Abstract
B-doped ultrananocrystalline diamond (UNCD) films are grown using hot-filament chemical vapor deposition method, and their electrical transport properties varying with temperature are investigated. When the B-doped concentration of UNCD film is low, a step-like increase feature of the resistance is observed with decreasing temperature, reflecting at least three temperature-modified electronic state densities at the Fermi level according to three-dimensional Mott's variable range hopping transport mechanism, which is very different from that of reported B-doped nanodiamond. With increasing B-doped concentration, a superconductive transformation occurs in the UNCD film and the highest transformation temperature of 5.3K is observed, which is higher than that reported for superconducting nanodiamond films. In addition, the superconducting coherence length is about 0.63nm, which breaks a reported theoretical and experimental prediction about ultra-nanoscale diamond's superconductivity.
| Original language | English |
|---|---|
| Article number | 182602 |
| Journal | Applied Physics Letters |
| Volume | 104 |
| Issue number | 18 |
| DOIs | |
| Publication status | Published - 5 May 2014 |
| Externally published | Yes |