Magnetic-Field Controllable Displacement-Type Ferroelectricity Driven by Off-Center Fe2+ Ions in CaFe3Ti4O12 Perovskite

Dabiao Lu; Denis Sheptyakov; Yingying Cao; Haoting Zhao; Jie Zhang; Maocai Pi; Xubin Ye; Zhehong Liu; Xueqiang Zhang; Zhao Pan; Xingxing Jiang; Zhiwei Hu; Yi feng Yang; Pu Yu; Youwen Long

doi:10.1002/adfm.202411133

Magnetic-Field Controllable Displacement-Type Ferroelectricity Driven by Off-Center Fe²⁺ Ions in CaFe₃Ti₄O₁₂ Perovskite

Dabiao Lu
, Denis Sheptyakov
, Yingying Cao
, Haoting Zhao
, Jie Zhang
, Maocai Pi
, Xubin Ye
, Zhehong Liu
, Xueqiang Zhang
, Zhao Pan
, Xingxing Jiang
, Zhiwei Hu
, Yi feng Yang
, Pu Yu
, Youwen Long^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

Displacement-type ferroelectrics usually exclude magnetic d-electron contribution. Applying a magnetic field thus can little change the electric polarization. Herein, a magnetic ionic driven displacement-type perovskite ferroelectric CaFe₃Ti₄O₁₂ is reported. In this compound, magnetic Fe²⁺ ions contribute to both ferroelectric and antiferromagnetic orders respectively at T_C ≈107 and T_N ≈ 3.1 K, resulting in coupled electric and magnetic domains. A moderate magnetic field can induce a metamagnetic transition toward ferromagnetic correlations. External magnetic fields can thus readily tune the magnetic and the joint ferroelectric domains, giving rise to exceptional magnetic-field controllable displacement-type polarization with a large magnetoelectric (ME) coupling coefficient. This study opens up a new avenue to find unprecedented ME effects in displacement-type ferroelectrics for numerous applications.

Original language	English
Article number	2411133
Journal	Advanced Functional Materials
Volume	34
Issue number	52
DOIs	https://doi.org/10.1002/adfm.202411133
Publication status	Published - 23 Dec 2024
Externally published	Yes

Keywords

A-site ordered perovskite
displacement-type ferroelectric
high-pressure synthesis
magnetoelectric coupling

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10.1002/adfm.202411133

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Lu, D., Sheptyakov, D., Cao, Y., Zhao, H., Zhang, J., Pi, M., Ye, X., Liu, Z., Zhang, X., Pan, Z., Jiang, X., Hu, Z., Yang, Y. F., Yu, P., & Long, Y. (2024). Magnetic-Field Controllable Displacement-Type Ferroelectricity Driven by Off-Center Fe²⁺ Ions in CaFe₃Ti₄O₁₂ Perovskite. Advanced Functional Materials, 34(52), Article 2411133. https://doi.org/10.1002/adfm.202411133

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title = "Magnetic-Field Controllable Displacement-Type Ferroelectricity Driven by Off-Center Fe2+ Ions in CaFe3Ti4O12 Perovskite",

abstract = "Displacement-type ferroelectrics usually exclude magnetic d-electron contribution. Applying a magnetic field thus can little change the electric polarization. Herein, a magnetic ionic driven displacement-type perovskite ferroelectric CaFe3Ti4O12 is reported. In this compound, magnetic Fe2+ ions contribute to both ferroelectric and antiferromagnetic orders respectively at TC ≈107 and TN ≈ 3.1 K, resulting in coupled electric and magnetic domains. A moderate magnetic field can induce a metamagnetic transition toward ferromagnetic correlations. External magnetic fields can thus readily tune the magnetic and the joint ferroelectric domains, giving rise to exceptional magnetic-field controllable displacement-type polarization with a large magnetoelectric (ME) coupling coefficient. This study opens up a new avenue to find unprecedented ME effects in displacement-type ferroelectrics for numerous applications.",

keywords = "A-site ordered perovskite, displacement-type ferroelectric, high-pressure synthesis, magnetoelectric coupling",

author = "Dabiao Lu and Denis Sheptyakov and Yingying Cao and Haoting Zhao and Jie Zhang and Maocai Pi and Xubin Ye and Zhehong Liu and Xueqiang Zhang and Zhao Pan and Xingxing Jiang and Zhiwei Hu and Yang, \{Yi feng\} and Pu Yu and Youwen Long",

note = "Publisher Copyright: {\textcopyright} 2024 Wiley-VCH GmbH.",

year = "2024",

month = dec,

day = "23",

doi = "10.1002/adfm.202411133",

language = "English",

volume = "34",

journal = "Advanced Functional Materials",

issn = "1616-301X",

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TY - JOUR

T1 - Magnetic-Field Controllable Displacement-Type Ferroelectricity Driven by Off-Center Fe2+ Ions in CaFe3Ti4O12 Perovskite

AU - Lu, Dabiao

AU - Sheptyakov, Denis

AU - Cao, Yingying

AU - Zhao, Haoting

AU - Zhang, Jie

AU - Pi, Maocai

AU - Ye, Xubin

AU - Liu, Zhehong

AU - Zhang, Xueqiang

AU - Pan, Zhao

AU - Jiang, Xingxing

AU - Hu, Zhiwei

AU - Yang, Yi feng

AU - Yu, Pu

AU - Long, Youwen

PY - 2024/12/23

Y1 - 2024/12/23

N2 - Displacement-type ferroelectrics usually exclude magnetic d-electron contribution. Applying a magnetic field thus can little change the electric polarization. Herein, a magnetic ionic driven displacement-type perovskite ferroelectric CaFe3Ti4O12 is reported. In this compound, magnetic Fe2+ ions contribute to both ferroelectric and antiferromagnetic orders respectively at TC ≈107 and TN ≈ 3.1 K, resulting in coupled electric and magnetic domains. A moderate magnetic field can induce a metamagnetic transition toward ferromagnetic correlations. External magnetic fields can thus readily tune the magnetic and the joint ferroelectric domains, giving rise to exceptional magnetic-field controllable displacement-type polarization with a large magnetoelectric (ME) coupling coefficient. This study opens up a new avenue to find unprecedented ME effects in displacement-type ferroelectrics for numerous applications.

AB - Displacement-type ferroelectrics usually exclude magnetic d-electron contribution. Applying a magnetic field thus can little change the electric polarization. Herein, a magnetic ionic driven displacement-type perovskite ferroelectric CaFe3Ti4O12 is reported. In this compound, magnetic Fe2+ ions contribute to both ferroelectric and antiferromagnetic orders respectively at TC ≈107 and TN ≈ 3.1 K, resulting in coupled electric and magnetic domains. A moderate magnetic field can induce a metamagnetic transition toward ferromagnetic correlations. External magnetic fields can thus readily tune the magnetic and the joint ferroelectric domains, giving rise to exceptional magnetic-field controllable displacement-type polarization with a large magnetoelectric (ME) coupling coefficient. This study opens up a new avenue to find unprecedented ME effects in displacement-type ferroelectrics for numerous applications.

KW - A-site ordered perovskite

KW - displacement-type ferroelectric

KW - high-pressure synthesis

KW - magnetoelectric coupling

UR - https://www.scopus.com/pages/publications/85201187190

U2 - 10.1002/adfm.202411133

DO - 10.1002/adfm.202411133

M3 - Article

AN - SCOPUS:85201187190

SN - 1616-301X

VL - 34

JO - Advanced Functional Materials

JF - Advanced Functional Materials

IS - 52

M1 - 2411133

ER -

Magnetic-Field Controllable Displacement-Type Ferroelectricity Driven by Off-Center Fe²⁺ Ions in CaFe₃Ti₄O₁₂ Perovskite

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Keywords

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