[Mo8S4O12(OH)8(C 2O4)]: A novel polyoxothiomolybdate ring synthesized via a hydrothermal method

Xiao Ping Zhan; Can Zhong Lu; Wen Bin Yang; Hong Wei Ma; Chuan De Wu; Quan Zheng Zhang

doi:10.1039/b300828b

[Mo₈S₄O₁₂(OH)₈(C ₂O₄)]: A novel polyoxothiomolybdate ring synthesized via a hydrothermal method

Xiao Ping Zhan
, Can Zhong Lu^*
, Wen Bin Yang
, Hong Wei Ma
, Chuan De Wu
, Quan Zheng Zhang

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

A hydrothermally synthesized new octameric ring, [Mo₈S ₄O₁₂(OH)₈(C₂O ₄)] formed by edge-sharing Mo₂(S)O₃ building blocks was investigated. The significance of this method was that it presented another method to obtain new polyoxothiomolybdates and more novel ring-shaped compounds can be obtained by addition of suitable carboxylates as templates. The x-ray study revealed that its ring-shaped backbone was built by four novel building blocks. The inner-diameter of the neutral cyclic compound was found to be about 7.76 Å.

Original language	English
Pages (from-to)	1457-1458
Number of pages	2
Journal	Dalton Transactions
Issue number	8
DOIs	https://doi.org/10.1039/b300828b
Publication status	Published - 21 Apr 2003
Externally published	Yes

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10.1039/b300828b

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title = "[Mo8S4O12(OH)8(C 2O4)]: A novel polyoxothiomolybdate ring synthesized via a hydrothermal method",

abstract = "A hydrothermally synthesized new octameric ring, [Mo8S 4O12(OH)8(C2O 4)] formed by edge-sharing Mo2(S)O3 building blocks was investigated. The significance of this method was that it presented another method to obtain new polyoxothiomolybdates and more novel ring-shaped compounds can be obtained by addition of suitable carboxylates as templates. The x-ray study revealed that its ring-shaped backbone was built by four novel building blocks. The inner-diameter of the neutral cyclic compound was found to be about 7.76 {\AA}.",

author = "Zhan, \{Xiao Ping\} and Lu, \{Can Zhong\} and Yang, \{Wen Bin\} and Ma, \{Hong Wei\} and Wu, \{Chuan De\} and Zhang, \{Quan Zheng\}",

year = "2003",

month = apr,

day = "21",

doi = "10.1039/b300828b",

language = "English",

pages = "1457--1458",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "8",

}

TY - JOUR

T1 - [Mo8S4O12(OH)8(C 2O4)]

T2 - A novel polyoxothiomolybdate ring synthesized via a hydrothermal method

AU - Zhan, Xiao Ping

AU - Lu, Can Zhong

AU - Yang, Wen Bin

AU - Ma, Hong Wei

AU - Wu, Chuan De

AU - Zhang, Quan Zheng

PY - 2003/4/21

Y1 - 2003/4/21

N2 - A hydrothermally synthesized new octameric ring, [Mo8S 4O12(OH)8(C2O 4)] formed by edge-sharing Mo2(S)O3 building blocks was investigated. The significance of this method was that it presented another method to obtain new polyoxothiomolybdates and more novel ring-shaped compounds can be obtained by addition of suitable carboxylates as templates. The x-ray study revealed that its ring-shaped backbone was built by four novel building blocks. The inner-diameter of the neutral cyclic compound was found to be about 7.76 Å.

AB - A hydrothermally synthesized new octameric ring, [Mo8S 4O12(OH)8(C2O 4)] formed by edge-sharing Mo2(S)O3 building blocks was investigated. The significance of this method was that it presented another method to obtain new polyoxothiomolybdates and more novel ring-shaped compounds can be obtained by addition of suitable carboxylates as templates. The x-ray study revealed that its ring-shaped backbone was built by four novel building blocks. The inner-diameter of the neutral cyclic compound was found to be about 7.76 Å.

UR - https://www.scopus.com/pages/publications/23944466373

U2 - 10.1039/b300828b

DO - 10.1039/b300828b

M3 - Article

AN - SCOPUS:23944466373

SN - 1477-9226

SP - 1457

EP - 1458

JO - Dalton Transactions

JF - Dalton Transactions

IS - 8

ER -

[Mo₈S₄O₁₂(OH)₈(C ₂O₄)]: A novel polyoxothiomolybdate ring synthesized via a hydrothermal method

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