Magnetic nanosized {M II 24}-wheel-based (M = Co, Ni) coordination polymers

Jia Li; Jun Tao; Rong Bin Huang; Lan Sun Zheng

doi:10.1021/ic300487a

Magnetic nanosized {M ^II ₂₄}-wheel-based (M = Co, Ni) coordination polymers

Jia Li, Jun Tao^*, Rong Bin Huang, Lan Sun Zheng

^*Corresponding author for this work

Xiamen University

Research output: Contribution to journal › Article › peer-review

65 Citations (Scopus)

Abstract

Two 3D coordination polymers, [Co ₂₄(OH) ₁₂(SO ₄) ₁₂(ip) ₆(DMSO) ₁₈(H ₂O) ₆](DMSO) ₆(EtOH) ₆(H ₂O) ₃₆ (1guests, ip = isophthalate) and [Ni ₂₄(OH) ₁₂(SO ₄) ₁₂(ip) ₆(DMSO) ₁₂(H ₂O) ₁₂](DMSO) ₆(EtOH) ₆(H ₂O) ₂₀ (2guests), constructed with nanosized tetraicosanuclear Co ^II and Ni ^II wheels are solvothermally synthesized. Both complexes show intra- and interwheel dominant antiferromagnetic interactions.

Original language	English
Pages (from-to)	5988-5990
Number of pages	3
Journal	Inorganic Chemistry
Volume	51
Issue number	11
DOIs	https://doi.org/10.1021/ic300487a
Publication status	Published - 4 Jun 2012
Externally published	Yes

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title = "Magnetic nanosized {M II 24}-wheel-based (M = Co, Ni) coordination polymers",

abstract = "Two 3D coordination polymers, [Co 24(OH) 12(SO 4) 12(ip) 6(DMSO) 18(H 2O) 6](DMSO) 6(EtOH) 6(H 2O) 36 (1guests, ip = isophthalate) and [Ni 24(OH) 12(SO 4) 12(ip) 6(DMSO) 12(H 2O) 12](DMSO) 6(EtOH) 6(H 2O) 20 (2guests), constructed with nanosized tetraicosanuclear Co II and Ni II wheels are solvothermally synthesized. Both complexes show intra- and interwheel dominant antiferromagnetic interactions.",

author = "Jia Li and Jun Tao and Huang, {Rong Bin} and Zheng, {Lan Sun}",

year = "2012",

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T1 - Magnetic nanosized {M II 24}-wheel-based (M = Co, Ni) coordination polymers

AU - Li, Jia

AU - Tao, Jun

AU - Huang, Rong Bin

AU - Zheng, Lan Sun

PY - 2012/6/4

Y1 - 2012/6/4

N2 - Two 3D coordination polymers, [Co 24(OH) 12(SO 4) 12(ip) 6(DMSO) 18(H 2O) 6](DMSO) 6(EtOH) 6(H 2O) 36 (1guests, ip = isophthalate) and [Ni 24(OH) 12(SO 4) 12(ip) 6(DMSO) 12(H 2O) 12](DMSO) 6(EtOH) 6(H 2O) 20 (2guests), constructed with nanosized tetraicosanuclear Co II and Ni II wheels are solvothermally synthesized. Both complexes show intra- and interwheel dominant antiferromagnetic interactions.

AB - Two 3D coordination polymers, [Co 24(OH) 12(SO 4) 12(ip) 6(DMSO) 18(H 2O) 6](DMSO) 6(EtOH) 6(H 2O) 36 (1guests, ip = isophthalate) and [Ni 24(OH) 12(SO 4) 12(ip) 6(DMSO) 12(H 2O) 12](DMSO) 6(EtOH) 6(H 2O) 20 (2guests), constructed with nanosized tetraicosanuclear Co II and Ni II wheels are solvothermally synthesized. Both complexes show intra- and interwheel dominant antiferromagnetic interactions.

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JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 11

ER -

Magnetic nanosized {M ^II ₂₄}-wheel-based (M = Co, Ni) coordination polymers

Abstract

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