Lanthanide-organic frameworks based on {Ln4(μ3-OH)4(μ2-OH)2} Cluster units

Wei Hui Fang; Zhi Long Wang; Guo Yu Yang

doi:10.1007/s10876-010-0327-5

Lanthanide-organic frameworks based on {Ln₄(μ₃-OH)₄(μ₂-OH)₂} Cluster units

Wei Hui Fang
, Zhi Long Wang
, Guo Yu Yang^*

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

Three novel lanthanide-organic frameworks: [Ln₂(pyba)₃(μ₃-OH)₂(μ₂-OH)(H₂O)]_n (Ln = Er (1), Y (2), Dy (3) Hpyba = 4-pyridin-4-yl-benzoic acid) have been hydrothermally synthesized and structurally characterized by single crystal X-ray diffraction. Structure analysis shows that each {Ln₄(μ₃-OH)₄(μ₂-OH)₂} cluster units interconnect to form 1-D chains, which are further linked by π-π interactions to make a 3-D supramolecular network structure. Furthermore, the IR, PXRD and TGA of compounds 1-3 were also studied. Graphical Abstract: Three novel lanthanide-organic frameworks: [Ln₂(pyba)₃(μ₃-OH)₂(μ₂-OH)(H₂O)]_n (Ln = Er (1), Y (2), Dy (3), Hpyba = 4-pyridin-4-yl-benzoic acid) have been hydrothermally synthesized and structurally characterized. Single-crystal X-ray structure analysis shows that each {Ln₄(μ₃-OH)₄(μ₂-OH)₂} cluster units interconnect to form 1-D chains, which are further linked by π-π interactions to make a 3-D supramolecular network.[Figure not available: see fulltext.]

Original language	English
Pages (from-to)	187-195
Number of pages	9
Journal	Journal of Cluster Science
Volume	21
Issue number	2
DOIs	https://doi.org/10.1007/s10876-010-0327-5
Publication status	Published - 2010
Externally published	Yes

Keywords

1-D chain
Hydrothermal synthesis
Lanthanide-organic frameworks

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10.1007/s10876-010-0327-5

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@article{4d4a4b1256f649ae99a94ddf5403c69f,

title = "Lanthanide-organic frameworks based on \{Ln4(μ3-OH)4(μ2-OH)2\} Cluster units",

abstract = "Three novel lanthanide-organic frameworks: [Ln2(pyba)3(μ3-OH)2(μ2-OH)(H2O)]n (Ln = Er (1), Y (2), Dy (3) Hpyba = 4-pyridin-4-yl-benzoic acid) have been hydrothermally synthesized and structurally characterized by single crystal X-ray diffraction. Structure analysis shows that each \{Ln4(μ3-OH)4(μ2-OH)2\} cluster units interconnect to form 1-D chains, which are further linked by π-π interactions to make a 3-D supramolecular network structure. Furthermore, the IR, PXRD and TGA of compounds 1-3 were also studied. Graphical Abstract: Three novel lanthanide-organic frameworks: [Ln2(pyba)3(μ3-OH)2(μ2-OH)(H2O)]n (Ln = Er (1), Y (2), Dy (3), Hpyba = 4-pyridin-4-yl-benzoic acid) have been hydrothermally synthesized and structurally characterized. Single-crystal X-ray structure analysis shows that each \{Ln4(μ3-OH)4(μ2-OH)2\} cluster units interconnect to form 1-D chains, which are further linked by π-π interactions to make a 3-D supramolecular network.[Figure not available: see fulltext.]",

keywords = "1-D chain, Hydrothermal synthesis, Lanthanide-organic frameworks",

author = "Fang, \{Wei Hui\} and Wang, \{Zhi Long\} and Yang, \{Guo Yu\}",

year = "2010",

doi = "10.1007/s10876-010-0327-5",

language = "English",

volume = "21",

pages = "187--195",

journal = "Journal of Cluster Science",

issn = "1040-7278",

publisher = "Springer New York",

number = "2",

}

TY - JOUR

T1 - Lanthanide-organic frameworks based on {Ln4(μ3-OH)4(μ2-OH)2} Cluster units

AU - Fang, Wei Hui

AU - Wang, Zhi Long

AU - Yang, Guo Yu

PY - 2010

Y1 - 2010

N2 - Three novel lanthanide-organic frameworks: [Ln2(pyba)3(μ3-OH)2(μ2-OH)(H2O)]n (Ln = Er (1), Y (2), Dy (3) Hpyba = 4-pyridin-4-yl-benzoic acid) have been hydrothermally synthesized and structurally characterized by single crystal X-ray diffraction. Structure analysis shows that each {Ln4(μ3-OH)4(μ2-OH)2} cluster units interconnect to form 1-D chains, which are further linked by π-π interactions to make a 3-D supramolecular network structure. Furthermore, the IR, PXRD and TGA of compounds 1-3 were also studied. Graphical Abstract: Three novel lanthanide-organic frameworks: [Ln2(pyba)3(μ3-OH)2(μ2-OH)(H2O)]n (Ln = Er (1), Y (2), Dy (3), Hpyba = 4-pyridin-4-yl-benzoic acid) have been hydrothermally synthesized and structurally characterized. Single-crystal X-ray structure analysis shows that each {Ln4(μ3-OH)4(μ2-OH)2} cluster units interconnect to form 1-D chains, which are further linked by π-π interactions to make a 3-D supramolecular network.[Figure not available: see fulltext.]

AB - Three novel lanthanide-organic frameworks: [Ln2(pyba)3(μ3-OH)2(μ2-OH)(H2O)]n (Ln = Er (1), Y (2), Dy (3) Hpyba = 4-pyridin-4-yl-benzoic acid) have been hydrothermally synthesized and structurally characterized by single crystal X-ray diffraction. Structure analysis shows that each {Ln4(μ3-OH)4(μ2-OH)2} cluster units interconnect to form 1-D chains, which are further linked by π-π interactions to make a 3-D supramolecular network structure. Furthermore, the IR, PXRD and TGA of compounds 1-3 were also studied. Graphical Abstract: Three novel lanthanide-organic frameworks: [Ln2(pyba)3(μ3-OH)2(μ2-OH)(H2O)]n (Ln = Er (1), Y (2), Dy (3), Hpyba = 4-pyridin-4-yl-benzoic acid) have been hydrothermally synthesized and structurally characterized. Single-crystal X-ray structure analysis shows that each {Ln4(μ3-OH)4(μ2-OH)2} cluster units interconnect to form 1-D chains, which are further linked by π-π interactions to make a 3-D supramolecular network.[Figure not available: see fulltext.]

KW - 1-D chain

KW - Hydrothermal synthesis

KW - Lanthanide-organic frameworks

UR - https://www.scopus.com/pages/publications/77953534679

U2 - 10.1007/s10876-010-0327-5

DO - 10.1007/s10876-010-0327-5

M3 - Article

AN - SCOPUS:77953534679

SN - 1040-7278

VL - 21

SP - 187

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JO - Journal of Cluster Science

JF - Journal of Cluster Science

IS - 2

ER -

Lanthanide-organic frameworks based on {Ln₄(μ₃-OH)₄(μ₂-OH)₂} Cluster units

Abstract

Keywords

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