LiBa1.5[B5O8(OH)3]: A new 1-D metal borate chain constructed from B5O9(OH) 36 - Cluster units

Han Qing Wu; Bai Fei Yang; Huan He; Guo Yu Yang

doi:10.1016/j.inoche.2013.10.043

LiBa_1.5[B₅O₈(OH)₃]: A new 1-D metal borate chain constructed from B₅O₉(OH) ₃^{6 -} Cluster units

Han Qing Wu
, Bai Fei Yang
, Huan He
, Guo Yu Yang^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology
CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

A new mixed metal borate LiBa_1.5[B₅O ₈(OH)₃] (1) has been hydrothermally synthesized and structurally characterized by FT-IR spectroscopy, powder X-ray diffraction, single crystal X-ray diffraction, and thermogravimetric analysis, respectively. 1 crystallizes in the monoclinic system, space group C2/c, a = 11.2839(7) Å, b = 7.3974(4) Å, c = 20.7151(13) Å, β = 103.392(6), V = 1682.10(17) Å³ and Z = 8. The structure consists of infinite one-dimensional (1-D) borate chains constructed from B₅O ₉(OH)₃^{6 -} cluster units. These BO chains are further linked by the Ba^{2 +} and Li⁺ cations to form a 3-D framework.

Original language	English
Pages (from-to)	10-13
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	39
DOIs	https://doi.org/10.1016/j.inoche.2013.10.043
Publication status	Published - 2014

Keywords

Cluster
Crystal structure
Hydrothermal synthesis
Metal borate

Access to Document

10.1016/j.inoche.2013.10.043

Cite this

@article{8d6d1b00ab394529890f35541ebccbb7,

title = "LiBa1.5[B5O8(OH)3]: A new 1-D metal borate chain constructed from B5O9(OH) 36 - Cluster units",

abstract = "A new mixed metal borate LiBa1.5[B5O 8(OH)3] (1) has been hydrothermally synthesized and structurally characterized by FT-IR spectroscopy, powder X-ray diffraction, single crystal X-ray diffraction, and thermogravimetric analysis, respectively. 1 crystallizes in the monoclinic system, space group C2/c, a = 11.2839(7) {\AA}, b = 7.3974(4) {\AA}, c = 20.7151(13) {\AA}, β = 103.392(6), V = 1682.10(17) {\AA}3 and Z = 8. The structure consists of infinite one-dimensional (1-D) borate chains constructed from B5O 9(OH)36 - cluster units. These BO chains are further linked by the Ba2 + and Li+ cations to form a 3-D framework.",

keywords = "Cluster, Crystal structure, Hydrothermal synthesis, Metal borate",

author = "Wu, \{Han Qing\} and Yang, \{Bai Fei\} and Huan He and Yang, \{Guo Yu\}",

year = "2014",

doi = "10.1016/j.inoche.2013.10.043",

language = "English",

volume = "39",

pages = "10--13",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - LiBa1.5[B5O8(OH)3]

T2 - A new 1-D metal borate chain constructed from B5O9(OH) 36 - Cluster units

AU - Wu, Han Qing

AU - Yang, Bai Fei

AU - He, Huan

AU - Yang, Guo Yu

PY - 2014

Y1 - 2014

N2 - A new mixed metal borate LiBa1.5[B5O 8(OH)3] (1) has been hydrothermally synthesized and structurally characterized by FT-IR spectroscopy, powder X-ray diffraction, single crystal X-ray diffraction, and thermogravimetric analysis, respectively. 1 crystallizes in the monoclinic system, space group C2/c, a = 11.2839(7) Å, b = 7.3974(4) Å, c = 20.7151(13) Å, β = 103.392(6), V = 1682.10(17) Å3 and Z = 8. The structure consists of infinite one-dimensional (1-D) borate chains constructed from B5O 9(OH)36 - cluster units. These BO chains are further linked by the Ba2 + and Li+ cations to form a 3-D framework.

AB - A new mixed metal borate LiBa1.5[B5O 8(OH)3] (1) has been hydrothermally synthesized and structurally characterized by FT-IR spectroscopy, powder X-ray diffraction, single crystal X-ray diffraction, and thermogravimetric analysis, respectively. 1 crystallizes in the monoclinic system, space group C2/c, a = 11.2839(7) Å, b = 7.3974(4) Å, c = 20.7151(13) Å, β = 103.392(6), V = 1682.10(17) Å3 and Z = 8. The structure consists of infinite one-dimensional (1-D) borate chains constructed from B5O 9(OH)36 - cluster units. These BO chains are further linked by the Ba2 + and Li+ cations to form a 3-D framework.

KW - Cluster

KW - Crystal structure

KW - Hydrothermal synthesis

KW - Metal borate

UR - https://www.scopus.com/pages/publications/84887597243

U2 - 10.1016/j.inoche.2013.10.043

DO - 10.1016/j.inoche.2013.10.043

M3 - Article

AN - SCOPUS:84887597243

SN - 1387-7003

VL - 39

SP - 10

EP - 13

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -

LiBa_1.5[B₅O₈(OH)₃]: A new 1-D metal borate chain constructed from B₅O₉(OH) ₃^{6 -} Cluster units

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this