NaxMV(PO4)3 (M = Mn, Fe, Ni) Structure and Properties for Sodium Extraction

Weidong Zhou; Leigang Xue; Xujie Lü; Hongcai Gao; Yutao Li; Sen Xin; Gengtao Fu; Zhiming Cui; Ye Zhu; John B. Goodenough

doi:10.1021/acs.nanolett.6b04044

Na_xMV(PO₄)₃ (M = Mn, Fe, Ni) Structure and Properties for Sodium Extraction

Weidong Zhou
, Leigang Xue
, Xujie Lü
, Hongcai Gao
, Yutao Li^*
, Sen Xin
, Gengtao Fu
, Zhiming Cui
, Ye Zhu
, John B. Goodenough

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

344 Citations (Scopus)

Abstract

NASICON (Na⁺ super ionic conductor) structures of Na_xMV(PO₄)₃ (M = Mn, Fe, Ni) were prepared, characterized by aberration-corrected STEM and synchrotron radiation, and demonstrated to be durable cathode materials for rechargeable sodium-ion batteries. In Na₄MnV(PO₄)₃, two redox couples of Mn³⁺/Mn²⁺ and V⁴⁺/V³⁺ are accessed with two voltage plateaus located at 3.6 and 3.3 V and a capacity of 101 mAh g^-1 at 1 C. Furthermore, the Na₄MnV(PO₄)₃ cathode delivers a high initial efficiency of 97%, long durability over 1000 cycles, and good rate performance to 10 C. The robust framework structure and stable electrochemical performance makes it a reliable cathode materials for sodium-ion batteries.

Original language	English
Pages (from-to)	7836-7841
Number of pages	6
Journal	Nano Letters
Volume	16
Issue number	12
DOIs	https://doi.org/10.1021/acs.nanolett.6b04044
Publication status	Published - 14 Dec 2016
Externally published	Yes

Keywords

Na transport
STEM
Sodium cathodes
framework oxide
manganese oxidation

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10.1021/acs.nanolett.6b04044

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title = "NaxMV(PO4)3 (M = Mn, Fe, Ni) Structure and Properties for Sodium Extraction",

abstract = "NASICON (Na+ super ionic conductor) structures of NaxMV(PO4)3 (M = Mn, Fe, Ni) were prepared, characterized by aberration-corrected STEM and synchrotron radiation, and demonstrated to be durable cathode materials for rechargeable sodium-ion batteries. In Na4MnV(PO4)3, two redox couples of Mn3+/Mn2+ and V4+/V3+ are accessed with two voltage plateaus located at 3.6 and 3.3 V and a capacity of 101 mAh g-1 at 1 C. Furthermore, the Na4MnV(PO4)3 cathode delivers a high initial efficiency of 97\%, long durability over 1000 cycles, and good rate performance to 10 C. The robust framework structure and stable electrochemical performance makes it a reliable cathode materials for sodium-ion batteries.",

keywords = "Na transport, STEM, Sodium cathodes, framework oxide, manganese oxidation",

author = "Weidong Zhou and Leigang Xue and Xujie L{\"u} and Hongcai Gao and Yutao Li and Sen Xin and Gengtao Fu and Zhiming Cui and Ye Zhu and Goodenough, \{John B.\}",

note = "Publisher Copyright: {\textcopyright} 2016 American Chemical Society.",

year = "2016",

month = dec,

day = "14",

doi = "10.1021/acs.nanolett.6b04044",

language = "English",

volume = "16",

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journal = "Nano Letters",

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TY - JOUR

T1 - NaxMV(PO4)3 (M = Mn, Fe, Ni) Structure and Properties for Sodium Extraction

AU - Zhou, Weidong

AU - Xue, Leigang

AU - Lü, Xujie

AU - Gao, Hongcai

AU - Li, Yutao

AU - Xin, Sen

AU - Fu, Gengtao

AU - Cui, Zhiming

AU - Zhu, Ye

AU - Goodenough, John B.

PY - 2016/12/14

Y1 - 2016/12/14

N2 - NASICON (Na+ super ionic conductor) structures of NaxMV(PO4)3 (M = Mn, Fe, Ni) were prepared, characterized by aberration-corrected STEM and synchrotron radiation, and demonstrated to be durable cathode materials for rechargeable sodium-ion batteries. In Na4MnV(PO4)3, two redox couples of Mn3+/Mn2+ and V4+/V3+ are accessed with two voltage plateaus located at 3.6 and 3.3 V and a capacity of 101 mAh g-1 at 1 C. Furthermore, the Na4MnV(PO4)3 cathode delivers a high initial efficiency of 97%, long durability over 1000 cycles, and good rate performance to 10 C. The robust framework structure and stable electrochemical performance makes it a reliable cathode materials for sodium-ion batteries.

AB - NASICON (Na+ super ionic conductor) structures of NaxMV(PO4)3 (M = Mn, Fe, Ni) were prepared, characterized by aberration-corrected STEM and synchrotron radiation, and demonstrated to be durable cathode materials for rechargeable sodium-ion batteries. In Na4MnV(PO4)3, two redox couples of Mn3+/Mn2+ and V4+/V3+ are accessed with two voltage plateaus located at 3.6 and 3.3 V and a capacity of 101 mAh g-1 at 1 C. Furthermore, the Na4MnV(PO4)3 cathode delivers a high initial efficiency of 97%, long durability over 1000 cycles, and good rate performance to 10 C. The robust framework structure and stable electrochemical performance makes it a reliable cathode materials for sodium-ion batteries.

KW - Na transport

KW - STEM

KW - Sodium cathodes

KW - framework oxide

KW - manganese oxidation

UR - https://www.scopus.com/pages/publications/85006246894

U2 - 10.1021/acs.nanolett.6b04044

DO - 10.1021/acs.nanolett.6b04044

M3 - Article

AN - SCOPUS:85006246894

SN - 1530-6984

VL - 16

SP - 7836

EP - 7841

JO - Nano Letters

JF - Nano Letters

IS - 12

ER -

Na_xMV(PO₄)₃ (M = Mn, Fe, Ni) Structure and Properties for Sodium Extraction

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Keywords

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