Metal-Organic Layers Efficiently Catalyze Photoinduced Polymerization under Visible Light

Ruoyu Xu; Zhengxu Cai; Guangxu Lan; Wenbin Lin

doi:10.1021/acs.inorgchem.8b01637

Metal-Organic Layers Efficiently Catalyze Photoinduced Polymerization under Visible Light

Ruoyu Xu
, Zhengxu Cai
, Guangxu Lan
, Wenbin Lin

The University of Chicago

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

A photosensitizing metal-organic layer (MOL), IrBPY-MOL, based on hafnium-oxo clusters and cyclometalated iridium-complex-derived organic linkers, was synthesized and used as an efficient catalyst for photopolymerization of methyl methacrylate and other monomers to afford polymers with high-number-averaged molar masses and low polydispersity indices. The corresponding metal-organic framework (MOF) failed to photopolymerize or exhibited low catalytic efficiency under identical conditions. This work highlights the advantages of MOLs over their MOF counterparts in overcoming pore-size and diffusion limitations in photopolymerization reactions.

Original language	English
Pages (from-to)	10489-10493
Number of pages	5
Journal	Inorganic Chemistry
Volume	57
Issue number	17
DOIs	https://doi.org/10.1021/acs.inorgchem.8b01637
Publication status	Published - 4 Sept 2018
Externally published	Yes

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title = "Metal-Organic Layers Efficiently Catalyze Photoinduced Polymerization under Visible Light",

abstract = "A photosensitizing metal-organic layer (MOL), IrBPY-MOL, based on hafnium-oxo clusters and cyclometalated iridium-complex-derived organic linkers, was synthesized and used as an efficient catalyst for photopolymerization of methyl methacrylate and other monomers to afford polymers with high-number-averaged molar masses and low polydispersity indices. The corresponding metal-organic framework (MOF) failed to photopolymerize or exhibited low catalytic efficiency under identical conditions. This work highlights the advantages of MOLs over their MOF counterparts in overcoming pore-size and diffusion limitations in photopolymerization reactions.",

author = "Ruoyu Xu and Zhengxu Cai and Guangxu Lan and Wenbin Lin",

note = "Publisher Copyright: Copyright {\textcopyright} 2018 American Chemical Society.",

year = "2018",

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doi = "10.1021/acs.inorgchem.8b01637",

language = "English",

volume = "57",

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journal = "Inorganic Chemistry",

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T1 - Metal-Organic Layers Efficiently Catalyze Photoinduced Polymerization under Visible Light

AU - Xu, Ruoyu

AU - Cai, Zhengxu

AU - Lan, Guangxu

AU - Lin, Wenbin

PY - 2018/9/4

Y1 - 2018/9/4

N2 - A photosensitizing metal-organic layer (MOL), IrBPY-MOL, based on hafnium-oxo clusters and cyclometalated iridium-complex-derived organic linkers, was synthesized and used as an efficient catalyst for photopolymerization of methyl methacrylate and other monomers to afford polymers with high-number-averaged molar masses and low polydispersity indices. The corresponding metal-organic framework (MOF) failed to photopolymerize or exhibited low catalytic efficiency under identical conditions. This work highlights the advantages of MOLs over their MOF counterparts in overcoming pore-size and diffusion limitations in photopolymerization reactions.

AB - A photosensitizing metal-organic layer (MOL), IrBPY-MOL, based on hafnium-oxo clusters and cyclometalated iridium-complex-derived organic linkers, was synthesized and used as an efficient catalyst for photopolymerization of methyl methacrylate and other monomers to afford polymers with high-number-averaged molar masses and low polydispersity indices. The corresponding metal-organic framework (MOF) failed to photopolymerize or exhibited low catalytic efficiency under identical conditions. This work highlights the advantages of MOLs over their MOF counterparts in overcoming pore-size and diffusion limitations in photopolymerization reactions.

UR - https://www.scopus.com/pages/publications/85053063575

U2 - 10.1021/acs.inorgchem.8b01637

DO - 10.1021/acs.inorgchem.8b01637

M3 - Article

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AN - SCOPUS:85053063575

SN - 0020-1669

VL - 57

SP - 10489

EP - 10493

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 17

ER -

Metal-Organic Layers Efficiently Catalyze Photoinduced Polymerization under Visible Light

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