tricarboxylic acid) has been solvothermally synthesized and characterized by single-crystal diffraction, IR, TGA and elemental analysis. Compound 1 crystallizes in the triclinic space group P over(1, ̄) and shows a fairly complicated structure, which should be attributed to the high connectivity of H₃ptc ligand. Meanwhile, we defined a novel trinodal (4² · 8⁴)(4³ · 6³)₂(4⁶ · 6³ · 8⁶)₂ topology net, two types of Mn(II) ions in different chemical environment and ptc^3- anion act as four-connected, four-connected and six-connected node, respectively. The magnetic measurement in the temperature range of 2-300 K displays weak antiferromagnetic coupling interaction between the Mn(II) ions.

Original language	English
Pages (from-to)	836-838
Number of pages	3
Journal	Inorganic Chemistry Communications
Volume	10
Issue number	7
DOIs	https://doi.org/10.1016/j.inoche.2007.03.031
Publication status	Published - Jul 2007
Externally published	Yes

Keywords

Magnetic behavior
Manganese(II)
Novel topology
Pyridine-2,4,6-tricarboxylate
Solvothermal synthesis

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10.1016/j.inoche.2007.03.031

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@article{1799517f06be4699ac0f94030d487b92,

title = "Novel (42 · 84)(43 · 63)2(46 · 63 · 86)2 topology network built up from the highly connective pyridine-2,4,6-tricarboxylate ligand",

abstract = "A new manganese polymer Mn3(ptc)2(H2O)4 (1) (H3ptc = Pyridine-2,4,6-tricarboxylic acid) has been solvothermally synthesized and characterized by single-crystal diffraction, IR, TGA and elemental analysis. Compound 1 crystallizes in the triclinic space group P over(1,{\= }) and shows a fairly complicated structure, which should be attributed to the high connectivity of H3ptc ligand. Meanwhile, we defined a novel trinodal (42 · 84)(43 · 63)2(46 · 63 · 86)2 topology net, two types of Mn(II) ions in different chemical environment and ptc3- anion act as four-connected, four-connected and six-connected node, respectively. The magnetic measurement in the temperature range of 2-300 K displays weak antiferromagnetic coupling interaction between the Mn(II) ions.",

keywords = "Magnetic behavior, Manganese(II), Novel topology, Pyridine-2,4,6-tricarboxylate, Solvothermal synthesis",

author = "Peng Ren and Chen, \{Pang Kuan\} and Xu, \{Gong Feng\} and Zhi Chen",

year = "2007",

month = jul,

doi = "10.1016/j.inoche.2007.03.031",

language = "English",

volume = "10",

pages = "836--838",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

number = "7",

}

TY - JOUR

T1 - Novel (42 · 84)(43 · 63)2(46 · 63 · 86)2 topology network built up from the highly connective pyridine-2,4,6-tricarboxylate ligand

AU - Ren, Peng

AU - Chen, Pang Kuan

AU - Xu, Gong Feng

AU - Chen, Zhi

PY - 2007/7

Y1 - 2007/7

N2 - A new manganese polymer Mn3(ptc)2(H2O)4 (1) (H3ptc = Pyridine-2,4,6-tricarboxylic acid) has been solvothermally synthesized and characterized by single-crystal diffraction, IR, TGA and elemental analysis. Compound 1 crystallizes in the triclinic space group P over(1, ̄) and shows a fairly complicated structure, which should be attributed to the high connectivity of H3ptc ligand. Meanwhile, we defined a novel trinodal (42 · 84)(43 · 63)2(46 · 63 · 86)2 topology net, two types of Mn(II) ions in different chemical environment and ptc3- anion act as four-connected, four-connected and six-connected node, respectively. The magnetic measurement in the temperature range of 2-300 K displays weak antiferromagnetic coupling interaction between the Mn(II) ions.

AB - A new manganese polymer Mn3(ptc)2(H2O)4 (1) (H3ptc = Pyridine-2,4,6-tricarboxylic acid) has been solvothermally synthesized and characterized by single-crystal diffraction, IR, TGA and elemental analysis. Compound 1 crystallizes in the triclinic space group P over(1, ̄) and shows a fairly complicated structure, which should be attributed to the high connectivity of H3ptc ligand. Meanwhile, we defined a novel trinodal (42 · 84)(43 · 63)2(46 · 63 · 86)2 topology net, two types of Mn(II) ions in different chemical environment and ptc3- anion act as four-connected, four-connected and six-connected node, respectively. The magnetic measurement in the temperature range of 2-300 K displays weak antiferromagnetic coupling interaction between the Mn(II) ions.

KW - Magnetic behavior

KW - Manganese(II)

KW - Novel topology

KW - Pyridine-2,4,6-tricarboxylate

KW - Solvothermal synthesis

UR - https://www.scopus.com/pages/publications/34249902030

U2 - 10.1016/j.inoche.2007.03.031

DO - 10.1016/j.inoche.2007.03.031

M3 - Article

AN - SCOPUS:34249902030

SN - 1387-7003

VL - 10

SP - 836

EP - 838

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 7

ER -

Novel (4² · 8⁴)(4³ · 6³)₂(4⁶ · 6³ · 8⁶)₂ topology network built up from the highly connective pyridine-2,4,6-tricarboxylate ligand

Abstract

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