K2Na3[{B6O10(OH)}{B3O4(OH)3}] ⋅ H2O: A Layered Borate Built by Mixed Oxoboron Clusters with Nonlinear-Optical Property

Chong An Chen; Qi Ming Qiu; Guo Yu Yang

doi:10.1002/asia.202100869

K₂Na₃[{B₆O₁₀(OH)}{B₃O₄(OH)₃}] ⋅ H₂O: A Layered Borate Built by Mixed Oxoboron Clusters with Nonlinear-Optical Property

Chong An Chen
, Qi Ming Qiu
, Guo Yu Yang^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

A new acentric borate, K₂Na₃[{B₆O₁₀(OH)}-{B₃O₄(OH)₃}] ⋅ H₂O (1) has been made under solvothermal condition. 1 has layered structure made by B₆O₁₃(OH)-based chains and B₃O₅(OH)₃-bridging clusters. Second-harmonic generation (SHG) measurements reveal that 1 is a phase-matchable nonlinear optical (NLO) material, showing the SHG signal intensity of 1.8 times that of KDP (KH₂PO₄). Besides, UV-Vis diffuse reflectance spectrum shows that 1 has the short deep UV (DUV) absorption cutoff edge of 198 nm. Thermogravimetric analysis reveals it has good thermal stability. Also 1 represents firstly mixed oxoboron clusters-made 2D layered borate with NLO property.

Original language	English
Pages (from-to)	3244-3248
Number of pages	5
Journal	Chemistry - An Asian Journal
Volume	16
Issue number	20
DOIs	https://doi.org/10.1002/asia.202100869
Publication status	Published - 18 Oct 2021

Keywords

Borate
Layered structure
Mixed-oxoboron cluster
Nonlinear optics
Solvothermal syntheses

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@article{3452270813064c44a522f88d12b48671,

title = "K2Na3[\{B6O10(OH)\}\{B3O4(OH)3\}] ⋅ H2O: A Layered Borate Built by Mixed Oxoboron Clusters with Nonlinear-Optical Property",

abstract = "A new acentric borate, K2Na3[\{B6O10(OH)\}-\{B3O4(OH)3\}] ⋅ H2O (1) has been made under solvothermal condition. 1 has layered structure made by B6O13(OH)-based chains and B3O5(OH)3-bridging clusters. Second-harmonic generation (SHG) measurements reveal that 1 is a phase-matchable nonlinear optical (NLO) material, showing the SHG signal intensity of 1.8 times that of KDP (KH2PO4). Besides, UV-Vis diffuse reflectance spectrum shows that 1 has the short deep UV (DUV) absorption cutoff edge of 198 nm. Thermogravimetric analysis reveals it has good thermal stability. Also 1 represents firstly mixed oxoboron clusters-made 2D layered borate with NLO property.",

keywords = "Borate, Layered structure, Mixed-oxoboron cluster, Nonlinear optics, Solvothermal syntheses",

author = "Chen, \{Chong An\} and Qiu, \{Qi Ming\} and Yang, \{Guo Yu\}",

note = "Publisher Copyright: {\textcopyright} 2021 Wiley-VCH GmbH",

year = "2021",

month = oct,

day = "18",

doi = "10.1002/asia.202100869",

language = "English",

volume = "16",

pages = "3244--3248",

journal = "Chemistry - An Asian Journal",

issn = "1861-4728",

publisher = "John Wiley and Sons Ltd",

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TY - JOUR

T1 - K2Na3[{B6O10(OH)}{B3O4(OH)3}] ⋅ H2O

T2 - A Layered Borate Built by Mixed Oxoboron Clusters with Nonlinear-Optical Property

AU - Chen, Chong An

AU - Qiu, Qi Ming

AU - Yang, Guo Yu

PY - 2021/10/18

Y1 - 2021/10/18

N2 - A new acentric borate, K2Na3[{B6O10(OH)}-{B3O4(OH)3}] ⋅ H2O (1) has been made under solvothermal condition. 1 has layered structure made by B6O13(OH)-based chains and B3O5(OH)3-bridging clusters. Second-harmonic generation (SHG) measurements reveal that 1 is a phase-matchable nonlinear optical (NLO) material, showing the SHG signal intensity of 1.8 times that of KDP (KH2PO4). Besides, UV-Vis diffuse reflectance spectrum shows that 1 has the short deep UV (DUV) absorption cutoff edge of 198 nm. Thermogravimetric analysis reveals it has good thermal stability. Also 1 represents firstly mixed oxoboron clusters-made 2D layered borate with NLO property.

AB - A new acentric borate, K2Na3[{B6O10(OH)}-{B3O4(OH)3}] ⋅ H2O (1) has been made under solvothermal condition. 1 has layered structure made by B6O13(OH)-based chains and B3O5(OH)3-bridging clusters. Second-harmonic generation (SHG) measurements reveal that 1 is a phase-matchable nonlinear optical (NLO) material, showing the SHG signal intensity of 1.8 times that of KDP (KH2PO4). Besides, UV-Vis diffuse reflectance spectrum shows that 1 has the short deep UV (DUV) absorption cutoff edge of 198 nm. Thermogravimetric analysis reveals it has good thermal stability. Also 1 represents firstly mixed oxoboron clusters-made 2D layered borate with NLO property.

KW - Borate

KW - Layered structure

KW - Mixed-oxoboron cluster

KW - Nonlinear optics

KW - Solvothermal syntheses

UR - https://www.scopus.com/pages/publications/85114315467

U2 - 10.1002/asia.202100869

DO - 10.1002/asia.202100869

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AN - SCOPUS:85114315467

SN - 1861-4728

VL - 16

SP - 3244

EP - 3248

JO - Chemistry - An Asian Journal

JF - Chemistry - An Asian Journal

IS - 20

ER -

K₂Na₃[{B₆O₁₀(OH)}{B₃O₄(OH)₃}] ⋅ H₂O: A Layered Borate Built by Mixed Oxoboron Clusters with Nonlinear-Optical Property

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