Near-infrared photothermal conversion of stable radicals photoinduced from a viologen-based coordination polymer

Shanshan Wang; Shuning Li; Junyu Xiong; Zhengguo Lin; Wei Wei; Yanqing Xu

doi:10.1039/d0cc02193h

Near-infrared photothermal conversion of stable radicals photoinduced from a viologen-based coordination polymer

Shanshan Wang
, Shuning Li
, Junyu Xiong
, Zhengguo Lin
, Wei Wei
, Yanqing Xu^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

71 Citations (Scopus)

Abstract

Upon simple UV-visible irradiation, a viologen-based coordination polymer was transformed to a highly stable radical, protected against quenching by a densely packed structure. The photo-generated radical exhibited a remarkable near-infrared (NIR) photothermal effect with good recyclability and high conversion efficiency. To our knowledge, this is the first example of a crystalline viologen-based coordination polymer that functions as a NIR photothermal material by forming stable radicals.

Original language	English
Pages (from-to)	7399-7402
Number of pages	4
Journal	Chemical Communications
Volume	56
Issue number	54
DOIs	https://doi.org/10.1039/d0cc02193h
Publication status	Published - 11 Jul 2020
Externally published	Yes

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abstract = "Upon simple UV-visible irradiation, a viologen-based coordination polymer was transformed to a highly stable radical, protected against quenching by a densely packed structure. The photo-generated radical exhibited a remarkable near-infrared (NIR) photothermal effect with good recyclability and high conversion efficiency. To our knowledge, this is the first example of a crystalline viologen-based coordination polymer that functions as a NIR photothermal material by forming stable radicals.",

author = "Shanshan Wang and Shuning Li and Junyu Xiong and Zhengguo Lin and Wei Wei and Yanqing Xu",

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T1 - Near-infrared photothermal conversion of stable radicals photoinduced from a viologen-based coordination polymer

AU - Wang, Shanshan

AU - Li, Shuning

AU - Xiong, Junyu

AU - Lin, Zhengguo

AU - Wei, Wei

AU - Xu, Yanqing

N1 - Publisher Copyright: © The Royal Society of Chemistry.

PY - 2020/7/11

Y1 - 2020/7/11

N2 - Upon simple UV-visible irradiation, a viologen-based coordination polymer was transformed to a highly stable radical, protected against quenching by a densely packed structure. The photo-generated radical exhibited a remarkable near-infrared (NIR) photothermal effect with good recyclability and high conversion efficiency. To our knowledge, this is the first example of a crystalline viologen-based coordination polymer that functions as a NIR photothermal material by forming stable radicals.

AB - Upon simple UV-visible irradiation, a viologen-based coordination polymer was transformed to a highly stable radical, protected against quenching by a densely packed structure. The photo-generated radical exhibited a remarkable near-infrared (NIR) photothermal effect with good recyclability and high conversion efficiency. To our knowledge, this is the first example of a crystalline viologen-based coordination polymer that functions as a NIR photothermal material by forming stable radicals.

UR - https://www.scopus.com/pages/publications/85087763073

U2 - 10.1039/d0cc02193h

DO - 10.1039/d0cc02193h

M3 - Article

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AN - SCOPUS:85087763073

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VL - 56

SP - 7399

EP - 7402

JO - Chemical Communications

JF - Chemical Communications

IS - 54

ER -

Near-infrared photothermal conversion of stable radicals photoinduced from a viologen-based coordination polymer

Abstract

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