Lanthanide-transition-metal sandwich framework comprising {Cu3} cluster pillars and layered networks of {Er36} wheels

Jian Wen Cheng; Jie Zhang; Shou Tian Zheng; Man Bo Zhang; Guo Yu Yang

doi:10.1002/anie.200502917

Lanthanide-transition-metal sandwich framework comprising {Cu₃} cluster pillars and layered networks of {Er₃₆} wheels

Jian Wen Cheng^*
, Jie Zhang
, Shou Tian Zheng
, Man Bo Zhang
, Guo Yu Yang

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

329 Citations (Scopus)

Abstract

Synergistic coordination between isonicotinate (ina) and 1,2-benzenedicarboxylate (bdc) ligands under hydrothermal conditions results in the formation of two new coordination polymers, [Er₇(μ ₃-O)(μ₃-OH)₆(bdc)₃](ina) ₉[Cu₃X₄] (X = Cl, Br). Wheel-shaped [Er ₃₆(μ₃-OH)₃₀(μ₃-O) ₆-(bdc)₆]⁵⁴⁺ ions form a 2D network (see picture), which is further pillared by [Cu₃X₄(ina) ₆]^4- to give a 3D framework. (Figure Presented)

Original language	English
Pages (from-to)	73-77
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	45
Issue number	1
DOIs	https://doi.org/10.1002/anie.200502917
Publication status	Published - 16 Dec 2005
Externally published	Yes

Keywords

Bridging ligands
Cluster compounds
Copper
Hydrothermal synthesis
Lanthanides

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10.1002/anie.200502917

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title = "Lanthanide-transition-metal sandwich framework comprising \{Cu3\} cluster pillars and layered networks of \{Er36\} wheels",

abstract = "Synergistic coordination between isonicotinate (ina) and 1,2-benzenedicarboxylate (bdc) ligands under hydrothermal conditions results in the formation of two new coordination polymers, [Er7(μ 3-O)(μ3-OH)6(bdc)3](ina) 9[Cu3X4] (X = Cl, Br). Wheel-shaped [Er 36(μ3-OH)30(μ3-O) 6-(bdc)6]54+ ions form a 2D network (see picture), which is further pillared by [Cu3X4(ina) 6]4- to give a 3D framework. (Figure Presented)",

keywords = "Bridging ligands, Cluster compounds, Copper, Hydrothermal synthesis, Lanthanides",

author = "Cheng, \{Jian Wen\} and Jie Zhang and Zheng, \{Shou Tian\} and Zhang, \{Man Bo\} and Yang, \{Guo Yu\}",

year = "2005",

month = dec,

day = "16",

doi = "10.1002/anie.200502917",

language = "English",

volume = "45",

pages = "73--77",

journal = "Angewandte Chemie - International Edition",

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publisher = "John Wiley and Sons Ltd",

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T1 - Lanthanide-transition-metal sandwich framework comprising {Cu3} cluster pillars and layered networks of {Er36} wheels

AU - Cheng, Jian Wen

AU - Zhang, Jie

AU - Zheng, Shou Tian

AU - Zhang, Man Bo

AU - Yang, Guo Yu

PY - 2005/12/16

Y1 - 2005/12/16

N2 - Synergistic coordination between isonicotinate (ina) and 1,2-benzenedicarboxylate (bdc) ligands under hydrothermal conditions results in the formation of two new coordination polymers, [Er7(μ 3-O)(μ3-OH)6(bdc)3](ina) 9[Cu3X4] (X = Cl, Br). Wheel-shaped [Er 36(μ3-OH)30(μ3-O) 6-(bdc)6]54+ ions form a 2D network (see picture), which is further pillared by [Cu3X4(ina) 6]4- to give a 3D framework. (Figure Presented)

AB - Synergistic coordination between isonicotinate (ina) and 1,2-benzenedicarboxylate (bdc) ligands under hydrothermal conditions results in the formation of two new coordination polymers, [Er7(μ 3-O)(μ3-OH)6(bdc)3](ina) 9[Cu3X4] (X = Cl, Br). Wheel-shaped [Er 36(μ3-OH)30(μ3-O) 6-(bdc)6]54+ ions form a 2D network (see picture), which is further pillared by [Cu3X4(ina) 6]4- to give a 3D framework. (Figure Presented)

KW - Bridging ligands

KW - Cluster compounds

KW - Copper

KW - Hydrothermal synthesis

KW - Lanthanides

UR - https://www.scopus.com/pages/publications/29344475921

U2 - 10.1002/anie.200502917

DO - 10.1002/anie.200502917

M3 - Article

AN - SCOPUS:29344475921

SN - 1433-7851

VL - 45

SP - 73

EP - 77

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 1

ER -

Lanthanide-transition-metal sandwich framework comprising {Cu₃} cluster pillars and layered networks of {Er₃₆} wheels

Abstract

Keywords

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