TY - JOUR
T1 - Magnesium Azotetrazole-1,1′-dioxide
T2 - Synthesis and Promising Properties of Green Insensitive Energetic Materials
AU - He, Piao
AU - Zhang, Jian Guo
AU - Wu, Le
AU - Wu, Jin Ting
AU - Zhang, Tong Lai
N1 - Publisher Copyright:
© 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
PY - 2017/3/16
Y1 - 2017/3/16
N2 - Magnesium azotetrazole-1,1′-dioxide (1) was first prepared and intensively characterized by single-crystal X-ray diffraction, IR spectroscopy, mass spectrometry, elemental analysis, and DSC measurements. The heat of formation was calculated using the atomization energy method based on quantum chemistry and the heat of detonation was also predicted. The NBO analysis was performed for inspecting charge distributions. The sensitivities towards impact and friction were tested using the BAM standard. The high detonation performance (5289 kJ·kg–1), good thermal stabilities (245.5 °C) and excellent insensitivity (39.2 J and >360 N) as well as clean decomposition products supports it of great interest as a promising candidate of green insensitive energetic materials.
AB - Magnesium azotetrazole-1,1′-dioxide (1) was first prepared and intensively characterized by single-crystal X-ray diffraction, IR spectroscopy, mass spectrometry, elemental analysis, and DSC measurements. The heat of formation was calculated using the atomization energy method based on quantum chemistry and the heat of detonation was also predicted. The NBO analysis was performed for inspecting charge distributions. The sensitivities towards impact and friction were tested using the BAM standard. The high detonation performance (5289 kJ·kg–1), good thermal stabilities (245.5 °C) and excellent insensitivity (39.2 J and >360 N) as well as clean decomposition products supports it of great interest as a promising candidate of green insensitive energetic materials.
KW - Energetic materials; Azotetrazole-1,1′-dioxide; Magnesium; Crystal structures
KW - Heats of detonation; Sensitivity
UR - https://www.scopus.com/pages/publications/85013290318
U2 - 10.1002/zaac.201600471
DO - 10.1002/zaac.201600471
M3 - Article
AN - SCOPUS:85013290318
SN - 0044-2313
VL - 643
SP - 432
EP - 436
JO - Zeitschrift fur Anorganische und Allgemeine Chemie
JF - Zeitschrift fur Anorganische und Allgemeine Chemie
IS - 6
ER -