{LnIII[μ5-κ2, κ1, κ1,κ1,κ1-1,2-(CO 2)2C6H4][isonicotine][H 2O]}2CuI·X (Ln = Eu, Sm, Nd; X = ClO4-, Cl-): A new pillared-layer approach to heterobimetallic 3d-4f 3D-network solids

Jian Wen Cheng; Shou Tian Zheng; En Ma; Guo Yu Yang

doi:10.1021/ic700893w

{Ln^III[μ₅-κ², κ¹, κ¹,κ¹,κ¹-1,2-(CO ₂)₂C₆H₄][isonicotine][H ₂O]}₂Cu^I·X (Ln = Eu, Sm, Nd; X = ClO₄^-, Cl-): A new pillared-layer approach to heterobimetallic 3d-4f 3D-network solids

Jian Wen Cheng
, Shou Tian Zheng
, En Ma
, Guo Yu Yang^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

113 Citations (Scopus)

Abstract

A new series of heterometallic lanthanide(III)-copper(I) coordination polymers Ln₂(bdc)₂(ina)₂(H₂O) ₂Cu·X (Hina = isonicotinic acid; H₂bdc = 1,2-benzenedicarboxylic acid; Ln = Eu (1), Sm (2), Nd (3), X = ClO ₄^-; Ln = Nd (4), X = Cl^-) have been hydrothermally synthesized in the presence/absence of HClO₄. Both compounds are isostructural and contained two distinct units of 2D Ln-bdc layers and linear [Cu(ina)₂]^-. The linear [Cu(ina) ₂]^- complexes act as pillars and further link the Ln-bdc layers resulting in four heterometallic metal-organic frameworks, which represent the first pillared-layer 3d-4f framework with two distinct types of channels along the b and c axes. The compounds can be specified by the Schläfli symbol (4⁷·6³)(4⁷· 6⁸) as a novel 3D (5,6)-connected net. Furthermore, the IR, TGA, PXRD, and UV-vis spectral and luminescent properties of 1-4 were also studied.

Original language	English
Pages (from-to)	10534-10538
Number of pages	5
Journal	Inorganic Chemistry
Volume	46
Issue number	25
DOIs	https://doi.org/10.1021/ic700893w
Publication status	Published - 10 Dec 2007
Externally published	Yes

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@article{9a911485085d4d0fba4da9f06e5d6ee6,

title = "\{LnIII[μ5-κ2, κ1, κ1,κ1,κ1-1,2-(CO 2)2C6H4][isonicotine][H 2O]\}2CuI·X (Ln = Eu, Sm, Nd; X = ClO4-, Cl-): A new pillared-layer approach to heterobimetallic 3d-4f 3D-network solids",

abstract = "A new series of heterometallic lanthanide(III)-copper(I) coordination polymers Ln2(bdc)2(ina)2(H2O) 2Cu·X (Hina = isonicotinic acid; H2bdc = 1,2-benzenedicarboxylic acid; Ln = Eu (1), Sm (2), Nd (3), X = ClO 4-; Ln = Nd (4), X = Cl-) have been hydrothermally synthesized in the presence/absence of HClO4. Both compounds are isostructural and contained two distinct units of 2D Ln-bdc layers and linear [Cu(ina)2]-. The linear [Cu(ina) 2]- complexes act as pillars and further link the Ln-bdc layers resulting in four heterometallic metal-organic frameworks, which represent the first pillared-layer 3d-4f framework with two distinct types of channels along the b and c axes. The compounds can be specified by the Schl{\"a}fli symbol (47·63)(47· 68) as a novel 3D (5,6)-connected net. Furthermore, the IR, TGA, PXRD, and UV-vis spectral and luminescent properties of 1-4 were also studied.",

author = "Cheng, \{Jian Wen\} and Zheng, \{Shou Tian\} and En Ma and Yang, \{Guo Yu\}",

year = "2007",

month = dec,

day = "10",

doi = "10.1021/ic700893w",

language = "English",

volume = "46",

pages = "10534--10538",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "25",

}

{Ln^III[μ₅-κ², κ¹, κ¹,κ¹,κ¹-1,2-(CO ₂)₂C₆H₄][isonicotine][H ₂O]}₂Cu^I·X (Ln = Eu, Sm, Nd; X = ClO₄^-, Cl-): A new pillared-layer approach to heterobimetallic 3d-4f 3D-network solids. / Cheng, Jian Wen; Zheng, Shou Tian; Ma, En et al.
In: Inorganic Chemistry, Vol. 46, No. 25, 10.12.2007, p. 10534-10538.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - {LnIII[μ5-κ2, κ1, κ1,κ1,κ1-1,2-(CO 2)2C6H4][isonicotine][H 2O]}2CuI·X (Ln = Eu, Sm, Nd; X = ClO4-, Cl-)

T2 - A new pillared-layer approach to heterobimetallic 3d-4f 3D-network solids

AU - Cheng, Jian Wen

AU - Zheng, Shou Tian

AU - Ma, En

AU - Yang, Guo Yu

PY - 2007/12/10

Y1 - 2007/12/10

N2 - A new series of heterometallic lanthanide(III)-copper(I) coordination polymers Ln2(bdc)2(ina)2(H2O) 2Cu·X (Hina = isonicotinic acid; H2bdc = 1,2-benzenedicarboxylic acid; Ln = Eu (1), Sm (2), Nd (3), X = ClO 4-; Ln = Nd (4), X = Cl-) have been hydrothermally synthesized in the presence/absence of HClO4. Both compounds are isostructural and contained two distinct units of 2D Ln-bdc layers and linear [Cu(ina)2]-. The linear [Cu(ina) 2]- complexes act as pillars and further link the Ln-bdc layers resulting in four heterometallic metal-organic frameworks, which represent the first pillared-layer 3d-4f framework with two distinct types of channels along the b and c axes. The compounds can be specified by the Schläfli symbol (47·63)(47· 68) as a novel 3D (5,6)-connected net. Furthermore, the IR, TGA, PXRD, and UV-vis spectral and luminescent properties of 1-4 were also studied.

AB - A new series of heterometallic lanthanide(III)-copper(I) coordination polymers Ln2(bdc)2(ina)2(H2O) 2Cu·X (Hina = isonicotinic acid; H2bdc = 1,2-benzenedicarboxylic acid; Ln = Eu (1), Sm (2), Nd (3), X = ClO 4-; Ln = Nd (4), X = Cl-) have been hydrothermally synthesized in the presence/absence of HClO4. Both compounds are isostructural and contained two distinct units of 2D Ln-bdc layers and linear [Cu(ina)2]-. The linear [Cu(ina) 2]- complexes act as pillars and further link the Ln-bdc layers resulting in four heterometallic metal-organic frameworks, which represent the first pillared-layer 3d-4f framework with two distinct types of channels along the b and c axes. The compounds can be specified by the Schläfli symbol (47·63)(47· 68) as a novel 3D (5,6)-connected net. Furthermore, the IR, TGA, PXRD, and UV-vis spectral and luminescent properties of 1-4 were also studied.

UR - https://www.scopus.com/pages/publications/37549004418

U2 - 10.1021/ic700893w

DO - 10.1021/ic700893w

M3 - Article

AN - SCOPUS:37549004418

SN - 0020-1669

VL - 46

SP - 10534

EP - 10538

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 25

ER -

{Ln^III[μ₅-κ², κ¹, κ¹,κ¹,κ¹-1,2-(CO ₂)₂C₆H₄][isonicotine][H ₂O]}₂Cu^I·X (Ln = Eu, Sm, Nd; X = ClO₄^-, Cl-): A new pillared-layer approach to heterobimetallic 3d-4f 3D-network solids

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