Linear Main-Chain 1,2,4-Triazolium Poly(ionic liquid)s: Single-Step Synthesis and Stabilization of Cellulose Nanocrystals

Mohamed Yahia; Shilin Mei; Aji P. Mathew; Jiayin Yuan

doi:10.1021/acsmacrolett.9b00542

Linear Main-Chain 1,2,4-Triazolium Poly(ionic liquid)s: Single-Step Synthesis and Stabilization of Cellulose Nanocrystals

Mohamed Yahia
, Shilin Mei
, Aji P. Mathew
, Jiayin Yuan^*

^*Corresponding author for this work

Stockholm University
Capital University - Egypt
Helmholtz Centre Berlin for Materials and Energy

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

Linear main-chain 1,2,4-triazolium-based poly(ionic liquid)s (PILs) were synthesized in this contribution. The polymerization process is experimentally very simple and involves only a single-step polycondensation of a commercially available monomer in DMSO as solvent at 120 °C. Their thermal stability and solubility were analyzed in terms of different counteranions. Due to the ease of this synthetic route, it was readily applied to graft onto sulfonated cellulose nanocrystals (CNCs) via a one-step in situ polymerization. The as-synthesized PIL@CNC hybrid colloids exhibit adaptive dispensability in water and organic solvents.

Original language	English
Pages (from-to)	1372-1377
Number of pages	6
Journal	ACS Macro Letters
Volume	8
Issue number	10
DOIs	https://doi.org/10.1021/acsmacrolett.9b00542
Publication status	Published - 15 Oct 2019
Externally published	Yes

Access to Document

10.1021/acsmacrolett.9b00542

Cite this

@article{5a58f87424df4a668025443c3c8d2b6c,

title = "Linear Main-Chain 1,2,4-Triazolium Poly(ionic liquid)s: Single-Step Synthesis and Stabilization of Cellulose Nanocrystals",

abstract = "Linear main-chain 1,2,4-triazolium-based poly(ionic liquid)s (PILs) were synthesized in this contribution. The polymerization process is experimentally very simple and involves only a single-step polycondensation of a commercially available monomer in DMSO as solvent at 120 °C. Their thermal stability and solubility were analyzed in terms of different counteranions. Due to the ease of this synthetic route, it was readily applied to graft onto sulfonated cellulose nanocrystals (CNCs) via a one-step in situ polymerization. The as-synthesized PIL@CNC hybrid colloids exhibit adaptive dispensability in water and organic solvents.",

author = "Mohamed Yahia and Shilin Mei and Mathew, \{Aji P.\} and Jiayin Yuan",

note = "Publisher Copyright: Copyright {\textcopyright} 2019 American Chemical Society.",

year = "2019",

month = oct,

day = "15",

doi = "10.1021/acsmacrolett.9b00542",

language = "English",

volume = "8",

pages = "1372--1377",

journal = "ACS Macro Letters",

issn = "2161-1653",

publisher = "American Chemical Society",

number = "10",

}

TY - JOUR

T1 - Linear Main-Chain 1,2,4-Triazolium Poly(ionic liquid)s

T2 - Single-Step Synthesis and Stabilization of Cellulose Nanocrystals

AU - Yahia, Mohamed

AU - Mei, Shilin

AU - Mathew, Aji P.

AU - Yuan, Jiayin

PY - 2019/10/15

Y1 - 2019/10/15

N2 - Linear main-chain 1,2,4-triazolium-based poly(ionic liquid)s (PILs) were synthesized in this contribution. The polymerization process is experimentally very simple and involves only a single-step polycondensation of a commercially available monomer in DMSO as solvent at 120 °C. Their thermal stability and solubility were analyzed in terms of different counteranions. Due to the ease of this synthetic route, it was readily applied to graft onto sulfonated cellulose nanocrystals (CNCs) via a one-step in situ polymerization. The as-synthesized PIL@CNC hybrid colloids exhibit adaptive dispensability in water and organic solvents.

AB - Linear main-chain 1,2,4-triazolium-based poly(ionic liquid)s (PILs) were synthesized in this contribution. The polymerization process is experimentally very simple and involves only a single-step polycondensation of a commercially available monomer in DMSO as solvent at 120 °C. Their thermal stability and solubility were analyzed in terms of different counteranions. Due to the ease of this synthetic route, it was readily applied to graft onto sulfonated cellulose nanocrystals (CNCs) via a one-step in situ polymerization. The as-synthesized PIL@CNC hybrid colloids exhibit adaptive dispensability in water and organic solvents.

UR - https://www.scopus.com/pages/publications/85073103610

U2 - 10.1021/acsmacrolett.9b00542

DO - 10.1021/acsmacrolett.9b00542

M3 - Article

C2 - 35651167

AN - SCOPUS:85073103610

SN - 2161-1653

VL - 8

SP - 1372

EP - 1377

JO - ACS Macro Letters

JF - ACS Macro Letters

IS - 10

ER -

Linear Main-Chain 1,2,4-Triazolium Poly(ionic liquid)s: Single-Step Synthesis and Stabilization of Cellulose Nanocrystals

Abstract

Access to Document

Other files and links

Fingerprint

Cite this