Magnesium-magnesium bond stabilized by a doubly reduced α-diimine: Synthesis and structure of [K(THF)3]2[LMg-MgL] (L ) [(2,6-iPr2C6H3)NC(Me)] 22-

Yanyan Liu; Shaoguang Li; Xiao Juan Yang; Peiju Yang; Biao Wu

doi:10.1021/ja900568c

Magnesium-magnesium bond stabilized by a doubly reduced α-diimine: Synthesis and structure of [K(THF)₃]₂[LMg-MgL] (L ) [(2,6-ⁱPr₂C₆H₃)NC(Me)] ₂^2-

Yanyan Liu^*
, Shaoguang Li
, Xiao Juan Yang
, Peiju Yang
, Biao Wu

^*Corresponding author for this work

CAS - Lanzhou Institute of Chemical Physics
Chinese Academy of Sciences
Lanzhou University

Research output: Contribution to journal › Article › peer-review

120 Citations (Scopus)

Abstract

A new Mg-Mg-bonded compound stabilized by a doubly reduced α-diimine ligand, [K(THF)₃]₂[LMg-MgL] (L = [(2,6-ⁱPr ₂C₆H₃)NC(Me)]₂ ^2-), has been synthesized and characterized by single-crystal X-ray diffraction and density functional theory analysis. The Mg-Mg bond length is 2.9370(18) Å.

Original language	English
Pages (from-to)	4210-4211
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	131
Issue number	12
DOIs	https://doi.org/10.1021/ja900568c
Publication status	Published - 1 Apr 2009
Externally published	Yes

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title = "Magnesium-magnesium bond stabilized by a doubly reduced α-diimine: Synthesis and structure of [K(THF)3]2[LMg-MgL] (L ) [(2,6-iPr2C6H3)NC(Me)] 22-",

abstract = "A new Mg-Mg-bonded compound stabilized by a doubly reduced α-diimine ligand, [K(THF)3]2[LMg-MgL] (L = [(2,6-iPr 2C6H3)NC(Me)]2 2-), has been synthesized and characterized by single-crystal X-ray diffraction and density functional theory analysis. The Mg-Mg bond length is 2.9370(18) {\AA}.",

author = "Yanyan Liu and Shaoguang Li and Yang, \{Xiao Juan\} and Peiju Yang and Biao Wu",

year = "2009",

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T1 - Magnesium-magnesium bond stabilized by a doubly reduced α-diimine

T2 - Synthesis and structure of [K(THF)3]2[LMg-MgL] (L ) [(2,6-iPr2C6H3)NC(Me)] 22-

AU - Liu, Yanyan

AU - Li, Shaoguang

AU - Yang, Xiao Juan

AU - Yang, Peiju

AU - Wu, Biao

PY - 2009/4/1

Y1 - 2009/4/1

N2 - A new Mg-Mg-bonded compound stabilized by a doubly reduced α-diimine ligand, [K(THF)3]2[LMg-MgL] (L = [(2,6-iPr 2C6H3)NC(Me)]2 2-), has been synthesized and characterized by single-crystal X-ray diffraction and density functional theory analysis. The Mg-Mg bond length is 2.9370(18) Å.

AB - A new Mg-Mg-bonded compound stabilized by a doubly reduced α-diimine ligand, [K(THF)3]2[LMg-MgL] (L = [(2,6-iPr 2C6H3)NC(Me)]2 2-), has been synthesized and characterized by single-crystal X-ray diffraction and density functional theory analysis. The Mg-Mg bond length is 2.9370(18) Å.

UR - https://www.scopus.com/pages/publications/67849102051

U2 - 10.1021/ja900568c

DO - 10.1021/ja900568c

M3 - Article

AN - SCOPUS:67849102051

SN - 0002-7863

VL - 131

SP - 4210

EP - 4211

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 12

ER -

Magnesium-magnesium bond stabilized by a doubly reduced α-diimine: Synthesis and structure of [K(THF)₃]₂[LMg-MgL] (L ) [(2,6-ⁱPr₂C₆H₃)NC(Me)] ₂^2-

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