K7{(BO3)Mn[B12O18(OH) 6]}·H2O: First manganese borate based on covalently linked B12O18(OH)6 clusters and BO3 units via Mn2+ cations

Hong Xia Zhang; Jie Zhang; Shou Tian Zheng; Guo Yu Yang

doi:10.1016/j.inoche.2004.04.015

K₇{(BO₃)Mn[B₁₂O₁₈(OH) ₆]}·H₂O: First manganese borate based on covalently linked B₁₂O₁₈(OH)₆ clusters and BO₃ units via Mn²⁺ cations

Hong Xia Zhang
, Jie Zhang
, Shou Tian Zheng
, Guo Yu Yang^*

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter
Nanjing University

Research output: Contribution to journal › Article › peer-review

32 Citations (Scopus)

Abstract

A novel manganese oxyborate, K₇{(BO₃)[B ₁₂O₁₈(OH)₆]}·H₂O (1), which is the first example showing the edge-sharing between boron and transition metal, has been solvothermally synthesized. The structure consists of [B ₁₂O₂₀(OH)₄] and [BO₃] which are linked through unusual MnO₅ polyhedron via vertexes and edges. This compound exhibits NLO properties and the intensity of the green light (frequency-doubled output: λ=532 nm) produced by 1 is as large as that of KDP.

Original language	English
Pages (from-to)	781-783
Number of pages	3
Journal	Inorganic Chemistry Communications
Volume	7
Issue number	6
DOIs	https://doi.org/10.1016/j.inoche.2004.04.015
Publication status	Published - Jun 2004
Externally published	Yes

Keywords

Borate
Manganese
NLO properties

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10.1016/j.inoche.2004.04.015

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@article{6feddd82da1242929a084e50aaa8ef6e,

title = "K7\{(BO3)Mn[B12O18(OH) 6]\}·H2O: First manganese borate based on covalently linked B12O18(OH)6 clusters and BO3 units via Mn2+ cations",

abstract = "A novel manganese oxyborate, K7\{(BO3)[B 12O18(OH)6]\}·H2O (1), which is the first example showing the edge-sharing between boron and transition metal, has been solvothermally synthesized. The structure consists of [B 12O20(OH)4] and [BO3] which are linked through unusual MnO5 polyhedron via vertexes and edges. This compound exhibits NLO properties and the intensity of the green light (frequency-doubled output: λ=532 nm) produced by 1 is as large as that of KDP.",

keywords = "Borate, Manganese, NLO properties",

author = "Zhang, \{Hong Xia\} and Jie Zhang and Zheng, \{Shou Tian\} and Yang, \{Guo Yu\}",

year = "2004",

month = jun,

doi = "10.1016/j.inoche.2004.04.015",

language = "English",

volume = "7",

pages = "781--783",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

number = "6",

}

TY - JOUR

T1 - K7{(BO3)Mn[B12O18(OH) 6]}·H2O

T2 - First manganese borate based on covalently linked B12O18(OH)6 clusters and BO3 units via Mn2+ cations

AU - Zhang, Hong Xia

AU - Zhang, Jie

AU - Zheng, Shou Tian

AU - Yang, Guo Yu

PY - 2004/6

Y1 - 2004/6

N2 - A novel manganese oxyborate, K7{(BO3)[B 12O18(OH)6]}·H2O (1), which is the first example showing the edge-sharing between boron and transition metal, has been solvothermally synthesized. The structure consists of [B 12O20(OH)4] and [BO3] which are linked through unusual MnO5 polyhedron via vertexes and edges. This compound exhibits NLO properties and the intensity of the green light (frequency-doubled output: λ=532 nm) produced by 1 is as large as that of KDP.

AB - A novel manganese oxyborate, K7{(BO3)[B 12O18(OH)6]}·H2O (1), which is the first example showing the edge-sharing between boron and transition metal, has been solvothermally synthesized. The structure consists of [B 12O20(OH)4] and [BO3] which are linked through unusual MnO5 polyhedron via vertexes and edges. This compound exhibits NLO properties and the intensity of the green light (frequency-doubled output: λ=532 nm) produced by 1 is as large as that of KDP.

KW - Borate

KW - Manganese

KW - NLO properties

UR - https://www.scopus.com/pages/publications/2542491155

U2 - 10.1016/j.inoche.2004.04.015

DO - 10.1016/j.inoche.2004.04.015

M3 - Article

AN - SCOPUS:2542491155

SN - 1387-7003

VL - 7

SP - 781

EP - 783

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 6

ER -

K₇{(BO₃)Mn[B₁₂O₁₈(OH) ₆]}·H₂O: First manganese borate based on covalently linked B₁₂O₁₈(OH)₆ clusters and BO₃ units via Mn²⁺ cations

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Keywords

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