[Ni(C10H8N2)3] 2[V4O12].11H2O

Guo Yu Yang; Da Wei Gao; Ying Chen; Ji Qing Xu; Qing Xin Zeng; Hao Ran Sun; Zhi Wu Pei; Qiang Su; Yan Xing; Yong Hua Ling; Heng Qing Jia

doi:10.1107/S0108270197018751

[Ni(C₁₀H₈N₂)₃] ₂[V₄O₁₂].11H₂O

Guo Yu Yang^*
, Da Wei Gao
, Ying Chen
, Ji Qing Xu
, Qing Xin Zeng
, Hao Ran Sun
, Zhi Wu Pei
, Qiang Su
, Yan Xing
, Yong Hua Ling
, Heng Qing Jia

^*Corresponding author for this work

Jilin University
CAS - Changchun Institute of Applied Chemistry

Research output: Contribution to journal › Article › peer-review

29 Citations (Scopus)

Abstract

The crystal structure of the title compound, bis[tris(2,2́-bipyridyl-N,N′)nickel(II)] cyclo-tetravanadate undecahydrate, contains a centrosymmetric [V₄O₁₂]₄- anion, which has an eight-membered ring structure formed by four VO₄ tetrahedra sharing vertices, and two complex cations containing octahedrally-coordinated Ni^II ions. The anion and coordinated Ni^II ions are isolated and make up anion and cation layers, respectively. The Ni-N distances range from 2.077 (3) to 2.112 (2) Å and the V-O distances range from 1.621 (2) to 1.803 (2) Å.

Original language	English
Pages (from-to)	616-618
Number of pages	3
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	54
Issue number	5
DOIs	https://doi.org/10.1107/S0108270197018751
Publication status	Published - 15 May 1998
Externally published	Yes

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@article{19aad9c465a44141b5a656ceaa4c0631,

title = "[Ni(C10H8N2)3] 2[V4O12].11H2O",

abstract = "The crystal structure of the title compound, bis[tris(2,{\'2}-bipyridyl-N,N′)nickel(II)] cyclo-tetravanadate undecahydrate, contains a centrosymmetric [V4O12]4- anion, which has an eight-membered ring structure formed by four VO4 tetrahedra sharing vertices, and two complex cations containing octahedrally-coordinated NiII ions. The anion and coordinated NiII ions are isolated and make up anion and cation layers, respectively. The Ni-N distances range from 2.077 (3) to 2.112 (2) {\AA} and the V-O distances range from 1.621 (2) to 1.803 (2) {\AA}.",

author = "Yang, \{Guo Yu\} and Gao, \{Da Wei\} and Ying Chen and Xu, \{Ji Qing\} and Zeng, \{Qing Xin\} and Sun, \{Hao Ran\} and Pei, \{Zhi Wu\} and Qiang Su and Yan Xing and Ling, \{Yong Hua\} and Jia, \{Heng Qing\}",

year = "1998",

month = may,

day = "15",

doi = "10.1107/S0108270197018751",

language = "English",

volume = "54",

pages = "616--618",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

number = "5",

}

TY - JOUR

T1 - [Ni(C10H8N2)3] 2[V4O12].11H2O

AU - Yang, Guo Yu

AU - Gao, Da Wei

AU - Chen, Ying

AU - Xu, Ji Qing

AU - Zeng, Qing Xin

AU - Sun, Hao Ran

AU - Pei, Zhi Wu

AU - Su, Qiang

AU - Xing, Yan

AU - Ling, Yong Hua

AU - Jia, Heng Qing

PY - 1998/5/15

Y1 - 1998/5/15

N2 - The crystal structure of the title compound, bis[tris(2,2́-bipyridyl-N,N′)nickel(II)] cyclo-tetravanadate undecahydrate, contains a centrosymmetric [V4O12]4- anion, which has an eight-membered ring structure formed by four VO4 tetrahedra sharing vertices, and two complex cations containing octahedrally-coordinated NiII ions. The anion and coordinated NiII ions are isolated and make up anion and cation layers, respectively. The Ni-N distances range from 2.077 (3) to 2.112 (2) Å and the V-O distances range from 1.621 (2) to 1.803 (2) Å.

AB - The crystal structure of the title compound, bis[tris(2,2́-bipyridyl-N,N′)nickel(II)] cyclo-tetravanadate undecahydrate, contains a centrosymmetric [V4O12]4- anion, which has an eight-membered ring structure formed by four VO4 tetrahedra sharing vertices, and two complex cations containing octahedrally-coordinated NiII ions. The anion and coordinated NiII ions are isolated and make up anion and cation layers, respectively. The Ni-N distances range from 2.077 (3) to 2.112 (2) Å and the V-O distances range from 1.621 (2) to 1.803 (2) Å.

UR - https://www.scopus.com/pages/publications/0001178520

U2 - 10.1107/S0108270197018751

DO - 10.1107/S0108270197018751

M3 - Article

AN - SCOPUS:0001178520

SN - 0108-2701

VL - 54

SP - 616

EP - 618

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 5

ER -

[Ni(C₁₀H₈N₂)₃] ₂[V₄O₁₂].11H₂O

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