Nanomechanical Characterization of Plasma-Sprayed Nanostructured Yb₄Hf₃O₁₂ Thermal/Environmental Barrier Coatings

Thermal/environmental barrier coatings (T/EBCs) have become a notable research field for the development of high-performance thermal protection coatings. The mechanical properties are essential for T/EBCs, which determine the functionality, reliability and durability of coatings. The Yb₄Hf₃O₁₂ TEBCs were prepared by atmospheric plasma spraying using nanostructured spherical feedstocks and the nanomechanical properties of the Yb₄Hf₃O₁₂ coatings were characterized by nano-indentation in this work. Results indicate the elastic indentation work (W_e) is 16.06 ± 1.45 nJ and the plastic indentation work is 28.62 ± 6.87 nJ for nanostructured Yb₄Hf₃O₁₂ coatings. The ratio of plastic work to total deformation work during indentation as the energy dissipation parameter (η) is 0.63 ± 0.05 for nanostructured Yb₄Hf₃O₁₂ coatings and it can be preliminarily inferred that the Yb₄Hf₃O₁₂ coating may possess favorable erosion resistance, although direct erosion testing is needed for confirmation.