Li2CsB7O10(OH)4: A Deep-Ultraviolet Nonlinear-Optical Mixed-Alkaline Borate Constructed by Unusual Heptaborate Anions

Jian Hao Huang; Cong Cong Jin; Pei Li Xu; Pifu Gong; Zheshuai Lin; Jian Wen Cheng; Guo Yu Yang

doi:10.1021/acs.inorgchem.8b03495

Li₂CsB₇O₁₀(OH)₄: A Deep-Ultraviolet Nonlinear-Optical Mixed-Alkaline Borate Constructed by Unusual Heptaborate Anions

Jian Hao Huang
, Cong Cong Jin
, Pei Li Xu
, Pifu Gong
, Zheshuai Lin
, Jian Wen Cheng^*
, Guo Yu Yang

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

83 Citations (Scopus)

Abstract

A new noncentrosymmetric mixed-alkaline borate, Li₂CsB₇O₁₀(OH)₄ (1), was made under solvothermal conditions. This layered boron oxide framework consists of unique bird-shaped [B₇O₁₂(OH)₄]^7- clusters with large 14-ring pores. Its second-harmonic-generation (SHG) signal is 2.5KDP (KH₂PO₄), with its short ultraviolet (UV) cutoff edge indicating that this crystal is a potential deep-UV transparent nonlinear-optical material.

Original language	English
Pages (from-to)	1755-1758
Number of pages	4
Journal	Inorganic Chemistry
Volume	58
Issue number	3
DOIs	https://doi.org/10.1021/acs.inorgchem.8b03495
Publication status	Published - 4 Feb 2019

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title = "Li2CsB7O10(OH)4: A Deep-Ultraviolet Nonlinear-Optical Mixed-Alkaline Borate Constructed by Unusual Heptaborate Anions",

abstract = "A new noncentrosymmetric mixed-alkaline borate, Li2CsB7O10(OH)4 (1), was made under solvothermal conditions. This layered boron oxide framework consists of unique bird-shaped [B7O12(OH)4]7- clusters with large 14-ring pores. Its second-harmonic-generation (SHG) signal is 2.5KDP (KH2PO4), with its short ultraviolet (UV) cutoff edge indicating that this crystal is a potential deep-UV transparent nonlinear-optical material.",

author = "Huang, \{Jian Hao\} and Jin, \{Cong Cong\} and Xu, \{Pei Li\} and Pifu Gong and Zheshuai Lin and Cheng, \{Jian Wen\} and Yang, \{Guo Yu\}",

note = "Publisher Copyright: {\textcopyright} 2019 American Chemical Society.",

year = "2019",

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doi = "10.1021/acs.inorgchem.8b03495",

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T1 - Li2CsB7O10(OH)4

T2 - A Deep-Ultraviolet Nonlinear-Optical Mixed-Alkaline Borate Constructed by Unusual Heptaborate Anions

AU - Huang, Jian Hao

AU - Jin, Cong Cong

AU - Xu, Pei Li

AU - Gong, Pifu

AU - Lin, Zheshuai

AU - Cheng, Jian Wen

AU - Yang, Guo Yu

PY - 2019/2/4

Y1 - 2019/2/4

N2 - A new noncentrosymmetric mixed-alkaline borate, Li2CsB7O10(OH)4 (1), was made under solvothermal conditions. This layered boron oxide framework consists of unique bird-shaped [B7O12(OH)4]7- clusters with large 14-ring pores. Its second-harmonic-generation (SHG) signal is 2.5KDP (KH2PO4), with its short ultraviolet (UV) cutoff edge indicating that this crystal is a potential deep-UV transparent nonlinear-optical material.

AB - A new noncentrosymmetric mixed-alkaline borate, Li2CsB7O10(OH)4 (1), was made under solvothermal conditions. This layered boron oxide framework consists of unique bird-shaped [B7O12(OH)4]7- clusters with large 14-ring pores. Its second-harmonic-generation (SHG) signal is 2.5KDP (KH2PO4), with its short ultraviolet (UV) cutoff edge indicating that this crystal is a potential deep-UV transparent nonlinear-optical material.

UR - https://www.scopus.com/pages/publications/85061042617

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DO - 10.1021/acs.inorgchem.8b03495

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JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 3

ER -

Li₂CsB₇O₁₀(OH)₄: A Deep-Ultraviolet Nonlinear-Optical Mixed-Alkaline Borate Constructed by Unusual Heptaborate Anions

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