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(NH4)2Na3(V3 W3O19).12H2O

  • Yan Xu
  • , Ji Qing Xu*
  • , Guo Yu Yang
  • , Tie Gang Wang
  • , Yan Xing
  • , Yong Hua Lin
  • , Heng Qing Jia
  • *Corresponding author for this work
  • Juin University
  • CAS - Changchun Institute of Applied Chemistry

Research output: Contribution to journalArticlepeer-review

Abstract

(NH4)2Na3(V3W3O 19). 12H2O, diammonium trisodium nonadecaoxo(tritungsto)trivanadate dodecahydrate, is a mixed V/W salt in which each site has an approximately equal population of V and W atoms. The centrosymmetric polyanion consists of six (V/W)O6 edge-sharing distorted octahedra and has a well established structure. Each of the three Na+ cations is surrounded by six water molecules in a distorted octahedron. The (V/W) - O distances are between 1.644 (14) and 2.2885 (10)Å.

Original languageEnglish
Pages (from-to)563-565
Number of pages3
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume54
Issue number5
DOIs
Publication statusPublished - 15 May 1998
Externally publishedYes

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