Mild, efficient and highly selective hydrolysis of acetonides with antimony trichloride (supporting information)

Qinpei Wu; Wei Chen; Yuang Wang; Yunbo Qu; Qingshan Zhang

doi:10.2174/157017806776114630

Mild, efficient and highly selective hydrolysis of acetonides with antimony trichloride (supporting information)

Qinpei Wu^*
, Wei Chen
, Yuang Wang
, Yunbo Qu
, Qingshan Zhang

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

A mild and efficient procedure for chemoselective and regioselective hydrolysis of acetonide with SbCl₃ in the presence of other frequently used hydroxy protecting groups, TBDMS, TBDPS, Bz, Bn, Ac, Ts and Tr, was described. The mechanism was examined and proposed.

Original language	English
Pages (from-to)	271-274
Number of pages	4
Journal	Letters in Organic Chemistry
Volume	3
Issue number	4
DOIs	https://doi.org/10.2174/157017806776114630
Publication status	Published - Apr 2006

Keywords

Acetonide
Antimony
Catalysis
Hydrolysis
Lewis acid
Protecting groups

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10.2174/157017806776114630

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title = "Mild, efficient and highly selective hydrolysis of acetonides with antimony trichloride (supporting information)",

abstract = "A mild and efficient procedure for chemoselective and regioselective hydrolysis of acetonide with SbCl3 in the presence of other frequently used hydroxy protecting groups, TBDMS, TBDPS, Bz, Bn, Ac, Ts and Tr, was described. The mechanism was examined and proposed.",

keywords = "Acetonide, Antimony, Catalysis, Hydrolysis, Lewis acid, Protecting groups",

author = "Qinpei Wu and Wei Chen and Yuang Wang and Yunbo Qu and Qingshan Zhang",

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doi = "10.2174/157017806776114630",

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TY - JOUR

T1 - Mild, efficient and highly selective hydrolysis of acetonides with antimony trichloride (supporting information)

AU - Wu, Qinpei

AU - Chen, Wei

AU - Wang, Yuang

AU - Qu, Yunbo

AU - Zhang, Qingshan

PY - 2006/4

Y1 - 2006/4

N2 - A mild and efficient procedure for chemoselective and regioselective hydrolysis of acetonide with SbCl3 in the presence of other frequently used hydroxy protecting groups, TBDMS, TBDPS, Bz, Bn, Ac, Ts and Tr, was described. The mechanism was examined and proposed.

AB - A mild and efficient procedure for chemoselective and regioselective hydrolysis of acetonide with SbCl3 in the presence of other frequently used hydroxy protecting groups, TBDMS, TBDPS, Bz, Bn, Ac, Ts and Tr, was described. The mechanism was examined and proposed.

KW - Acetonide

KW - Antimony

KW - Catalysis

KW - Hydrolysis

KW - Lewis acid

KW - Protecting groups

UR - https://www.scopus.com/pages/publications/33746159869

U2 - 10.2174/157017806776114630

DO - 10.2174/157017806776114630

M3 - Article

AN - SCOPUS:33746159869

SN - 1570-1786

VL - 3

SP - 271

EP - 274

JO - Letters in Organic Chemistry

JF - Letters in Organic Chemistry

IS - 4

ER -

Mild, efficient and highly selective hydrolysis of acetonides with antimony trichloride (supporting information)

Abstract

Keywords

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